Calcium hydroxide

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Contents

Calcium hydroxide
Calcium hydroxide.jpg
Mg(OH)2Xray.jpg
Names
IUPAC name
Calcium hydroxide
Other names
  • Slaked lime
  • Milk of lime
  • Calcium(II) hydroxide
  • Pickling lime
  • Hydrated lime
  • Portlandite
  • Calcium hydrate
  • Calcium dihydroxide
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.013.762 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 215-13
E number E526 (acidity regulators, ...)
846915
KEGG
PubChem CID
RTECS number
  • EW2800000
UNII
  • InChI=1S/Ca.2H2O/h;2*1H2/q+2;;/p-2 Yes check.svgY
    Key: AXCZMVOFGPJBDE-UHFFFAOYSA-L Yes check.svgY
  • InChI=1/Ca.2H2O/h;2*1H2/q+2;;/p-2
    Key: AXCZMVOFGPJBDE-NUQVWONBAD
  • [Ca+2].[OH-].[OH-]
  • [OH-].[OH-].[Ca+2]
Properties
Ca(OH)2
Molar mass 74.093 g/mol
AppearanceWhite powder
Odor Odorless
Density 2.211 g/cm3, solid
Melting point 580 °C (1,076 °F; 853 K) (loses water, decomposes)
  • 1.89 g/L (0 °C)
  • 1.73 g/L (20 °C)
  • 0.66 g/L (100 °C)
  • (retrograde solubility, i.e., unusually decreasing with T)
5.02×106 [1]
Solubility
Acidity (pKa)pKa1 = 12.63
pKa2 = 11.57 [2] [3]
−22.0·10−6 cm3/mol
1.574
Structure
Hexagonal, hP3 [4]
P3m1 No. 164
a = 0.35853 nm, c = 0.4895 nm
Thermochemistry
Std molar
entropy
(S298)
83 J·mol−1·K−1 [5]
−987 kJ·mol−1 [5]
Hazards
GHS labelling:
GHS-pictogram-acid.svg GHS-pictogram-exclam.svg
Danger
H314, H335, H402
P261, P280, P305+P351+P338
NFPA 704 (fire diamond)
NFPA 704.svgHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
3
0
0
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
7340 mg/kg (oral, rat)
7300 mg/kg (mouse)
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 15 mg/m3 (total) 5 mg/m3 (resp.) [6]
REL (Recommended)
TWA 5 mg/m3 [6]
IDLH (Immediate danger)
N.D. [6]
Safety data sheet (SDS) [7]
Related compounds
Other cations
Magnesium hydroxide
Strontium hydroxide
Barium hydroxide
Related bases
Calcium oxide
Supplementary data page
Calcium hydroxide (data page)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Yes check.svgY  verify  (what is  Yes check.svgYX mark.svgN ?)

Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula Ca(OH)2. It is a colorless crystal or white powder and is produced when quicklime (calcium oxide) is mixed with water. Annually, approximately 125 million tons of calcium hydroxide are produced worldwide. [8]

Calcium hydroxide has many names including hydrated lime, caustic lime, builders' lime, slaked lime, cal, and pickling lime. Calcium hydroxide is used in many applications, including food preparation, where it has been identified as E number E526. Limewater, also called milk of lime, is the common name for a saturated solution of calcium hydroxide.

Solubility

Calcium hydroxide is modestly soluble in water, as seen for many dihydroxides. Its solubility increases from 0.66 g/L at 100 °C to 1.89 g/L at 0 °C. [8] Its solubility product Ksp of 5.02×10−6 at 25 °C, [1] its dissociation in water is large enough that its solutions are basic according to the following dissolution reaction:

Ca(OH)2 → Ca2+ + 2 OH

The solubility is affected by the common-ion effect. Its solubility drastically decreases upon addition of hydroxide or calcium sources.

