Common-ion effect

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In chemistry, the common-ion effect refers to the decrease in solubility of an ionic precipitate by the addition to the solution of a soluble compound with an ion in common with the precipitate. [1] This behaviour is a consequence of Le Chatelier's principle for the equilibrium reaction of the ionic association/dissociation. The effect is commonly seen as an effect on the solubility of salts and other weak electrolytes. Adding an additional amount of one of the ions of the salt generally leads to increased precipitation of the salt, which reduces the concentration of both ions of the salt until the solubility equilibrium is reached. The effect is based on the fact that both the original salt and the other added chemical have one ion in common with each other.

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Examples of the common-ion effect

Dissociation of hydrogen sulfide in presence of hydrochloric acid

Hydrogen sulfide (H2S) is a weak electrolyte. It is partially ionized when in aqueous solution, therefore there exists an equilibrium between un-ionized molecules and constituent ions in an aqueous medium as follows:

H2S H+ + HS

By applying the law of mass action, we have

Hydrochloric acid (HCl) is a strong electrolyte, which nearly completely ionizes as

HCl → H+ + Cl

If HCl is added to the H2S solution, H+ is a common ion and creates a common ion effect. Due to the increase in concentration of H+ ions from the added HCl, the equilibrium of the dissociation of H2S shifts to the left and keeps the value of Ka constant. Thus the dissociation of H2S decreases, the concentration of un-ionized H2S increases, and as a result, the concentration of sulfide ions decreases.

Solubility of barium iodate in presence of barium nitrate

Barium iodate, Ba(IO3)2, has a solubility product Ksp = [Ba2+][IO3]2 = 1.57 x 10−9. Its solubility in pure water is 7.32 x 10−4 M. However in a solution that is 0.0200 M in barium nitrate, Ba(NO3)2, the increase in the common ion barium leads to a decrease in iodate ion concentration. The solubility is therefore reduced to 1.40 x 10−4 M, about five times smaller. [1]

Solubility effects

A practical example used very widely in areas drawing drinking water from chalk or limestone aquifers is the addition of sodium carbonate to the raw water to reduce the hardness of the water. In the water treatment process, highly soluble sodium carbonate salt is added to precipitate out sparingly soluble calcium carbonate. The very pure and finely divided precipitate of calcium carbonate that is generated is a valuable by-product used in the manufacture of toothpaste.

The salting-out process used in the manufacture of soaps benefits from the common-ion effect. Soaps are sodium salts of fatty acids. Addition of sodium chloride reduces the solubility of the soap salts. The soaps precipitate due to a combination of common-ion effect and increased ionic strength.

Sea, brackish and other waters that contain appreciable amount of sodium ions (Na+) interfere with the normal behavior of soap because of common-ion effect. In the presence of excess Na+, the solubility of soap salts is reduced, making the soap less effective.

Buffering effect

A buffer solution contains an acid and its conjugate base or a base and its conjugate acid. [2] Addition of the conjugate ion will result in a change of pH of the buffer solution. For example, if both sodium acetate and acetic acid are dissolved in the same solution they both dissociate and ionize to produce acetate ions. Sodium acetate is a strong electrolyte, so it dissociates completely in solution. Acetic acid is a weak acid, so it only ionizes slightly. According to Le Chatelier's principle, the addition of acetate ions from sodium acetate will suppress the ionization of acetic acid and shift its equilibrium to the left. Thus the percent dissociation of the acetic acid will decrease, and the pH of the solution will increase. The ionization of an acid or a base is limited by the presence of its conjugate base or acid.

NaCH3CO2(s) → Na+(aq) + CH3CO2(aq)
CH3CO2H(aq) H+(aq) + CH3CO2(aq)

This will decrease the hydronium concentration, and thus the common-ion solution will be less acidic than a solution containing only acetic acid.

Exceptions

Many transition-metal compounds violate this rule due to the formation of complex ions, a scenario not part of the equilibria that are involved in simple precipitation of salts from ionic solution. For example, copper(I) chloride is insoluble in water, but it dissolves when chloride ions are added, such as when hydrochloric acid is added. This is due to the formation of soluble CuCl2 complex ions.

Uncommon-ion effect

Sometimes adding an ion other than the ones that are part of the precipitated salt itself can increase the solubility of the salt. This "salting in" is called the "uncommon-ion effect" (also "salt effect" or the "diverse-ion effect"). It occurs because as the total ion concentration increases, inter-ion attraction within the solution can become an important factor. [3] This alternate equilibrium makes the ions less available for the precipitation reaction. This is also called odd ion effect.

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An acid is a molecule or ion capable of either donating a proton (i.e. hydrogen ion, H+), known as a Brønsted–Lowry acid, or forming a covalent bond with an electron pair, known as a Lewis acid.

<span class="mw-page-title-main">Acid–base reaction</span> Chemical reaction between an acid and a base

In chemistry, an acid–base reaction is a chemical reaction that occurs between an acid and a base. It can be used to determine pH via titration. Several theoretical frameworks provide alternative conceptions of the reaction mechanisms and their application in solving related problems; these are called the acid–base theories, for example, Brønsted–Lowry acid–base theory.

