Names | |
---|---|
Preferred IUPAC name Calcium diformate | |
Other names
| |
Identifiers | |
3D model (JSmol) | |
ChEBI | |
ChemSpider | |
ECHA InfoCard | 100.008.058 |
EC Number |
|
E number | E238 (preservatives) |
KEGG | |
PubChem CID | |
RTECS number |
|
UNII | |
CompTox Dashboard (EPA) | |
| |
| |
Properties | |
Ca(HCO2)2 | |
Molar mass | 130.113 g/mol |
Appearance | white-to-yellow crystals or crystalline powder [1] |
Odor | smells slightly like acetic acid [2] |
Density | 2.02 g/cm3 [3] |
Melting point | decomposes at 300 °C [3] |
16.1 g/100 g (0 °C) 18.4 g/100 g (100 °C) | |
Solubility | insoluble in ethanol [3] methanol: 0.27 g/100 g (15 °C) 0.23 g/100 g (66 °C) [4] |
Hazards | |
GHS labelling: | |
Danger | |
H318 | |
P264, P280, P305+P351+P338, P310, P337+P313 | |
NFPA 704 (fire diamond) | |
Lethal dose or concentration (LD, LC): | |
LD50 (median dose) | rats: 2640 mg/kg (oral), 154 mg/kg (IV) [4] |
Related compounds | |
Other anions | Calcium acetate |
Other cations | Sodium formate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Calcium formate is the calcium salt of formic acid. It is also known as E238. Under this E number it is used as an animal feed preservative within EU, but not in foods intended for people. [5]
Calcium formate is stable at room temperature, [5] is flammable and forms orthorhombic crystals. [2] The mineral form is very rare and called formicaite, and is known from a few boron deposits.
Calcium formate is used within EU as an animal feed preservative. It acidifies the feed thus preventing microbe growth and increasing shelf life. About 15 g of calcium formate addition per kg of feed lowers its pH by one. 15 g/kg is the maximum recommended feed concentration within EU – this level is thought to be safe for pigs, chickens, fish and ruminants. The compound is not environmentally harmful in feed use at these levels. Calcium formate prevents the growth bacteria such as E. coli, Pseudomonas aeruginosa, Staphylococcus aureus and Enterococcus hirae in growth mediums. It also prevents the growth of fungi like Aspergillus niger and Candida albicans . However, the relevance of these experimental observations to feed preservation is not known. [5]
Calcium formate is used as a masking agent in the chrome tanning of leather. Calcium formate in tannage formulation promotes faster, more efficient leather penetration of the chrome. Calcium formate can also be used as a replacement for formic acid in the pickling operation. [4]
As a grout and cement additive, calcium formate imparts a number of desirable properties in the final product, e.g. increased hardness and decreased setting time. Its addition is desirable for work at low temperature and for inhibition of corrosion of metal substrates within cement/grout. It is also effective in the prevention of efflorescence. In drywall (gypsum board), calcium formate can function as a fire retardant. [4]
Calcium formate and urea mixtures are effective deicers, and tend to cause less corrosion of steel and cement surfaces relative to some other deicers. [4]
Calcium formate seems to be safe as a calcium supplement for people with one time doses of 3.9 g (1200 of calcium) per day. [6] Increases in blood formate concentration have been observed with such doses, but in healthy subjects the formate does not accumulate, and is quickly metabolized. Calcium formate is shown to be more readily absorbed form of calcium than calcium carbonate and calcium citrate. [7] No optic nerve damage has been observed with calcium formate supplementation – along with formaldehyde, formate is a major metabolic product of methanol, which can cause blindness upon ingestion. [8]
Calcium formate could be used to remove environmentally harmful (see acid rain) sulfur oxides (SOX) from fossil fuel exhausts of e.g. power plants. Calcium formate is added to wet calcium carbonate to promote the formation of gypsum when exhaust is run through it. This process is called wet flue gas desulfurization (WFGS). Gypsum binds sulfur oxides thus reducing their release to the environment via exhaust. Calcium formate seems to be more effective than or almost equally as effective as some other industrially used WFGS agents. [9]
Calcium formate is formed as a co-product during trimethylolpropane production. Hydrated lime (calcium hydroxide) is used as the source of calcium. Butyraldehyde and formaldehyde react in a water solution in the presence of a basic catalyst, forming an unstable intermediate product, dimethylol butyraldehyde (DIMBA). DIMBA reacts further with formaldehyde to give trimethylolpropane and calcium formate. Calcium formate is separated from the solution, heat treated to remove formaldehyde and then dried. [5]
Calcium formate can also be made from calcium hydroxide and carbon monoxide at high pressure and temperature [2] – e.g., at 180 °C and 35 atm. [10] It may also be made from calcium chloride and formic acid. [2]
Pure calcium formate powder irritates eyes severely, but causes no skin irritation. Powder inhalation can be dangerous. [5] The compound has a stinging taste. Ingesting liquids with high calcium formate concentrations cause severe gastrointestinal lesions. [11]
Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula CaSO4·2H2O. It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, drywall and blackboard or sidewalk chalk. Gypsum also crystallizes as translucent crystals of selenite. It forms as an evaporite mineral and as a hydration product of anhydrite. The Mohs scale of mineral hardness defines gypsum as hardness value 2 based on scratch hardness comparison.
