Cellulose is an organic compound with the formula (C
6H
10O
5)
n, a polysaccharide consisting of a linear chain of several hundred to many thousands of β(1→4) linked D-glucose units. Cellulose is an important structural component of the primary cell wall of green plants, many forms of algae and the oomycetes. Some species of bacteria secrete it to form biofilms. Cellulose is the most abundant organic polymer on Earth. The cellulose content of cotton fiber is 90%, that of wood is 40–50%, and that of dried hemp is approximately 57%.
Lignin is a class of complex organic polymers that form key structural materials in the support tissues of most plants. Lignins are particularly important in the formation of cell walls, especially in wood and bark, because they lend rigidity and do not rot easily. Chemically, lignins are polymers made by cross-linking phenolic precursors.
Pulp is a lignocellulosic fibrous material prepared by chemically or mechanically separating cellulose fibers from wood, fiber crops, waste paper, or rags. Mixed with water and other chemical or plant-based additives, pulp is the major raw material used in papermaking and the industrial production of other paper products.
A paper machine is an industrial machine which is used in the pulp and paper industry to create paper in large quantities at high speed. Modern paper-making machines are based on the principles of the Fourdrinier Machine, which uses a moving woven mesh to create a continuous paper web by filtering out the fibres held in a paper stock and producing a continuously moving wet mat of fibre. This is dried in the machine to produce a strong paper web.
Lyocell is a semi-synthetic fiber used to make textiles for clothing and other purposes. It is a form of regenerated cellulose made by dissolving pulp and dry jet-wet spinning. Unlike rayon made by some of the more common viscose processes, Lyocell production does not use carbon disulfide, which is toxic to workers and the environment. Lyocell was originally trademarked as Tencel in 1982.
Bagasse is the dry pulpy fibrous material that remains after crushing sugarcane or sorghum stalks to extract their juice. It is used as a biofuel for the production of heat, energy, and electricity, and in the manufacture of pulp and building materials. Agave bagasse is similar, but is the material remnants after extracting blue agave sap.
The kraft process (also known as kraft pulping or sulfate process) is a process for conversion of wood into wood pulp, which consists of almost pure cellulose fibres, the main component of paper. The kraft process involves treatment of wood chips with a hot mixture of water, sodium hydroxide (NaOH), and sodium sulfide (Na2S), known as white liquor, that breaks the bonds that link lignin, hemicellulose, and cellulose. The technology entails several steps, both mechanical and chemical. It is the dominant method for producing paper. In some situations, the process has been controversial because kraft plants can release odorous products and in some situations produce substantial liquid wastes.
A pulp mill is a manufacturing facility that converts wood chips or other plant fiber sources into a thick fiber board which can be shipped to a paper mill for further processing. Pulp can be manufactured using mechanical, semi-chemical, or fully chemical methods. The finished product may be either bleached or non-bleached, depending on the customer requirements.
In industrial chemistry, black liquor is the by-product from the kraft process when digesting pulpwood into paper pulp removing lignin, hemicelluloses and other extractives from the wood to free the cellulose fibers.
Kraft paper or kraft is paper or paperboard (cardboard) produced from chemical pulp produced in the kraft process.
A biocomposite is a composite material formed by a matrix (resin) and a reinforcement of natural fibers. Environmental concern and cost of synthetic fibres have led the foundation of using natural fibre as reinforcement in polymeric composites. The matrix phase is formed by polymers derived from renewable and nonrenewable resources. The matrix is important to protect the fibers from environmental degradation and mechanical damage, to hold the fibers together and to transfer the loads on it. In addition, biofibers are the principal components of biocomposites, which are derived from biological origins, for example fibers from crops, recycled wood, waste paper, crop processing byproducts or regenerated cellulose fiber (viscose/rayon). The interest in biocomposites is rapidly growing in terms of industrial applications and fundamental research, due to its great benefits. Biocomposites can be used alone, or as a complement to standard materials, such as carbon fiber. Advocates of biocomposites state that use of these materials improve health and safety in their production, are lighter in weight, have a visual appeal similar to that of wood, and are environmentally superior.