<span class="mw-page-title-main">Carbonate</span> Salt or ester of carbonic acid

A carbonate is a salt of carbonic acid, H2CO3, characterized by the presence of the carbonate ion, a polyatomic ion with the formula CO2−3. The word "carbonate" may also refer to a carbonate ester, an organic compound containing the carbonate groupO=C(−O−)2.

<span class="mw-page-title-main">Carboxylic acid</span> Organic compound containing a –C(=O)OH group

In organic chemistry, a carboxylic acid is an organic acid that contains a carboxyl group attached to an R-group. The general formula of a carboxylic acid is often written as R−COOH or R−CO2H, sometimes as R−C(O)OH with R referring to an organyl group, or hydrogen, or other groups. Carboxylic acids occur widely. Important examples include the amino acids and fatty acids. Deprotonation of a carboxylic acid gives a carboxylate anion.

<span class="mw-page-title-main">Salt (chemistry)</span> Chemical compound involving ionic bonding

In chemistry, a salt or ionic compound is a chemical compound consisting of an assembly of positively charged ions (cations) and negatively charged ions (anions), which results in a compound with no net electric charge. The constituent ions are held together by electrostatic forces termed ionic bonds.

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<span class="mw-page-title-main">Aqueous solution</span> Solution in which the solvent is water

An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, also known as sodium chloride (NaCl), in water would be represented as Na+(aq) + Cl(aq). The word aqueous means pertaining to, related to, similar to, or dissolved in, water. As water is an excellent solvent and is also naturally abundant, it is a ubiquitous solvent in chemistry. Since water is frequently used as the solvent in experiments, the word solution refers to an aqueous solution, unless the solvent is specified.

<span class="mw-page-title-main">Base (chemistry)</span> Type of chemical substance

In chemistry, there are three definitions in common use of the word "base": Arrhenius bases, Brønsted bases, and Lewis bases. All definitions agree that bases are substances that react with acids, as originally proposed by G.-F. Rouelle in the mid-18th century.

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In chemistry and biochemistry, the Henderson–Hasselbalch equation relates the pH of a chemical solution of a weak acid to the numerical value of the acid dissociation constant, Ka, of acid and the ratio of the concentrations, of the acid and its conjugate base in an equilibrium.

<span class="mw-page-title-main">Neutralization (chemistry)</span> Chemical reaction in which an acid and a base react quantitatively

In chemistry, neutralization or neutralisation is a chemical reaction in which acid and a base react with an equivalent quantity of each other. In a reaction in water, neutralization results in there being no excess of hydrogen or hydroxide ions present in the solution. The pH of the neutralized solution depends on the acid strength of the reactants.

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<span class="mw-page-title-main">Dissociation (chemistry)</span> Separation of molecules or ionic compounds into smaller constituent entities

Dissociation in chemistry is a general process in which molecules (or ionic compounds such as salts, or complexes) separate or split into other things such as atoms, ions, or radicals, usually in a reversible manner. For instance, when an acid dissolves in water, a covalent bond between an electronegative atom and a hydrogen atom is broken by heterolytic fission, which gives a proton (H+) and a negative ion. Dissociation is the opposite of association or recombination.

Acid salts are a class of salts that produce an acidic solution after being dissolved in a solvent. Its formation as a substance has a greater electrical conductivity than that of the pure solvent. An acidic solution formed by acid salt is made during partial neutralization of diprotic or polyprotic acids. A half-neutralization occurs due to the remaining of replaceable hydrogen atoms from the partial dissociation of weak acids that have not been reacted with hydroxide ions to create water molecules.

In chemistry, a strong electrolyte is a solute that completely, or almost completely, ionizes or dissociates in a solution. These ions are good conductors of electric current in the solution.

The molar conductivity of an electrolyte solution is defined as its conductivity divided by its molar concentration.

<span class="mw-page-title-main">Alkali soil</span> Soil type with pH > 8.5

Alkali, or alkaline, soils are clay soils with high pH, a poor soil structure and a low infiltration capacity. Often they have a hard calcareous layer at 0.5 to 1 metre depth. Alkali soils owe their unfavorable physico-chemical properties mainly to the dominating presence of sodium carbonate, which causes the soil to swell and difficult to clarify/settle. They derive their name from the alkali metal group of elements, to which sodium belongs, and which can induce basicity. Sometimes these soils are also referred to as alkaline sodic soils. Alkaline soils are basic, but not all basic soils are alkaline.

Acid strength is the tendency of an acid, symbolised by the chemical formula , to dissociate into a proton, , and an anion, . The dissociation or ionization of a strong acid in solution is effectively complete, except in its most concentrated solutions.

References

  1. 1 2 Skoog, Douglas A.; West, Donald M.; Holler, F. James; Crouch, Stanley R. (2014). Fundamentals of Analytical Chemistry (9th ed.). Brooks/Cole. p. 209. ISBN   978-0-495-55828-6.
  2. Mendham, J.; Denney, R. C.; Barnes, J. D.; Thomas, M. J. K. (2000), Vogel's Quantitative Chemical Analysis (6th ed.), New York: Prentice Hall, p. 28, ISBN   0-582-22628-7
  3. Claude E. Boyd (14 July 2015). Water Quality: An Introduction. Springer. pp. 56–. ISBN   978-3-319-17446-4.