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Powder sample of white calcium oxide | |
Names | |
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IUPAC name Calcium oxide | |
Other names
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Identifiers | |
3D model (JSmol) | |
ChEBI | |
ChEMBL | |
ChemSpider | |
ECHA InfoCard | 100.013.763 |
EC Number |
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E number | E529 (acidity regulators, ...) |
485425 | |
KEGG | |
PubChem CID | |
RTECS number |
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UNII | |
UN number | 1910 |
CompTox Dashboard (EPA) | |
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Properties | |
CaO | |
Molar mass | 56.0774 g/mol |
Appearance | White to pale yellow/brown powder |
Odor | Odorless |
Density | 3.34 g/cm3 [1] |
Melting point | 2,613 °C (4,735 °F; 2,886 K) [1] |
Boiling point | 2,850 °C (5,160 °F; 3,120 K) (100 hPa) [2] |
Reacts to form calcium hydroxide | |
Solubility in Methanol | Insoluble (also in diethyl ether, octanol) |
Acidity (pKa) | 12.8 |
−15.0×10−6 cm3/mol | |
Structure | |
Cubic, cF8 | |
Thermochemistry | |
Std molar entropy (S⦵298) | 40 J·mol−1·K−1 [3] |
Std enthalpy of formation (ΔfH⦵298) | −635 kJ·mol−1 [3] |
Pharmacology | |
QP53AX18 ( WHO ) | |
Hazards | |
GHS labelling: | |
Danger | |
H302, H314, H315, H335 | |
P260, P261, P264, P270, P271, P280, P301+P312, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P310, P312, P321, P330, P332+P313, P362, P363, P403+P233, P405, P501 | |
NFPA 704 (fire diamond) | |
Flash point | Non-flammable [4] |
NIOSH (US health exposure limits): | |
PEL (Permissible) | TWA 5 mg/m3 [4] |
REL (Recommended) | TWA 2 mg/m3 [4] |
IDLH (Immediate danger) | 25 mg/m3 [4] |
Safety data sheet (SDS) | ICSC 0409 |
Related compounds | |
Other anions | Calcium sulfide Calcium hydroxide Calcium selenide Calcium telluride |
Other cations | Beryllium oxide Magnesium oxide Strontium oxide Barium oxide Radium oxide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Calcium oxide (formula: Ca O), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term lime connotes calcium-containing inorganic compounds, in which carbonates, oxides, and hydroxides of calcium, silicon, magnesium, aluminium, and iron predominate. By contrast, quicklime specifically applies to the single compound calcium oxide. Calcium oxide that survives processing without reacting in building products, such as cement, is called free lime. [5]
Quicklime is relatively inexpensive. Both it and the chemical derivative calcium hydroxide (of which quicklime is the base anhydride) are important commodity chemicals.
Calcium oxide is usually made by the thermal decomposition of materials, such as limestone or seashells, that contain calcium carbonate (CaCO3; mineral calcite) in a lime kiln. This is accomplished by heating the material to above 825 °C (1,517 °F), [6] [7] a process called calcination or lime-burning, to liberate a molecule of carbon dioxide (CO2), leaving quicklime behind. This is also one of the few chemical reactions known in prehistoric times. [8]
The quicklime is not stable and, when cooled, will spontaneously react with CO2 from the air until, after enough time, it will be completely converted back to calcium carbonate unless slaked with water to set as lime plaster or lime mortar.
