Paper chemicals designate a group of chemicals that are used for paper manufacturing, or modify the properties of paper. These chemicals can be used to alter the paper in many ways, including changing its color and brightness, or by increasing its strength and resistance to water. [1] The chemicals can be defined on basis of their usage in the process.
Chemical usage is not only for imparting properties to paper but to handle the water cycles in the process, conditioning of fabrics, cleaning of equipment and several other applications.
Common name | Scientific name | Chemical formula | Notes |
---|---|---|---|
Alum | "Sulfate of alumina" | Al2(SO4)3· 18 H2O | For alkaline sizing along with rosin[ clarification needed ] |
Albarine | "Calcium sulfate" | CaSO4· 2 H2O | Building materials |
Chlorine dioxide | Chlorine dioxide | Cl O 2 | Pulp bleaching |
Chlorine | Chlorine | Cl2 | Pulp bleaching |
Dolomite | Calcium magnesium carbonate | CaMg(CO3)2 | Filler, Coating |
DTPA | Diethylenetriaminepentaacetic acid | C 14 H 33 N 3 O 10 | Used for chelation (removal of transition metals from pulp). |
EDTA | Ethylenediaminetetraacetic acid | C10H16N2O8 | Used for chelation (removal of transition metals from pulp). |
Enzyme [ which? ] | Used in deinking | ||
FSA | Formamidine Sulfuric acid or Thiourea dioxide | CH4N2SO2 | Post deinking bleaching |
Guar gum | Natural polymer; no systematic name | Dry strength additive | |
Gypsum or mineral white or plaster | Calcium sulfate | Ca SO4 · 2 H2O | Gypsum board |
Hydrogen peroxide | Hydrogen peroxide | H 2 O 2 | In pulp bleaching |
Hypochlorous acid | Hypochlorous acid | HOCl | In pulp bleaching |
Lime | Calcium oxide | Ca O | Alkaline pulping process chemical recovery, bleaching |
Limestone | Calcium carbonate | CaCO3 | To make precipitated CaCO3, is used as filler and in coating |
Magnesium bisulfite | Magnesium bisulfite | Mg(HSO3)2 | Used in sulfite pulping |
Magnesite | Magnesium carbonate | MgCO3 -100% | Filler for cigarette paper |
Milk of Lime | Calcium hydroxide | Ca(OH)2 | For causticizing of green liquor |
Milk of Magnesia | Magnesium hydroxide | Mg(OH)2 | |
Oxygen | Oxygen | O2 | In pulp bleaching |
Ozone | Ozone | O3 | In pulp bleaching |
Rosin | Abietic acid | C19H29 COOH | Sizing |
Rosin Soap | Sodium abietate | C19H29COONa | Sizing |
Salt Cake | Sodium sulfate | Na2SO410H2O | Makeup chemical in sulfate pulping chemical recovery (Na2SO4. ---Na2S) |
Soap / fatty acid | Deinking | ||
Sodium bisulfite | Sodium bisulfite | NaHSO3 | Used in sulfite pulping |
Soda ash | Sodium carbonate | Na2CO3 | Makeup chemical in alkaline pulping chemical recovery (Na2CO3+Ca(OH)2---2NaOH+CaCO3) |
Sodium aluminate | Sodium aluminate | Na 2 Al 2 O 4 | Used in conjunction with alum to control pH |
Sodium bisulfite | Sodium bisulfite | NaHSO3 | An acid type cooking liquor chemical component sometimes used to neutralized residual chlorine in the pulp during the bleaching process. |
Sodium chlorate | Sodium chlorate | NaClO3 | Used to generate Chlorine Dioxide |
Sodium dithionite | Sodium hydrosulfite | Na 2 S 2 O 4 | Bleaching |
Sodium hypochlorite | Sodium hypochlorite | Na O Cl | Bleaching |
Sodium peroxide | Sodium peroxide | Na 2 O 2 | Bleaching |
Sodium silicate | Sodium silicate | Na2SiO3 | In waste paper deinking for wetting, peptization, ink dispersion, peroxide stabilization. |
Sodium sulfide | Sodium sulfide | Na 2 S | Active chemical in kraft/sulfate cooking liquor |
Sodium thiosulfate | Sodium thiosulfate | Na 2 S 2 O 3 | Bleaching |
Sodium tripolyphosphate | Sodium tripolyphosphate | Na 5 P 3 O 10 | Dispersant |
Starch | Wet and dry end additive | Consists of glucose units linked together by oxygen bridges called glycosides | |
Sulfur | Sulfur | S | To make HSO3f or bi-sulfite pulping |
Surfactant | Used in deinking. Used as debonders in fluff pulp manufacture. | ||
Titania | Titanium dioxide | TiO2 | Filler to increase the opacity and brightness of paper. Used in coating. |
Anatase | Titanium dioxide | TiO2 |
