Manganese(II) hydroxide

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Manganese(II) hydroxide
Names
Other names
Manganese dihydroxide, manganese hydroxide, Manganous hydroxide, Pyrochroite
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.126.826
EC Number
  • 606-171-3
PubChem CID
Properties
H2MnO2
Molar mass 88.952 g·mol−1
Appearancewhite solid
Density 3.258 g/cm3
Melting point decomposes
0.00034 g/100 mL at 18 °C. [1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Manganese(II) hydroxide is the inorganic compound with the formula Mn (OH)2. It is a white solid although samples darken quickly upon exposure to air owing to oxidation. It is poorly soluble in water.

Preparation and reactions

Manganese(II) hydroxide precipitates as a solid when an alkali metal hydroxide is added to an aqueous solution of Mn2+ salt: [2]

Mn2+ + 2 NaOH → Mn(OH)2 + 2 Na+

Manganese(II) hydroxide oxidises readily in air, as indicated by darkening of samples.

The compound adopts the brucite structure, as do several other metal dihydroxides.

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2
. This blackish or brown solid occurs naturally as the mineral pyrolusite, which is the main ore of manganese and a component of manganese nodules. The principal use for MnO
2
is for dry-cell batteries, such as the alkaline battery and the zinc-carbon battery. MnO
2
is also used as a pigment and as a precursor to other manganese compounds, such as KMnO
4
. It is used as a reagent in organic synthesis, for example, for the oxidation of allylic alcohols. MnO
2
in the α polymorph can incorporate a variety of atoms in the "tunnels" or "channels" between the manganese oxide octahedra. There is considerable interest in α-MnO
2
as a possible cathode for lithium ion batteries.

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4
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4
, also known as manganate(VI) because it contains manganese in the +6 oxidation state. Manganates are the only known manganese(VI) compounds.

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4
.

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Cobalt(II) hydroxide chemical compound

Cobalt(II) hydroxide or cobaltous hydroxide is the inorganic compound with the formula Co(OH)
2
, consisting of divalent cobalt cations Co2+
and hydroxide anions HO
. The pure compound, often called the "beta form" is a pink solid insoluble in water.

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References

  1. Lide, David R., ed. (2006). CRC Handbook of Chemistry and Physics (87th ed.). Boca Raton, FL: CRC Press. ISBN   0-8493-0487-3.
  2. H. Lux "Manganese(IV) Hydroxide" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 1456.