Potassium ferrocyanide is the inorganic compound with formula K4[Fe(CN)6]·3H2O. It is the potassium salt of the coordination complex [Fe(CN)6]4−. This salt forms lemon-yellow monoclinic crystals.
Calcium carbonate is a chemical compound with the chemical formula CaCO3. It is a common substance found in rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skeletons and pearls. Materials containing much calcium carbonate or resembling it are described as calcareous. Calcium carbonate is the active ingredient in agricultural lime and is produced when calcium ions in hard water react with carbonate ions to form limescale. It has medical use as a calcium supplement or as an antacid, but excessive consumption can be hazardous and cause hypercalcemia and digestive issues.
Calcium oxide, commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term lime connotes calcium-containing inorganic compounds, in which carbonates, oxides, and hydroxides of calcium, silicon, magnesium, aluminium, and iron predominate. By contrast, quicklime specifically applies to the single compound calcium oxide. Calcium oxide that survives processing without reacting in building products, such as cement, is called free lime.
Calcium silicate can refer to several silicates of calcium including:
Calcium sulfate (or calcium sulphate) is the inorganic compound with the formula CaSO4 and related hydrates. In the form of γ-anhydrite (the anhydrous form), it is used as a desiccant. One particular hydrate is better known as plaster of Paris, and another occurs naturally as the mineral gypsum. It has many uses in industry. All forms are white solids that are poorly soluble in water. Calcium sulfate causes permanent hardness in water.
Trisodium citrate has the molecular formula Na3C6H5O7. It is sometimes referred to simply as "sodium citrate", though sodium citrate can refer to any of the three sodium salts of citric acid. It possesses a saline, mildly tart flavor, and is a mild alkali.
Calcium citrate is the calcium salt of citric acid. It is commonly used as a food additive (E333), usually as a preservative, but sometimes for flavor. In this sense, it is similar to sodium citrate. Calcium citrate is also found in some dietary calcium supplements. Calcium makes up 24.1% of calcium citrate (anhydrous) and 21.1% of calcium citrate (tetrahydrate) by mass. The tetrahydrate occurs in nature as the mineral Earlandite.
Deicing is the process of removing snow, ice or frost from a surface. Anti-icing is the application of chemicals that not only deice but also remain on a surface and continue to delay the reformation of ice for a certain period of time, or prevent adhesion of ice to make mechanical removal easier.
Calcium lactate is a white crystalline salt with formula C
6H
10CaO
6, consisting of two lactate anions H
3C(CHOH)CO−
2 for each calcium cation Ca2+
. It forms several hydrates, the most common being the pentahydrate C
6H
10CaO
6·5H
2O.
Calcium citrate malate is a water-soluble calcium supplement. It is the calcium salt of citric acid and malic acid with variable composition.
Potassium acetate (also called potassium ethanoate), (CH3COOK) is the potassium salt of acetic acid. It is a hygroscopic solid at room temperature.
Sodium formate, HCOONa, is the sodium salt of formic acid, HCOOH. It usually appears as a white deliquescent powder.
A cement mill is the equipment used to grind the hard, nodular clinker from the cement kiln into the fine grey powder that is cement. Most cement is currently ground in ball mills and also vertical roller mills which are more effective than ball mills.
Calcium sulfite, or calcium sulphite, is a chemical compound, the calcium salt of sulfite with the formula CaSO3·x(H2O). Two crystalline forms are known, the hemihydrate and the tetrahydrate, respectively CaSO3·½(H2O) and CaSO3·4(H2O). All forms are white solids. It is most notable as the product of flue-gas desulfurization.
Calcium bisulfite is an inorganic compound which is the salt of a calcium cation and a bisulfite anion. It may be prepared by treating lime with an excess of sulfur dioxide and water. As a food additive it is used as a preservative under the E number E227. Calcium bisulfite is an acid salt and behaves like an acid in aqueous solution. It is used in the sulfite process for producing paper from wood chips.
Concrete degradation may have many different causes. Concrete is mostly damaged by the corrosion of reinforcement bars due to the carbonatation of hardened cement paste or chloride attack under wet conditions. Chemical damage is caused by the formation of expansive products produced by chemical reactions, by aggressive chemical species present in groundwater and seawater, or by microorganisms Other damaging processes can also involve calcium leaching by water infiltration, physical phenomena initiating cracks formation and propagation, fire or radiant heat, aggregate expansion, sea water effects, leaching, and erosion by fast-flowing water.
Amorphous calcium carbonate (ACC) is the amorphous and least stable polymorph of calcium carbonate. ACC is extremely unstable under normal conditions and is found naturally in taxa as wide-ranging as sea urchins, corals, mollusks, and foraminifera. It is usually found as a monohydrate, holding the chemical formula CaCO3·H2O; however, it can also exist in a dehydrated state, CaCO3. ACC has been known to science for over 100 years when a non-diffraction pattern of calcium carbonate was discovered by Sturcke Herman, exhibiting its poorly-ordered nature.
Calcium supplements are salts of calcium used in a number of conditions. Supplementation is generally only required when there is not enough calcium in the diet. By mouth they are used to treat and prevent low blood calcium, osteoporosis, and rickets. By injection into a vein they are used for low blood calcium that is resulting in muscle spasms and for high blood potassium or magnesium toxicity.
{{cite book}}
: CS1 maint: others (link)