Modified starch

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Pack of modified food starch, a food additive which is prepared by treating starch or starch granules. Modified food starch.JPG
Pack of modified food starch, a food additive which is prepared by treating starch or starch granules.

Modified starch, also called starch derivatives , is prepared by physically, enzymatically, or chemically treating native starch to change its properties. [1] Modified starches are used in practically all starch applications, such as in food products as a thickening agent, stabilizer or emulsifier; in pharmaceuticals as a disintegrant; or as binder in coated paper. They are also used in many other applications. [2]

Contents

Starches are modified to enhance their performance in different applications. Starches may be modified to increase their stability against excessive heat, acid, shear, time, cooling, or freezing, to change their texture, to decrease or increase their viscosity, to lengthen or shorten gelatinization time or to increase their visco-stability.

Modification methods

starch acetate Starkeacetat.png
starch acetate
hydroxypropylated starch Hydroxypropylstarke.png
hydroxypropylated starch
cationic starch Kationische Starke.png
cationic starch
carboxymethylated starch Carboxymethylstarke.png
carboxymethylated starch

An ancient way of modifying starch is malting grain, which humans have done for thousands of years. The plant's own enzymes modify the grain's starches. The effects can be modulated by varying the duration and the ambient conditions of the process. However, malting alone is not a limitless or optimized tool for every desirable end product. In recent centuries, humans have expanded their repertoire of starch-modifying methods by learning how to use simple substances such as acids, alkalis, and enzymes from nature to modify starches in tailored ways.

Acid-treated starch (INS 1401), [3] also called thin boiling starch, is prepared by treating starch or starch granules with inorganic acids, e.g. hydrochloric acid (equivalent to stomach acid), breaking down the starch molecule and thus reducing the viscosity.

Other treatments producing modified starch (with different INS and E-numbers) are:

and combined modifications such as

Modified starch may also be a cold-water-soluble, pregelatinized or instant starch which thickens and gels without heat, or a cook-up starch which must be cooked like regular starch. Drying methods to make starches cold-water-soluble are extrusion, drum drying, spray drying or dextrinization.

Other starch derivatives, the starch sugars, like glucose, high fructose syrup, glucose syrups, maltodextrins, starch degraded with amylase enzyme are mainly sold as liquid syrup to make a sweetener.

Examples of use and functionality of modified starch

Pre-gelatinized starch is used to thicken instant desserts, allowing the food to thicken with the addition of cold water or milk.[ citation needed ] Similarly, cheese sauce granules such as in Macaroni and Cheese, lasagna, or gravy granules may be thickened with boiling water without the product going lumpy. Commercial pizza toppings containing modified starch will thicken when heated in the oven, keeping them on top of the pizza, and then become runny when cooled. [4]

A suitably modified starch is used as a fat substitute for low-fat versions of traditionally fatty foods, [5] e.g. industrial milk-based desserts like yogurt [6] or reduced-fat hard salami [7] having about 1/3 the usual fat content. For the latter type of uses, it is an alternative to the product Olestra.

Modified starch is added to frozen products to prevent them from dripping when defrosted. Modified starch, bonded with phosphate, allows the starch to absorb more water and keeps the ingredients together. [8] Modified starch acts as an emulsifier for French dressing by enveloping oil droplets and suspending them in the water. Acid-treated starch forms the shell of jelly beans. Oxidized starch increases the stickiness of batter.

Carboxymethylated starches are used as a wallpaper adhesive, as textile printing thickener, as tablet disintegrants and excipients in the pharmaceutical industry.

Cationic starch is used as wet end sizing agent in paper manufacturing.

Genetically modified starch

Modified starch should not be confused with genetically modified starch, which refers to starch from genetically engineered plants, such as those that have been genetically modified to produce novel fatty acids or carbohydrates which might not occur in the plant species being harvested. In Europe the term "Genetically Modified Organism" is used solely where "the genetic material has been altered in a way that does not occur naturally through fertilisation and/or natural recombination". [9] The modification in "genetically modified" refers to the genetic engineering of the plant DNA, whereas in the term "Modified Starch" seen on mandatory ingredient labels it refers to the later processing or treatment of the starch or starch granules.

Genetically modified starch is of interest in the manufacture of biodegradable polymers and noncellulose feedstock in the paper industry, as well as the creation of new food additives. For example, researchers aim to alter the enzymes within living plants to create starches with desirable modified properties, and thus eliminate the need for enzymatic processing after starch is extracted from the plant. [10]

See also

Related Research Articles

<span class="mw-page-title-main">Starch</span> Glucose polymer used as energy store in plants

Starch or amylum is a polymeric carbohydrate consisting of numerous glucose units joined by glycosidic bonds. This polysaccharide is produced by most green plants for energy storage. Worldwide, it is the most common carbohydrate in human diets, and is contained in large amounts in staple foods such as wheat, potatoes, maize (corn), rice, and cassava (manioc).

