Green liquor

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Green liquor is the dissolved smelt of sodium carbonate, sodium sulfide and other compounds from the recovery boiler in the kraft process. The liquor's eponymous green colour arises from the presence of colloidal iron sulfide. [1]

The green liquor is usually reacted with lime (CaO) in the causticizing stage to regenerate white liquor. Alternatively, green liquor can be used prior to white liquor to extract some hemicellulose.

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White liquor is a strongly alkaline solution mainly of sodium hydroxide and sodium sulfide. It is used in the first stage of the Kraft process in which lignin and hemicellulose are separated from cellulose fiber for the production of pulp. The white liquor breaks the bonds between lignin and cellulose. It is called white liquor due to its white opaque colour.

References

  1. Giddings, J.F.; Roll, D.R.; Cappellino, C.A.; Day, M.; Nardone, R.A. (2008). "12.12.4.". In Karassik, I.; Messina, J.; Cooper, P.; Heald, C. (eds.). Pump Handbook (4th ed.). New York: McGraw Hill. ISBN   978-0-07-146044-6 . Retrieved February 21, 2013.