Reactions

When heated to 512 °C, the partial pressure of water in equilibrium with calcium hydroxide reaches 101 kPa (normal atmospheric pressure), which decomposes calcium hydroxide into calcium oxide and water: [9]

Ca(OH)2 → CaO + H2O

When carbon dioxide is passed through limewater, the solution takes on a milky appearance due to precipitation of insoluble calcium carbonate:

Ca(OH)2(aq) + CO2(g) → CaCO3(s) + H2O(l)

If excess CO2 is added: the following reaction takes place:

CaCO3(s) + H2O(l) + CO2(g)Ca(HCO3)2 (aq)

The milkiness disappears since calcium bicarbonate is water-soluble.

Calcium hydroxide reacts with aluminium. This reaction is the basis of aerated concrete. [8] It does not corrode iron and steel, owing to passivation of their surface.

Calcium hydroxide reacts with hydrochloric acid to give calcium hydroxychloride and then calcium chloride.

In a process called sulfation, sulphur dioxide reacts with limewater:

Ca(OH)2(aq) + SO2(g) → CaSO3(s) + H2O(l)

Limewater is used in a process known as lime softening to reduce water hardness. It is also used as a neutralizing agent in municipal waste water treatment.

Structure and preparation

SEM image of fractured hardened cement paste, showing plates of calcium hydroxide and needles of ettringite (micron scale) CaOH2SEM.jpg
SEM image of fractured hardened cement paste, showing plates of calcium hydroxide and needles of ettringite (micron scale)

Calcium hydroxide adopts a polymeric structure, as do all metal hydroxides. The structure is identical to that of Mg(OH)2 (brucite structure); i.e., the cadmium iodide motif. Strong hydrogen bonds exist between the layers. [10]

Calcium hydroxide is produced commercially by treating (slaking) quicklime with water:

CaO + H2O → Ca(OH)2

Alongside the production of quicklime from limestone by calcination, this is one of the oldest known chemical reactions; evidence of prehistoric production dates back to at least 7000 BCE. [11]

Uses

Calcium hydroxide is commonly used to prepare lime mortar.

One significant application of calcium hydroxide is as a flocculant, in water and sewage treatment. It forms a fluffy charged solid that aids in the removal of smaller particles from water, resulting in a clearer product. This application is enabled by the low cost and low toxicity of calcium hydroxide. It is also used in fresh-water treatment for raising the pH of the water so that pipes will not corrode where the base water is acidic, because it is self-regulating and does not raise the pH too much.[ citation needed ]

Another large application is in the paper industry, where it is an intermediate in the reaction in the production of sodium hydroxide. This conversion is part of the causticizing step in the Kraft process for making pulp. In the causticizing operation, burned lime is added to green liquor , which is a solution primarily of sodium carbonate and sodium sulfate produced by dissolving smelt, which is the molten form of these chemicals from the recovery furnace. [10]

In orchard crops, calcium hydroxide is used as a fungicide. Applications of 'lime water' prevent the development of cankers caused by the fungal pathogen Neonectria galligena . The trees are sprayed when they are dormant in winter to prevent toxic burns from the highly reactive calcium hydroxide. This use is authorised in the European Union and the United Kingdom under Basic Substance regulations. [12]

Calcium hydroxide is used in dentistry, primarily in the specialty of endodontics.

Food industry

Because of its low toxicity and the mildness of its basic properties, slaked lime is widely used in the food industry,

Native American uses

Dry untreated maize (left), and treated maize (right) after boiling in water with calcium hydroxide (15 ml, or 1 tbsp, lime for 500 g of corn) for 15 minutes Nixtamalized Corn maize El Salvador recipe.jpg
Dry untreated maize (left), and treated maize (right) after boiling in water with calcium hydroxide (15 ml, or 1 tbsp, lime for 500 g of corn) for 15 minutes

In Nahuatl, the language of the Aztecs, the word for calcium hydroxide is nextli. In a process called nixtamalization , maize is cooked with nextli to become nixtamal, also known as hominy. Nixtamalization significantly increases the bioavailability of niacin (vitamin B3), and is also considered tastier and easier to digest. Nixtamal is often ground into a flour, known as masa , which is used to make tortillas and tamales.[ citation needed ]

