Actinium(III) hydroxide

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Actinium(III) hydroxide
Names
Other names
Actinium hydroxide
Identifiers
3D model (JSmol)
  • InChI=1S/Ac.3H2O/h;3*1H2/q+3;;;/p-3
    Key: FXNGTWJQBRAZDM-UHFFFAOYSA-K
  • [Ac+3].[OH-].[OH-].[OH-]
Properties
Ac(OH)3
Appearancewhite solid
0.021 in water (20 °C)
Related compounds
Other anions
actinium(III) oxide
Other cations
scandium(III) hydroxide
yttrium(III) hydroxide
lanthanum(III) hydroxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Actinium(III) hydroxide is a white radioactive solid with the chemical formula of Ac(OH)3.

Contents

Preparation

Actinium(III) hydroxide may be formed from soluble actinium salts and alkalis or ammonia water, and the resulting gel is precipitated as the product: [1]

Ac3+ + 3 OH → Ac(OH)3

Its solubility is slightly greater than that of lanthanum hydroxide, but it is still insoluble in water.

Chemical properties

Actinium(III) hydroxide is an alkaline hydroxide, it can react with acids to obtain actinium salts: [1]

Ac(OH)3 + 3 HNO3 → Ac(NO3)3 + 3 H2O

Related Research Articles

The actinide or actinoid series encompasses the 14 metallic chemical elements with atomic numbers from 89 to 103, actinium through Lawrencium. The actinide series derives its name from the first element in the series, actinium. The informal chemical symbol An is used in general discussions of actinide chemistry to refer to any actinide.

In chemistry, an alkali is a basic, ionic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a soluble base has a pH greater than 7.0. The adjective alkaline, and less often, alkalescent, is commonly used in English as a synonym for basic, especially for bases soluble in water. This broad use of the term is likely to have come about because alkalis were the first bases known to obey the Arrhenius definition of a base, and they are still among the most common bases.

<span class="mw-page-title-main">Hydroxide</span> Chemical compound

Hydroxide is a diatomic anion with chemical formula OH. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. The corresponding electrically neutral compound HO is the hydroxyl radical. The corresponding covalently bound group –OH of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry.

<span class="mw-page-title-main">Sodium hydroxide</span> Chemical compound with formula NaOH

Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations Na+ and hydroxide anions OH.

<span class="mw-page-title-main">Iron(III)</span> The element iron in its +3 oxidation state

In chemistry, iron (III) refers to the element iron in its +3 oxidation state. In ionic compounds (salts), such an atom may occur as a separate cation (positive ion) denoted by Fe3+.

<span class="mw-page-title-main">Base (chemistry)</span> Type of chemical substance

In chemistry, there are three definitions in common use of the word "base": Arrhenius bases, Brønsted bases, and Lewis bases. All definitions agree that bases are substances that react with acids, as originally proposed by G.-F. Rouelle in the mid-18th century.

<span class="mw-page-title-main">Potassium hydroxide</span> Inorganic compound (KOH)

Potassium hydroxide is an inorganic compound with the formula KOH, and is commonly called caustic potash.

<span class="mw-page-title-main">Calcium hydroxide</span> Inorganic compound of formula Ca(OH)2

Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula Ca(OH)2. It is a colorless crystal or white powder and is produced when quicklime (calcium oxide) is mixed with water. It has many names including hydrated lime, caustic lime, builders' lime, slaked lime, cal, and pickling lime. Calcium hydroxide is used in many applications, including food preparation, where it has been identified as E number E526. Limewater, also called milk of lime, is the common name for a saturated solution of calcium hydroxide.

<span class="mw-page-title-main">Barium hydroxide</span> Chemical compound

Barium hydroxide is a chemical compound with the chemical formula Ba(OH)2. The monohydrate (x = 1), known as baryta or baryta-water, is one of the principal compounds of barium. This white granular monohydrate is the usual commercial form.