Annual worldwide production of quicklime is around 283 million tonnes. China is by far the world's largest producer, with a total of around 170 million tonnes per year. The United States is the next largest, with around 20 million tonnes per year. [9]
Approximately 1.8 t of limestone is required per 1.0 t of quicklime. Quicklime has a high affinity for water and is a more efficient desiccant than silica gel. The reaction of quicklime with water is associated with an increase in volume by a factor of at least 2.5. [10]
In 80 BC, the Roman general Sertorius deployed choking clouds of caustic lime powder to defeat the Characitani of Hispania, who had taken refuge in inaccessible caves. [23] A similar dust was used in China to quell an armed peasant revolt in 178 AD, when lime chariots equipped with bellows blew limestone powder into the crowds. [24]
Quicklime is also thought to have been a component of Greek fire. Upon contact with water, quicklime would increase its temperature above 150 °C (302 °F) and ignite the fuel. [25]
David Hume, in his History of England , recounts that early in the reign of Henry III, the English Navy destroyed an invading French fleet by blinding the enemy fleet with quicklime. [26] Quicklime may have been used in medieval naval warfare – up to the use of "lime-mortars" to throw it at the enemy ships. [27]
Limestone is a substitute for lime in many applications, which include agriculture, fluxing, and sulfur removal. Limestone, which contains less reactive material, is slower to react and may have other disadvantages compared with lime, depending on the application; however, limestone is considerably less expensive than lime. Calcined gypsum is an alternative material in industrial plasters and mortars. Cement, cement kiln dust, fly ash, and lime kiln dust are potential substitutes for some construction uses of lime. Magnesium hydroxide is a substitute for lime in pH control, and magnesium oxide is a substitute for dolomitic lime as a flux in steelmaking. [28]
Because of vigorous reaction of quicklime with water, quicklime causes severe irritation when inhaled or placed in contact with moist skin or eyes. Inhalation may cause coughing, sneezing, and labored breathing. It may then evolve into burns with perforation of the nasal septum, abdominal pain, nausea and vomiting. Although quicklime is not considered a fire hazard, its reaction with water can release enough heat to ignite combustible materials. [29] [ better source needed ]
Calcium oxide is also a separate mineral species (with the unit formula CaO), named 'Lime'. [30] [31] It has an isometric crystal system, and can form a solid solution series with monteponite. The crystal is brittle, pyrometamorphic, and is unstable in moist air, quickly turning into portlandite (Ca(OH)2). [32]
A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel (aggregate) together. Cement mixed with fine aggregate produces mortar for masonry, or with sand and gravel, produces concrete. Concrete is the most widely used material in existence and is behind only water as the planet's most-consumed resource.
Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations Na+ and hydroxide anions OH−.
Sodium carbonate is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water. Historically, it was extracted from the ashes of plants grown in sodium-rich soils, and because the ashes of these sodium-rich plants were noticeably different from ashes of wood, sodium carbonate became known as "soda ash". It is produced in large quantities from sodium chloride and limestone by the Solvay process, as well as by carbonating sodium hydroxide which is made using the Chlor-alkali process.
Plaster is a building material used for the protective or decorative coating of walls and ceilings and for moulding and casting decorative elements. In English, "plaster" usually means a material used for the interiors of buildings, while "render" commonly refers to external applications. The term stucco refers to plasterwork that is worked in some way to produce relief decoration, rather than flat surfaces.
Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula Ca(OH)2. It is a colorless crystal or white powder and is produced when quicklime (calcium oxide) is mixed with water. It has many names including hydrated lime, caustic lime, builders' lime, slaked lime, cal, and pickling lime. Calcium hydroxide is used in many applications, including food preparation, where it has been identified as E number E526. Limewater, also called milk of lime, is the common name for a saturated solution of calcium hydroxide.
Calcium silicate is the chemical compound Ca2SiO4, also known as calcium orthosilicate and is sometimes formulated as 2CaO·SiO2. It is also referred to by the shortened trade name Cal-Sil or Calsil. It occurs naturally as the mineral larnite.
Calcium sulfate (or calcium sulphate) is the inorganic compound with the formula CaSO4 and related hydrates. In the form of γ-anhydrite (the anhydrous form), it is used as a desiccant. One particular hydrate is better known as plaster of Paris, and another occurs naturally as the mineral gypsum. It has many uses in industry. All forms are white solids that are poorly soluble in water. Calcium sulfate causes permanent hardness in water.
Calcination is thermal treatment of a solid chemical compound (e.g. mixed carbonate ores) whereby the compound is raised to high temperature without melting under restricted supply of ambient oxygen (i.e. gaseous O2 fraction of air), generally for the purpose of removing impurities or volatile substances and/or to incur thermal decomposition.