The sulfite process produces wood pulp that is almost pure cellulose fibers by treating wood chips with solutions of sulfite and bisulfite ions. These chemicals cleave the bonds between the cellulose and lignin components of the lignocellulose. A variety of sulfite/bisulfite salts are used, including sodium (Na+), calcium (Ca2+), potassium (K+), magnesium (Mg2+), and ammonium (NH4+). The lignin is converted to lignosulfonates, which are soluble and can be separated from the cellulose fibers. For the production of cellulose, the sulfite process competes with the Kraft process which produces stronger fibers and is less environmentally costly.
Dissolving pulp, also called dissolving cellulose, is bleached wood pulp or cotton linters that has a high cellulose content. It has special properties including a high level of brightness and uniform molecular-weight distribution. This pulp is manufactured for uses that require a high chemical purity, and particularly low hemicellulose content, since the chemically similar hemicellulose can interfere with subsequent processes. Dissolving pulp is so named because it is not made into paper, but dissolved either in a solvent or by derivatization into a homogeneous solution, which makes it completely chemically accessible and removes any remaining fibrous structure. Once dissolved, it can be spun into textile fibers, or chemically reacted to produce derivatized celluloses, such cellulose triacetate, a plastic-like material formed into fibers or films, or cellulose ethers such as methyl cellulose, used as a thickener.
Cellulose fibers are fibers made with ethers or esters of cellulose, which can be obtained from the bark, wood or leaves of plants, or from other plant-based material. In addition to cellulose, the fibers may also contain hemicellulose and lignin, with different percentages of these components altering the mechanical properties of the fibers.
Bioproducts or bio-based products are materials, chemicals and energy derived from renewable biological material.
Wood-free paper is paper created exclusively from chemical pulp rather than mechanical pulp. Chemical pulp is normally made from pulpwood, but is not considered wood as most of the lignin is removed and separated from the cellulose fibers during processing, whereas mechanical pulp retains most of its wood components and can therefore still be described as wood. Wood-free paper is not as susceptible to yellowing as paper containing mechanical pulp. Wood-free paper offers several environmental and economic benefits, including reduced deforestation, decreased energy consumption, and improved waste management. The term Wood-free paper can be rather misleading or confusing for someone unfamiliar with the papermaking process because paper is normally made from wood pulp derived from trees and shrubs. However, wood free paper does not mean that the paper in question is not made from wood pulp but it means that the lignin in the wood fiber has been removed by a chemical process.
Paper chemicals designate a group of chemicals that are used for paper manufacturing, or modify the properties of paper. These chemicals can be used to alter the paper in many ways, including changing its color and brightness, or by increasing its strength and resistance to water. The chemicals can be defined on basis of their usage in the process.
Stone paper products, also referred to as bio-plastic paper, mineral paper or rich mineral paper, are strong and durable paper-like materials manufactured from calcium carbonate bonded with high-density polyethylene (HDPE) resin. They are used in many of the same applications as cellulose-based paper.
Fibre modification is a research field in which researchers aim at developing and applying technologies to impart new properties to natural fibres such as those in paper, in order to increase their functionality. Research areas in this field include many different technologies, amongst which the chemical modifications of fibres are widely used. One important sector of application of the chemical modifications is the treatment of wood for giving it enhanced properties such as higher mechanical properties, water impermeability, less hygroscopicity, bacterial and fungal resistance. Transferring and adapting the technical knowledge on fibre modification available for the wood sector to the recycled paper sector is an innovative use of these chemical treatments which has been the subject of studies that have been carried out within an EU co-funded project called Fibre+.
Hemp paper is paper varieties consisting exclusively or to a large extent from pulp obtained from fibers of industrial hemp. The products are mainly specialty papers such as cigarette paper, banknotes and technical filter papers. Compared to wood pulp, hemp pulp offers a four to five times longer fibre, a significantly lower lignin fraction as well as a higher tear resistance and tensile strength. Because the paper industry's processes have been optimized for wood as the feedstock, production costs currently are much higher than for paper from wood.
