Calcium permanganate

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Calcium permanganate
CalciumPermanganate.jpg
Names
IUPAC name
Calcium dipermanganate [1]
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.280 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 233-322-7
PubChem CID
RTECS number
  • EW3860000
UNII
  • InChI=1S/Ca.2Mn.8O/q+2;;;;;;;;;2*-1 Yes check.svgY
    Key: HYSMCTNXSYZEHS-UHFFFAOYSA-N Yes check.svgY
  • InChI=1/Ca.2Mn.8O/q+2;;;;;;;;;2*-1/rCa.2MnO4/c;2*2-1(3,4)5/q+2;2*-1
    Key: HYSMCTNXSYZEHS-KTXORSEZAZ
  • [Ca+2].O=[Mn](=O)(=O)[O-].[O-] [Mn](=O)(=O)=O
Properties
Ca(MnO4)2
Molar mass 277.9493 g/mol
Appearancepurple crystals
deliquesent
Density 2.49 g/cm3
Melting point 140 °C (284 °F; 413 K) (decomposes, tetrahydrate)
tetrahydrate:
331 g/100 mL (14 °C)
338 g/100 mL (25 °C)
Solubility soluble in ammonium hydroxide
decomposes in alcohol
Related compounds
Other cations
Sodium permanganate
Ammonium permanganate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Calcium permanganate is an oxidizing agent and chemical compound with the chemical formula Ca(MnO4)2. This salt consists of the metal calcium and two permanganate ions.

Contents

Preparation

The salt is prepared from the reaction of potassium permanganate with calcium chloride [2] or from the reaction of aluminium permanganate with calcium oxide. It can also be prepared by reacting manganese dioxide with a solution of calcium hypochlorite and a little bit of calcium hydroxide to increase the pH level.[ citation needed ]

Uses

Calcium permanganate is used in the textile industry, for sterilization of water, and as a deodorizer. [2] It is believed to help whiten teeth. [3] It was formerly used as a component of rocket fuel by the Luftwaffe. [4]

Safety

It is noncombustible, but being a strong oxidizing agent, it will accelerate the burning of combustible material. If the combustible material is finely divided, the resulting mixture may be explosive. Contact with liquid combustible materials may result in spontaneous ignition. Contact with sulfuric acid may cause fires or explosions. Mixtures with acetic acid or acetic anhydride can explode if not kept cold. Explosions can occur when mixtures of calcium permanganate and sulfuric acid come into contact with benzene, carbon disulfide, diethyl ether, ethyl alcohol, petroleum, or other organic matter. [5]

See also

Related Research Articles

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<span class="mw-page-title-main">Oxidizing agent</span> Chemical compound used to oxidize another substance in a chemical reaction

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Potassium chlorate is a compound containing potassium, chlorine and oxygen, with the molecular formula KClO3. In its pure form, it is a white crystalline substance. After sodium chlorate, it is the second most common chlorate in industrial use. It is a strong oxidizing agent and its most important application is in safety matches. In other applications it is mostly obsolete and has been replaced by safer alternatives in recent decades. It has been used

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Potassium permanganate is an inorganic compound with the chemical formula KMnO4. It is a purplish-black crystalline salt, that dissolves in water as K+ and MnO
4
, an intensely pink to purple solution.

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References

  1. "CALCIUM PERMANGANATE, CAS Number: 10118-76-0".
  2. 1 2 Perry, Dale L. (2011). Handbook of Inorganic Compounds (2nd ed.). Boca Raton: Taylor & Francis. pp. 94–95. ISBN   978-1-4398-1461-1.
  3. EP 1786352A1,"Permanganate containing whitening compositions and methods of their use",issued 2005-08-23
  4. Van Pelt, Michel (2012). Rocketing into the future : the history and technology of rocket planes. New York: Springer. p. 60. ISBN   978-1-4614-3200-5.
  5. "Calcium permanganate Safety Data Sheet". www.echemi.com.