Wood-free paper, tree-free paper, or fine paper is paper created from bleached, chemically-separated paper pulp, as to minimize lignin contents (the "wood" in question). [1] It is not as susceptible to yellowing as paper containing mechanical pulp. [2] [3] [4]
Lignin is a natural complex polymer containing aromatic compounds that provide much of a plant's strength. In its natural form, it gives rigidity and resilience to the plant's structure, but its presence causes paper to weaken and turn yellow as it ages and eventually disintegrate. The reason for this is that as the paper ages, lignin releases acid which degrades the paper. [5] Lignocellulose from the xylem of shrubs and cambium from the inner bark of trees are made up of lignin, hemicellulose and cellulose, relevant to papermaking. [6]
Paper pulp consists of cellulosic materials that have been broken down chemically and physically and filtered and mixed in water to reform into a web: creating pulp by breaking down the materials chemically is called chemical pulping, while creating pulp by breaking them down mechanically is called mechanical pulping. [6] [7]
In the chemical pulping of lignocellulose - plants with lignin content - chemicals separate the wood fibers. The chemicals lower the lignin content because chemical action solubilizes and degrades components of wood fibers, especially hemicelluloses and lignin. Chemical pulping yields single unbroken fibers that produce strong quality papers because the lignin that interferes with hydrogen bonding of wood fibers has been removed. Chemical pulps are used to create wood free paper that is of high quality and lasts long, such as is used in arts and archiving. [6] Chemical pulping processes take place at high pressures and temperatures under aqueous alkaline, neutral or acidic conditions, with the goal of totally removing the lignin and preserving the carbohydrates. Normally, about 90% of the lignin is removed. [7]
Mechanical pulping, in contrast, converts raw lignocellulose into pulp without separating the lignin from the cellulose. [7] No chemicals other than water or steam are used. The yield is about 90% to 98%. High yields result from the fact that lignin is retained. Mechanical pulps are characterized by low cost, high stiffness, high bulk, and high yield. Mechanical pulp has low strength because the lignin interferes with hydrogen bonding between wood fibers. The lignin also makes the pulp turn yellow when exposed to light and air. Mechanical pulps are used in the production of non-permanent papers such as newsprint and magazine paper. Mechanical pulps made up 20% to 25% of the world production and this is increasing because of the high yield of the process and increasing competition for fiber resources. Advances in technology have also made mechanical pulp increasingly desirable.[ clarification needed ] [6]
Woodfree uncoated paper (WFU), uncoated woodfree paper (UWF) or uncoated fine papers is the paper industry technical term for base wood-free paper. [8] Both softwood and hardwood chemical pulps are used and a minor part of mechanical pulp might be added (often of aspen or poplar). These paper grades are calendered.[ citation needed ] The properties are good strength, high brightness and good archival characteristics. [9] They provide a non-glare surface suitable for reading and writing as there is no coating involved.[ how? ]
Offset paper is a type of woodfree uncoated paper with ISO brightness > 80% and a basis weight of 40–300 g/m2. Surface strength and low linting are the main parameters, but brightness and opacity are also important.
Lightweight offset paper, also called onionskin , has a basis weight of 25–40 g/m2 and are normally used for bibles (hence the colloquial name Bible paper) and dictionaries.
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Wood-free paper is made from a variety of raw materials, including
Wood-free paper has a number of advantages over paper that contains mechanical pulp:
Wood-free paper is used in a variety of applications:
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