Limewater is used in the preparation of maize for corn tortillas and other culinary purposes using a process known as nixtamalization. Nixtamalization makes the niacin nutritionally available and prevents pellagra. [16] Traditionally lime water was used in Taiwan and China to preserve persimmon and to remove astringency. [17] :623

In chewing coca leaves, calcium hydroxide is usually chewed alongside to keep the alkaloid stimulants chemically available for absorption by the body. Similarly, Native Americans traditionally chewed tobacco leaves with calcium hydroxide derived from burnt mollusc shells to enhance the effects. It has also been used by some indigenous South American tribes as an ingredient in yopo , a psychedelic snuff prepared from the beans of some Anadenanthera species. [18]

Asian uses

Calcium hydroxide is typically added to a bundle of areca nut and betel leaf called "paan" to keep the alkaloid stimulants chemically available to enter the bloodstream via sublingual absorption.

It is used in making naswar (also known as nass or niswar), a type of dipping tobacco made from fresh tobacco leaves, calcium hydroxide (chuna/choona or soon), and wood ash. It is consumed most in the Pathan diaspora, Afghanistan, Pakistan, India and Bangladesh. Villagers also use calcium hydroxide to paint their mud houses in Afghanistan, Pakistan and India.

Hobby uses

In buon fresco painting, limewater is used as the colour solvent to apply on fresh plaster. Historically, it is known as the paint whitewash.

Closeup of cast of The Dying Gaul, showing distinctive hairstyle, supposedly derived from washing in limewater Dying Gaul (casting in Pushkin museum) 04 by shakko.jpg
Closeup of cast of The Dying Gaul, showing distinctive hairstyle, supposedly derived from washing in limewater

Limewater is widely used by marine aquarists as a primary supplement of calcium and alkalinity for reef aquariums. Corals of order Scleractinia build their endoskeletons from aragonite (a polymorph of calcium carbonate). When used for this purpose, limewater is usually referred to as Kalkwasser. It is also used in tanning and making parchment. The lime is used as a dehairing agent based on its alkaline properties. [19]

Personal care and adornment

Treating one's hair with limewater causes it to stiffen and bleach, with the added benefit of killing any lice or mites living there. Diodorus Siculus described the Celts as follows: "Their aspect is terrifying... They are very tall in stature, with rippling muscles under clear white skin. Their hair is blond, but not only naturally so: they bleach it, to this day, artificially, washing it in lime and combing it back from their foreheads. They look like wood-demons, their hair thick and shaggy like a horse's mane. Some of them are clean-shaven, but others – especially those of high rank, shave their cheeks but leave a moustache that covers the whole mouth...". [20] [21]

Calcium hydroxide is also applied in a leather process called liming.

Interstellar medium

The ion CaOH+ has been detected in the atmosphere of S-type stars. [22]

Limewater

Limewater is a saturated aqueous solution of calcium hydroxide. Calcium hydroxide is sparsely soluble at room temperature in water (1.5 g/L at 25 °C [23] ). "Pure" (i.e. less than or fully saturated) limewater is clear and colorless, with a slight earthy smell and an astringent/bitter taste. It is basic in nature with a pH of 12.4. Limewater is named after limestone, not the lime fruit. Limewater may be prepared by mixing calcium hydroxide (Ca(OH)2) with water and removing excess undissolved solute (e.g. by filtration). When excess calcium hydroxide is added (or when environmental conditions are altered, e.g. when its temperature is raised sufficiently), there results a milky solution due to the homogeneous suspension of excess calcium hydroxide. This liquid has been known traditionally as milk of lime.