<span class="mw-page-title-main">Iron(II) hydroxide</span> Chemical compound

Iron(II) hydroxide or ferrous hydroxide is an inorganic compound with the formula Fe(OH)2. It is produced when iron(II) salts, from a compound such as iron(II) sulfate, are treated with hydroxide ions. Iron(II) hydroxide is a white solid, but even traces of oxygen impart a greenish tinge. The air-oxidised solid is sometimes known as "green rust".

<span class="mw-page-title-main">Iron(III) oxide-hydroxide</span> Hydrous ferric oxide (HFO)

Iron(III) oxide-hydroxide or ferric oxyhydroxide is the chemical compound of iron, oxygen, and hydrogen with formula FeO(OH).

Zinc hydroxide Zn(OH)2 is an inorganic chemical compound. It also occurs naturally as 3 rare minerals: wülfingite (orthorhombic), ashoverite and sweetite (both tetragonal).

<span class="mw-page-title-main">Gold(III) hydroxide</span> Chemical compound

Gold(III) hydroxide, gold trihydroxide, or gold hydroxide is an inorganic compound, a hydroxide of gold, with formula Au(OH)3. It is also called auric acid with formula H3AuO3. It is easily dehydrated above 140 °C to gold(III) oxide. Salts of auric acid are termed aurates.

Aluminium triacetate, formally named aluminium acetate, is a chemical compound with composition Al(CH
3
CO
2
)
3
. Under standard conditions it appears as a white, water-soluble solid that decomposes on heating at around 200 °C. The triacetate hydrolyses to a mixture of basic hydroxide / acetate salts, and multiple species co-exist in chemical equilibrium, particularly in aqueous solutions of the acetate ion; the name aluminium acetate is commonly used for this mixed system.

<span class="mw-page-title-main">Actinium(III) fluoride</span> Chemical compound

Actinium(III) fluoride (AcF3) is an inorganic compound, a salt of actinium and fluorine.

<span class="mw-page-title-main">Actinium(III) chloride</span> Chemical compound

Actinium(III) chloride is a chemical compound containing the rare radioactive element actinium. This salt has the formula AcCl3. Molecular weight of the compound is 333.378 g/mol.

Thorium(IV) hydroxide is an inorganic compound with a chemical formula Th(OH)4.

Scandium(III) hydroxide is an inorganic compound with the chemical formula Sc(OH)3, the trivalent hydroxide of scandium. It is an amphoteric compound. It is slightly soluble in water, and its saturated solution contains Sc(OH)3 and a small amount of Sc(OH)+2. The solubility of scandium(III) hydroxide in water is 0.0279 mol/L. It will convert to ScO(OH) after aging, greatly reducing the solubility (0.0008 mol/L). Scandium(III) hydroxide can be produced by reacting scandium salts and alkali hydroxides. In the reaction, different starting ingredients can generate different intermediates such as Sc(OH)1.75Cl1.25, Sc(OH)2NO3 and Sc(OH)2.32(SO4)0.34.

<span class="mw-page-title-main">Actinium(III) nitrate</span> Chemical compound

Actinium(III) nitrate is an inorganic compound, actinium salt of nitric acid with the chemical formula Ac(NO3)3. The compound looks like white substance, readily soluble in water.

Radium compounds are compounds containing the element radium (Ra). Due to radium's radioactivity, not many compounds have been well characterized. Solid radium compounds are white as radium ions provide no specific coloring, but they gradually turn yellow and then dark over time due to self-radiolysis from radium's alpha decay. Insoluble radium compounds coprecipitate with all barium, most strontium, and most lead compounds.

References

  1. 1 2 Tang, Renhuan; Liu, Yuanfang; Zhang, Qinglian; Zhang, Zhiyao. Series of Inorganic Chemistry. Volume 10. Actinides, Transactinides. 4.4 Actinium compounds. pp 75. ISBN   978-7-03-030572-5 (in Chinese)