Chemical pulping involves dissolving lignin in order to extract the cellulose from the wood fiber. The different processes of chemical pulping include the Kraft process, which uses caustic soda and sodium sulfide and is the most common; alternatively, the use of sulfurous acid is known as the sulfite process, the neutral sulfite semichemical is treated as a third process separate from sulfite, and soda pulping which is the least ecologically hazardous utilizing sodium hydroxide or anthraquinone. [2]
Caustic soda is added to increase the pH in the pulping process of fibers. The higher pH of the paper-fiber solution causes the fibers to smoothen and swell, which is important for the grinding process of the fibers.
In the production of white paper, the wood pulp is bleached to remove any color from the trace amounts of lignin that was not extracted in the chemical pulping process. There are three predominant methods of bleaching:
Most paper types must have some water-resistance to maintain a specific writing quality and printability. Until 1980, the typical manner of adding this resistance was by using a rosin in combination with alum. When the paper industry started using chalk instead of china clay as filler, the paper chemistry had to switch to a neutral process. At several places AKD (alkyl ketene dimer) and ASA (alkenyl succinic anhydride) are used. Latest development is to use surface size, [5] which is applied using a size press. The advantage of surface sizing is that it does not interfere with the backend water chemistry.
Wet-strength additives ensure that paper retains its strength when it gets wet. This is especially important in tissue paper. Chemicals typically used for this purpose include epichlorohydrin, melamine, urea formaldehyde and polyimines. These substances polymerize in the paper and result in the construction of a strengthening network.
To enhance the paper's strength, cationic starch is added to wet pulp in the manufacturing process. Starch has a similar chemical structure as the cellulose fibre of the pulp, and the surface of both the starch and fibre are negatively charged. By adding cationic (positive charged) starch, the fibre can bind with the starch and thus also increase the interconnections between the fibres. The positively charged portion of the starch is usually formed by quaternary ammonium cations. Quaternary salts that are used include 2.3-epoxy propyl trimethyl ammoniumchloride (EPTAC, also known as or Glytac Quab, GMAC™) and (3-chloro-2-hydroxypropyl) trimethyl ammonium chloride (CHPTAC, also known as Quat 188, Quab 188, Reagens™).
Dry-strength additives, or dry-strengthening agents, are chemicals that improve paper strength normal conditions. These improve the paper's compression strength, bursting strength, tensile breaking strength, and delamination resistance. Typical chemicals used include cationic starch and polyacrylamide (PAM) derivatives. These substances work by binding fibers, often under the aid of aluminum ions in paper sheet.
Binders promote the binding of pigment particles between themselves and the coating layer of the paper. [6] Binders are spherical particles less than 1 μm in diameter. Common binders are styrene maleic anhydride copolymer or styrene-acrylate copolymer. [7] The surface chemical composition is differentiated by the adsorption of acrylic acid or an anionic surfactant, both of which are used for stabilization of the dispersion in water. [8] Co-binders, or thickeners, are generally water-soluble polymers that influence the paper's color viscosity, water retention, sizing, and gloss. Some common examples are carboxymethyl cellulose (CMC), cationic and anionic hydroxyethyl cellulose (EHEC), modified starch, and dextrin. Styrene butadiene latex, Styrene acrylic, dextrin, oxidized starch are used in coatings to bind the filler to the paper. Co-binders are natural products such as starch and CMC (Carboxymethyl cellulose), that are used along with the synthetic binders, like styrene acrylic or styrene butadiene. Co-binders are used to reduce the cost of the synthetic binder and improve the water retention and rheology of the coating.