Health risks

Unprotected exposure to Ca(OH)2, as with any strong base, can cause skin burns, but it is not acutely toxic. [8]

See also

Related Research Articles

In chemistry, an alkali is a basic, ionic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a soluble base has a pH greater than 7.0. The adjective alkaline, and less often, alkalescent, is commonly used in English as a synonym for basic, especially for bases soluble in water. This broad use of the term is likely to have come about because alkalis were the first bases known to obey the Arrhenius definition of a base, and they are still among the most common bases.

<span class="mw-page-title-main">Calcium carbonate</span> Chemical compound

Calcium carbonate is a chemical compound with the chemical formula CaCO3. It is a common substance found in rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skeletons and pearls. Materials containing much calcium carbonate or resembling it are described as calcareous. Calcium carbonate is the active ingredient in agricultural lime and is produced when calcium ions in hard water react with carbonate ions to form limescale. It has medical use as a calcium supplement or as an antacid, but excessive consumption can be hazardous and cause hypercalcemia and digestive issues.

<span class="mw-page-title-main">Sodium hydroxide</span> Chemical compound with formula NaOH

Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations Na+ and hydroxide anions OH.

<span class="mw-page-title-main">Base (chemistry)</span> Type of chemical substance

In chemistry, there are three definitions in common use of the word "base": Arrhenius bases, Brønsted bases, and Lewis bases. All definitions agree that bases are substances that react with acids, as originally proposed by G.-F. Rouelle in the mid-18th century.

<span class="mw-page-title-main">Calcium oxide</span> Chemical compound of calcium

Calcium oxide, commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term lime connotes calcium-containing inorganic compounds, in which carbonates, oxides, and hydroxides of calcium, silicon, magnesium, aluminium, and iron predominate. By contrast, quicklime specifically applies to the single compound calcium oxide. Calcium oxide that survives processing without reacting in building products, such as cement, is called free lime.

<span class="mw-page-title-main">Sodium carbonate</span> Chemical compound

Sodium carbonate is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water. Historically, it was extracted from the ashes of plants grown in sodium-rich soils, and because the ashes of these sodium-rich plants were noticeably different from ashes of wood, sodium carbonate became known as "soda ash". It is produced in large quantities from sodium chloride and limestone by the Solvay process, as well as by carbonating sodium hydroxide which is made using the chloralkali process.

<span class="mw-page-title-main">Lye</span> Sodium hydroxide and potassium hydroxide

A lye refers to sodium hydroxide and potassium hydroxide. The word lye most accurately refers to sodium hydroxide (NaOH), but historically has been conflated to include other alkali materials, most notably potassium hydroxide (KOH). In order to distinguish between the two, sodium hydroxide may be referred to as soda lye while potassium hydroxide may be referred to as potash lye.

<span class="mw-page-title-main">Potassium hydroxide</span> Inorganic compound (KOH)

Potassium hydroxide is an inorganic compound with the formula KOH, and is commonly called caustic potash.

<span class="mw-page-title-main">Magnesium carbonate</span> Chemical compound

Magnesium carbonate, MgCO3, is an inorganic salt that is a colourless or white solid. Several hydrated and basic forms of magnesium carbonate also exist as minerals.

<span class="mw-page-title-main">Soda lime</span> Chemical mixture for absorbing carbon dioxide

Soda lime, a mixture of sodium hydroxide (NaOH) and calcium oxide (CaO), is used in granular form within recirculating breathing environments like general anesthesia and its breathing circuit, submarines, rebreathers, and hyperbaric chambers and underwater habitats. Its purpose is to eliminate carbon dioxide from breathing gases, preventing carbon dioxide retention and, eventually, carbon dioxide poisoning. The creation of soda lime involves treating slaked lime with a concentrated sodium hydroxide solution.

<span class="mw-page-title-main">Neutralization (chemistry)</span> Chemical reaction in which an acid and a base react quantitatively

In chemistry, neutralization or neutralisation is a chemical reaction in which acid and a base react with an equivalent quantity of each other. In a reaction in water, neutralization results in there being no excess of hydrogen or hydroxide ions present in the solution. The pH of the neutralized solution depends on the acid strength of the reactants.