Lime is an inorganic material composed primarily of calcium oxides and hydroxides, usually calcium oxide and/or calcium hydroxide. It is also the name for calcium oxide which occurs as a product of coal-seam fires and in altered limestone xenoliths in volcanic ejecta. The International Mineralogical Association recognizes lime as a mineral with the chemical formula of CaO. The word lime originates with its earliest use as building mortar and has the sense of sticking or adhering.
Hydraulic lime (HL) is a general term for calcium oxide, a variety of lime also called quicklime, that sets by hydration. This contrasts with calcium hydroxide, also called slaked lime or air lime that is used to make lime mortar, the other common type of lime mortar, which sets by carbonation (re-absorbing carbon dioxide (CO2) from the air). Hydraulic lime provides a faster initial set and higher compressive strength than air lime, and hydraulic lime will set in more extreme conditions, including under water.
In horticulture, lime sulfur (lime sulphur in British English, see American and British English spelling differences) is mainly a mixture of calcium polysulfides and thiosulfate (plus other reaction by-products as sulfite and sulfate) formed by reacting calcium hydroxide with elemental sulfur, used in pest control. It can be prepared by boiling in water a suspension of poorly soluble calcium hydroxide (lime) and solid sulfur together with a small amount of surfactant to facilitate the dispersion of these solids in water. After elimination of any residual solids (flocculation, decantation and filtration), it is normally used as an aqueous solution, which is reddish-yellow in colour and has a distinctive offensive odor of hydrogen sulfide (H2S, rotten eggs).
Lime mortar or torching is a masonry mortar composed of lime and an aggregate such as sand, mixed with water. It is one of the oldest known types of mortar, used in ancient Rome and Greece, when it largely replaced the clay and gypsum mortars common to ancient Egyptian construction.
Cement clinker is a solid material produced in the manufacture of portland cement as an intermediary product. Clinker occurs as lumps or nodules, usually 3 millimetres (0.12 in) to 25 millimetres (0.98 in) in diameter. It is produced by sintering limestone and aluminosilicate materials such as clay during the cement kiln stage.
The alkali–silica reaction (ASR), also commonly known as concrete cancer, is a deleterious internal swelling reaction that occurs over time in concrete between the highly alkaline cement paste and the reactive amorphous silica found in many common aggregates, given sufficient moisture.
A carbon dioxide scrubber is a piece of equipment that absorbs carbon dioxide (CO2). It is used to treat exhaust gases from industrial plants or from exhaled air in life support systems such as rebreathers or in spacecraft, submersible craft or airtight chambers. Carbon dioxide scrubbers are also used in controlled atmosphere (CA) storage. They have also been researched for carbon capture and storage as a means of combating climate change.
Concrete degradation may have many different causes. Concrete is mostly damaged by the corrosion of reinforcement bars due to the carbonatation of hardened cement paste or chloride attack under wet conditions. Chemical damages are caused by the formation of expansive products produced by various chemical reactions, by aggressive chemical species present in groundwater and seawater, or by microorganisms. Other damaging processes can also involve calcium leaching by water infiltration and different physical phenomena initiating cracks formation and propagation. All these detrimental processes and damaging agents adversely affects the concrete mechanical strength and its durability.
The pozzolanic activity is a measure for the degree of reaction over time or the reaction rate between a pozzolan and Ca2+ or calcium hydroxide (Ca(OH)2) in the presence of water. The rate of the pozzolanic reaction is dependent on the intrinsic characteristics of the pozzolan such as the specific surface area, the chemical composition and the active phase content.
The conservation and restoration of frescoes is the process of caring for and maintaining frescos, and includes documentation, examination, research, and treatment to insure their long-term viability, when desired.
Calthemite is a secondary deposit, derived from concrete, lime, mortar or other calcareous material outside the cave environment. Calthemites grow on or under, man-made structures and mimic the shapes and forms of cave speleothems, such as stalactites, stalagmites, flowstone etc. Calthemite is derived from the Latin calx "lime" + Latin < Greek théma, "deposit" meaning ‘something laid down’, and the Latin –ita < Greek -itēs – used as a suffix indicating a mineral or rock. The term "speleothem", due to its definition can only be used to describe secondary deposits in caves and does not include secondary deposits outside the cave environment.
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