Mineral fillers are used to lower the consumption of more expensive binder material or to improve some properties of the paper. [9] China clay, calcium carbonate, titanium dioxide, and talc are common mineral fillers used in paper production.[ citation needed ]
A Retention agent is added to bind fillers to the paper. Fillers, such as calcium carbonate, usually have a weak surface charge. The retention agent is a polymer with high cationic, positively charged groups. An additional feature of a retention agent is to accelerate the dewatering in the wire section of the paper machine. Polyethyleneimine and polyacrylamide are examples of chemicals used in this process.[ citation needed ]
Pigments that absorb in the yellow and red part of the visible spectrum can be added. As the dye absorbs light, the brightness of the paper will decrease, unlike the effect of an optical-brightening agent. To increase whiteness, a combination of pigments and an optical-brightening agent are often used. The most commonly used pigments are blue and violet dyes.[ citation needed ]
Optical brightener is used to make paper appear whiter. Optical-brightening agents use fluorescence to absorb invisible radiation from the ultraviolet part of the light spectrum and re-emit the radiation as light in the visible blue range. The optical-brightening agent thus generates blue light that is added to the reflected light. The additional blue light offsets the yellowish tinge that would otherwise exist in the reflected light characteristics. It thus increases the brightness of the material (when the illumination includes ultraviolet radiation). [10]
Cellulose is an organic compound with the formula (C
6H
10O
5)
n, a polysaccharide consisting of a linear chain of several hundred to many thousands of β(1→4) linked D-glucose units. Cellulose is an important structural component of the primary cell wall of green plants, many forms of algae and the oomycetes. Some species of bacteria secrete it to form biofilms. Cellulose is the most abundant organic polymer on Earth. The cellulose content of cotton fiber is 90%, that of wood is 40–50%, and that of dried hemp is approximately 57%.
Pulp is a fibrous lignocellulosic material prepared by chemically, semi-chemically or mechanically producing cellulosic fibers from wood, fiber crops, waste paper, or rags. Mixed with water and other chemicals or plant-based additives, pulp is the major raw material used in papermaking and the industrial production of other paper products.
Paper engineering is a branch of engineering that deals with the usage of physical science and life sciences in conjunction with mathematics as applied to the converting of raw materials into useful paper products and co-products. The field applies various principles in process engineering and unit operations to the manufacture of paper, chemicals, energy and related materials. The following timeline shows some of the key steps in the development of the science of chemical and bioprocess engineering:
Paperboard is a thick paper-based material. While there is no rigid differentiation between paper and paperboard, paperboard is generally thicker than paper and has certain superior attributes such as foldability and rigidity. According to ISO standards, paperboard is a paper with a grammage above 250 g/m2, but there are exceptions. Paperboard can be single- or multi-ply.
A paper machine is an industrial machine which is used in the pulp and paper industry to create paper in large quantities at high speed. Modern paper-making machines are based on the principles of the Fourdrinier Machine, which uses a moving woven mesh to create a continuous paper web by filtering out the fibres held in a paper stock and producing a continuously moving wet mat of fibre. This is dried in the machine to produce a strong paper web.
Sizing or size is a substance that is applied to, or incorporated into, other materials—especially papers and textiles—to act as a protective filler or glaze. Sizing is used in papermaking and textile manufacturing to change the absorption and wear characteristics of those materials.
The kraft process (also known as kraft pulping or sulfate process) is a process for conversion of wood into wood pulp, which consists of almost pure cellulose fibres, the main component of paper. The kraft process involves treatment of wood chips with a hot mixture of water, sodium hydroxide (NaOH), and sodium sulfide (Na2S), known as white liquor, that breaks the bonds that link lignin, hemicellulose, and cellulose. The technology entails several steps, both mechanical and chemical. It is the dominant method for producing paper. In some situations, the process has been controversial because kraft plants can release odorous products and in some situations produce substantial liquid wastes.