<span class="mw-page-title-main">Calcium sulfate</span> Chemical derived from gypsum used in food and industry

Calcium sulfate (or calcium sulphate) is the inorganic compound with the formula CaSO4 and related hydrates. In the form of γ-anhydrite (the anhydrous form), it is used as a desiccant. One particular hydrate is better known as plaster of Paris, and another occurs naturally as the mineral gypsum. It has many uses in industry. All forms are white solids that are poorly soluble in water. Calcium sulfate causes permanent hardness in water.

<span class="mw-page-title-main">Barium chloride</span> Chemical compound

Barium chloride is an inorganic compound with the formula BaCl2. It is one of the most common water-soluble salts of barium. Like most other water-soluble barium salts, it is a white powder, highly toxic, and imparts a yellow-green coloration to a flame. It is also hygroscopic, converting to the dihydrate BaCl2·2H2O, which are colourless crystals with a bitter salty taste. It has limited use in the laboratory and industry.

Carbonatation is a chemical reaction in which calcium hydroxide reacts with carbon dioxide and forms insoluble calcium carbonate:

<span class="mw-page-title-main">Lime (material)</span> Calcium oxides and/or hydroxides

Lime is an inorganic material composed primarily of calcium oxides and hydroxides. It is also the name for calcium oxide which occurs as a product of coal-seam fires and in altered limestone xenoliths in volcanic ejecta. The International Mineralogical Association recognizes lime as a mineral with the chemical formula of CaO. The word lime originates with its earliest use as building mortar and has the sense of sticking or adhering.

<span class="mw-page-title-main">Nixtamalization</span> Procedure for preparing corn to eat

Nixtamalization is a process for the preparation of maize, or other grain, in which the grain is soaked and cooked in an alkaline solution, usually limewater, washed, and then hulled. The term can also refer to the removal via an alkali process of the pericarp from other grains such as sorghum.

In horticulture, lime sulfur (lime sulphur in British English, see American and British English spelling differences) is mainly a mixture of calcium polysulfides and thiosulfate (plus other reaction by-products as sulfite and sulfate) formed by reacting calcium hydroxide with elemental sulfur, used in pest control. It can be prepared by boiling in water a suspension of poorly soluble calcium hydroxide (lime) and solid sulfur together with a small amount of surfactant to facilitate the dispersion of these solids in water. After elimination of residual solids (flocculation, decantation, and filtration), it is normally used as an aqueous solution, which is reddish-yellow in colour and has a distinctive offensive odor of hydrogen sulfide (H2S, rotten eggs).

<span class="mw-page-title-main">Carbon dioxide scrubber</span> Device which absorbs carbon dioxide from circulated gas

A carbon dioxide scrubber is a piece of equipment that absorbs carbon dioxide (CO2). It is used to treat exhaust gases from industrial plants or from exhaled air in life support systems such as rebreathers or in spacecraft, submersible craft or airtight chambers. Carbon dioxide scrubbers are also used in controlled atmosphere (CA) storage and carbon capture and storage processes.

<span class="mw-page-title-main">Concrete degradation</span> Damage to concrete affecting its mechanical strength and its durability

Concrete degradation may have many different causes. Concrete is mostly damaged by the corrosion of reinforcement bars due to the carbonatation of hardened cement paste or chloride attack under wet conditions. Chemical damage is caused by the formation of expansive products produced by chemical reactions, by aggressive chemical species present in groundwater and seawater, or by microorganisms Other damaging processes can also involve calcium leaching by water infiltration, physical phenomena initiating cracks formation and propagation, fire or radiant heat, aggregate expansion, sea water effects, leaching, and erosion by fast-flowing water.

<span class="mw-page-title-main">Base anhydride</span>

A base anhydride is an oxide of a chemical element from group 1 or 2. They are obtained by removing water from the corresponding hydroxide base. If water is added to a base anhydride, a corresponding hydroxide salt can be [re]-formed.

References

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