<span class="mw-page-title-main">Angel food cake</span> Type of sponge cake

Angel food cake, or angel cake, is a type of sponge cake made with egg whites, flour, and sugar. A whipping agent, such as cream of tartar, is commonly added. It differs from other cakes because it uses no butter. Its aerated texture comes from whipped egg white. Angel food cake originated in the United States and first became popular in the late 19th century. It gained its unique reputation along with its name due to its light and fluffy texture and white color.

<span class="mw-page-title-main">Dextrin</span> Chemical compound

Dextrins are a group of low-molecular-weight carbohydrates produced by the hydrolysis of starch and glycogen. Dextrins are mixtures of polymers of D-glucose units linked by α-(1→4) or α-(1→6) glycosidic bonds.

<span class="mw-page-title-main">Cheez Whiz</span> Trademarked processed cheese dip

Cheez Whiz is a brand of processed cheese sauce and spread produced by Kraft Foods. It was developed by a team led by food scientist Edwin Traisman (1915–2007). It was first sold in 1952, and, with some changes in formulation, continues to be in production today.

<span class="mw-page-title-main">Maltodextrin</span> Polysaccharide of glucose

Maltodextrin is a name shared by two different families of chemicals. Both families are glucose polymers, but have little chemical or nutritional similarity.

Starch gelatinization is a process of breaking down of intermolecular bonds of starch molecules in the presence of water and heat, allowing the hydrogen bonding sites to engage more water. This irreversibly dissolves the starch granule in water. Water acts as a plasticizer.

<span class="mw-page-title-main">Glucose syrup</span> Syrup made from the hydrolysis of starch

Glucose syrup, also known as confectioner's glucose, is a syrup made from the hydrolysis of starch. Glucose is a sugar. Maize (corn) is commonly used as the source of the starch in the US, in which case the syrup is called "corn syrup", but glucose syrup is also made from potatoes and wheat, and less often from barley, rice and cassava.p. 21

<span class="mw-page-title-main">Easy Cheese</span> Canned processed cheese product

Easy Cheese is the trademark for a processed cheese spread product distributed by Mondelēz International. It is also commonly referred to by generic terms such as "spray cheese", "squirt cheese", "cheese in a can", and/or "cheese cans". Easy Cheese is packaged in a metal can filled with air covered with a plastic cap that reveals a straight, flexible nozzle where the cheese is extruded.

<span class="mw-page-title-main">Thickening agent</span> Increases the viscosity of a liquid without altering its other properties

A thickening agent or thickener is a substance which can increase the viscosity of a liquid without substantially changing its other properties. Edible thickeners are commonly used to thicken sauces, soups, and puddings without altering their taste; thickeners are also used in paints, inks, explosives, and cosmetics.

<span class="mw-page-title-main">Carboxymethyl cellulose</span> Cellulose derivative grafted with carboxymethyl groups

Carboxymethyl cellulose (CMC) or cellulose gum is a cellulose derivative with carboxymethyl groups (-CH2-COOH) bound to some of the hydroxyl groups of the glucopyranose monomers that make up the cellulose backbone. It is often used in its sodium salt form, sodium carboxymethyl cellulose. It used to be marketed under the name Tylose, a registered trademark of SE Tylose.

<span class="mw-page-title-main">Dough conditioner</span> Substance added to bread dough to strengthen its texture

A dough conditioner, flour treatment agent, improving agent or bread improver is any ingredient or chemical added to bread dough to strengthen its texture or otherwise improve it in some way. Dough conditioners may include enzymes, yeast nutrients, mineral salts, oxidants and reductants, bleaching agents and emulsifiers. They are food additives combined with flour to improve baking functionality. Flour treatment agents are used to increase the speed of dough rising and to improve the strength and workability of the dough.

<span class="mw-page-title-main">Acetylated distarch adipate</span> Chemical compound

Acetylated distarch adipate (E1422) is a food additive of the thickening agent type, and more specifically a bulking agent. It is also used as a stabilizer. This is an additive belonging to the family of modified starches.