A binder or binding agent is any material or substance that holds or draws other materials together to form a cohesive whole mechanically, chemically, by adhesion or cohesion.
A pulp mill is a manufacturing facility that converts wood chips or other plant fiber sources into a thick fiber board which can be shipped to a paper mill for further processing. Pulp can be manufactured using mechanical, semi-chemical, or fully chemical methods. The finished product may be either bleached or non-bleached, depending on the customer requirements.
Laundry detergent is a type of detergent used for cleaning dirty laundry (clothes). Laundry detergent is manufactured in powder and liquid form.
Kraft paper or kraft is paper or paperboard (cardboard) produced from chemical pulp produced in the kraft process.
Inkjet paper is a special fine paper designed for inkjet printers, typically classified by its weight, brightness and smoothness, and sometimes by its opacity.
Bleaching of wood pulp is the chemical processing of wood pulp to lighten its color and whiten the pulp. The primary product of wood pulp is paper, for which whiteness is an important characteristic. These processes and chemistry are also applicable to the bleaching of non-wood pulps, such as those made from bamboo or kenaf.
The sulfite process produces wood pulp that is almost pure cellulose fibers by treating wood chips with solutions of sulfite and bisulfite ions. These chemicals cleave the bonds between the cellulose and lignin components of the lignocellulose. A variety of sulfite/bisulfite salts are used, including sodium (Na+), calcium (Ca2+), potassium (K+), magnesium (Mg2+), and ammonium (NH4+). The lignin is converted to lignosulfonates, which are soluble and can be separated from the cellulose fibers. For the production of cellulose, the sulfite process competes with the Kraft process which produces stronger fibers and is less environmentally costly.
Dissolving pulp, also called dissolving cellulose, is bleached wood pulp or cotton linters that has a high cellulose content. It has special properties including a high level of brightness and uniform molecular-weight distribution. This pulp is manufactured for uses that require a high chemical purity, and particularly low hemicellulose content, since the chemically similar hemicellulose can interfere with subsequent processes. Dissolving pulp is so named because it is not made into paper, but dissolved either in a solvent or by derivatization into a homogeneous solution, which makes it completely chemically accessible and removes any remaining fibrous structure. Once dissolved, it can be spun into textile fibers, or chemically reacted to produce derivatized celluloses, such cellulose triacetate, a plastic-like material formed into fibers or films, or cellulose ethers such as methyl cellulose, used as a thickener.
The wet strength of paper and paperboard is a measure of how well the web of fibers holding the paper together can resist a force of rupture when the paper is wet. Wet strength is routinely expressed as the ratio of wet to dry tensile force at break.
Nanocellulose is a term referring to a familly of cellulosic materials that have at least one of their dimensions in the nanoscale. Examples of nanocellulosic materials are microfibrilated cellulose, cellulose nanofibers or cellulose nanocrystals. Nanocellulose may be obtained from natural cellulose fibers through different production processes. This family of materials possess various interesting properties for a wide range of potential applications.
Wet Processing Engineering is one of the major streams in Textile Engineering or Textile manufacturing which refers to the engineering of textile chemical processes and associated applied science. The other three streams in textile engineering are yarn engineering, fabric engineering, and apparel engineering. The processes of this stream are involved or carried out in an aqueous stage. Hence, it is called a wet process which usually covers pre-treatment, dyeing, printing, and finishing.
The surface chemistry of paper is responsible for many important paper properties, such as gloss, waterproofing, and printability. Many components are used in the paper-making process that affect the surface.
Alkenyl succinic anhydrides (ASA) are derivatives of succinic anhydrides. One H of the succinic anhydride ring is replaced with an iso-alkenyl chain (C14 to C22). ASA's are colorless and usually viscous liquids. They are widely used, especially in surface sizing of paper, paperboard, and cardboard, as well as in the hydrophobicization of cellulose fibers. Products treated with it show reduced penetration of aqueous media, such as inks or drinks (like milk or fruit juices).
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