<span class="mw-page-title-main">Potato starch</span> Thickening agent used for culinary purposes

Potato starch is starch extracted from potatoes. The cells of the root tubers of the potato plant contain leucoplasts. To extract the starch, the potatoes are crushed, and the starch grains are released from the destroyed cells. The starch is then left to settle out of solution or separated by hydrocyclones, then dried to powder.

<span class="mw-page-title-main">Instant noodles</span> Noodles sold in a precooked and dried block with flavoring

Instant noodles, or instant ramen, is a type of food consisting of noodles sold in a precooked and dried block with flavoring powder and/or seasoning oil. The dried noodle block was originally created by flash-frying cooked noodles, which is still the main method used in Asian countries; air-dried noodle blocks are favored in Western countries. Dried noodle blocks are designed to be cooked or soaked in boiling water before eating. Ramen, a Japanese adaptation of Chinese noodle soup, is sometimes used as a descriptor for instant noodle flavors by some Japanese manufacturers. It has become synonymous in the United States with all instant noodle products.

<span class="mw-page-title-main">Sour cream</span> Fermented dairy product

Sour cream is a dairy product obtained by fermenting regular cream with certain kinds of lactic acid bacteria. The bacterial culture, which is introduced either deliberately or naturally, sours and thickens the cream. Its name comes from the production of lactic acid by bacterial fermentation, which is called souring. Crème fraîche is one type of sour cream with a high fat content and less sour taste.

Monostarch phosphate, E1410 in the E number scheme of food additives, is a modified starches. These are not absorbed intact by the gut, but are significantly hydrolysed by intestinal enzymes and then fermented by intestinal microbiota.

Distarch phosphate, E1412 in the E number scheme of food additives, is a modified starch. These are not absorbed intact by the gut, but are significantly hydrolysed by intestinal enzymes and then fermented by intestinal microbiota.

Acetylated distarch phosphate, E1414 in the E number scheme of food additives, is a modified starch. These are not absorbed intact by the gut, but are significantly hydrolysed by intestinal enzymes and then fermented by intestinal microbiota.

Hydroxypropyl starch is a type of modified starch used as a food additive. I has the E number E1440. Hydroxyl propyl starch is not absorbed intact by the gut, but are significantly hydrolyzed by intestinal enzymes and then fermented by intestinal microbiota.

References

  1. Vickie Vaclavik; Vickie A. Vaclavik; Elizabeth W. Christian (2007). Essentials of food science (3rd ed.). Springer. p. 61. ISBN   978-0-387-69939-4.
  2. Starch derivatization: fascinating and unique industrial opportunities, K. F. Gotlieb, A. Capelle, Wageningen Academic Publishers, 2005, ISBN   978-90-76998-60-2
  3. 1 2 3 4 5 6 7 8 "Codex General Standard for Food Additives (GSFA) Online Database" (PDF).
  4. Zhang, Honghong; Fan, Haoran; Xu, Xueming; Xu, Dan (January 2024). "Deterioration mechanisms and quality improvement methods in frozen dough: An updated review". Trends in Food Science and Technology . 143 via Science Direct.
  5. Lin, Qianzhu; Jiang, Ling; Li, Xiaojing; Sang, Shangyuan; Ji, Hangyan; Jin, Zhengyu; Qiu, Chao (June 2024). "Starch based fat replacers in food system: Modification, structured design, and application". Food Bioscience. 59 via Science Direct.
  6. He, Jun; Han, Yumei; Liu, Min; Wang, Yanan; Yang, Yang; Yang, Xujin (2019). "Effect of 2 types of resistant starches on the quality of yogurt". Inner Mongolia Agricultural University . 102:3956 (3964): 8 via American Dairy Science Association.
  7. Skrede, G (1989). "Comparison of various types of starch when used in meat sausages". Meat Science. 25 (1): 21–36 via PubMed.
  8. Ačkar, Đurđica; Grec, Marijana; Grgić, Ivanka; Gryszkin, Artur; Styczyńska, Marzena; Jozinović, Antun; Miličević, Borislav; Šubarić, Drago; Babić, Jurislav (August 17, 2022). "Physical Properties of Starches Modified by Phosphorylation and High-Voltage Electrical Discharge (HVED)". Polymers . 14 (16): 3359 via PubMed.
  9. "GMO". European food Standards Agency. 24 April 2013.
  10. Zeeman, Samuel C.; Kossmann, Jens; Smith, Alison M. (2 June 2010). "Starch: Its Metabolism, Evolution, and Biotechnological Modification in Plants". Annual Review of Plant Biology. 61 (1): 209–234. doi:10.1146/annurev-arplant-042809-112301. PMID   20192737 . Retrieved 16 July 2021.

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