Names | |
---|---|
IUPAC name Manganese(II) sulfide | |
Other names | |
Identifiers | |
ECHA InfoCard | 100.038.711 |
PubChem CID | |
UNII | |
CompTox Dashboard (EPA) | |
Properties | |
MnS | |
Molar mass | 87.003 g/mol |
Appearance | Red, green or brown powder [1] |
Density | 3.99 g/cm3 [2] |
Melting point | 1610 ˚C [3] |
0.0047 g/100 mL (18 °C) [2] | |
Structure | |
Halite (cubic), cF8 | |
Fm3m, No. 225 | |
Octahedral (Mn2+); octahedral (S2−) | |
Hazards | |
Occupational safety and health (OHS/OSH): | |
Main hazards | Irritant |
Related compounds | |
Other anions | Manganese(II) oxide Manganese(II) selenide Manganese(II) telluride |
Manganese disulfide | |
Related compounds | Chromium(II) sulfide Iron(II) sulfide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Manganese(II) sulfide is a chemical compound of manganese and sulfur. It occurs in nature as the mineral alabandite (isometric), rambergite (hexagonal), and recently found browneite (isometric, with sphalerite-type structure, extremely rare, known only from a meteorite). [4]
Manganese(II) sulfide can be prepared by reacting a manganese(II) salt (such as manganese(II) chloride) with ammonium sulfide:
The crystal structure of manganese(II) sulfide is similar to that of sodium chloride.
The pink color of MnS likely results from poor coupling between the lowest energy unoccupied Mn orbitals, resulting in discrete states rather than a delocalized band. Thus the lowest energy band-to-band electronic transition requires very high energy (ultraviolet) photons.
In crystallography, the cubiccrystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals.
Classical qualitative inorganic analysis is a method of analytical chemistry which seeks to find the elemental composition of inorganic compounds. It is mainly focused on detecting ions in an aqueous solution, therefore materials in other forms may need to be brought to this state before using standard methods. The solution is then treated with various reagents to test for reactions characteristic of certain ions, which may cause color change, precipitation and other visible changes.
In chemistry, water(s) of crystallization or water(s) of hydration are water molecules that are present inside crystals. Water is often incorporated in the formation of crystals from aqueous solutions. In some contexts, water of crystallization is the total mass of water in a substance at a given temperature and is mostly present in a definite (stoichiometric) ratio. Classically, "water of crystallization" refers to water that is found in the crystalline framework of a metal complex or a salt, which is not directly bonded to the metal cation.
Manganese(II) chloride is the dichloride salt of manganese, MnCl2. This inorganic chemical exists in the anhydrous form, as well as the dihydrate (MnCl2·2H2O) and tetrahydrate (MnCl2·4H2O), with the tetrahydrate being the most common form. Like many Mn(II) species, these salts are pink, with the paleness of the color being characteristic of transition metal complexes with high spin d5 configurations.
Cobalt(II) chloride is an inorganic compound of cobalt and chlorine, with the formula CoCl
2. The compound forms several hydrates CoCl
2·nH
2O, for n = 1, 2, 6, and 9. Claims of the formation of tri- and tetrahydrates have not been confirmed. The anhydrous form is a blue crystalline solid; the dihydrate is purple and the hexahydrate is pink. Commercial samples are usually the hexahydrate, which is one of the most commonly used cobalt compounds in the lab.
A zinc–carbon battery (or carbon zinc battery in U.S. English) is a dry cell primary battery that provides direct electric current from the electrochemical reaction between zinc (Zn) and manganese dioxide (MnO2) in the presence of an ammonium chloride (NH4Cl) electrolyte. It produces a voltage of about 1.5 volts between the zinc anode, which is typically constructed as a cylindrical container for the battery cell, and a carbon rod surrounded by a compound with a higher Standard electrode potential (positive polarity), known as the cathode, that collects the current from the manganese dioxide electrode. The name "zinc-carbon" is slightly misleading as it implies that carbon is acting as the oxidizing agent rather than the manganese dioxide.
Scandium(III) oxide or scandia is a inorganic compound with formula Sc2O3. It is one of several oxides of rare earth elements with a high melting point. It is used in the preparation of other scandium compounds as well as in high-temperature systems (for its resistance to heat and thermal shock), electronic ceramics, and glass composition (as a helper material).
Birnessite (nominally MnO2·nH2O), also known as δ-MnO2, is a hydrous manganese dioxide mineral with a chemical formula of Na0.7Ca0.3Mn7O14·2.8H2O. It is the main manganese mineral species at the Earth's surface, and commonly occurs as fine-grained, poorly crystallized aggregates in soils, sediments, grain and rock coatings (e.g., desert varnish), and marine ferromanganese nodules and crusts. It was discovered at Birness, Aberdeenshire, Scotland.
Galaxite, also known as 'mangan-spinel' is an isometric mineral belonging to the spinel group of oxides with the ideal chemical formula Mn2+Al2O4.
Rambergite is a manganese sulfide mineral with formula MnS.
Corderoite is an extremely rare mercury sulfide chloride mineral with formula Hg3S2Cl2. It crystallizes in the isometric crystal system. It is soft, 1.5 to 2 on the Mohs scale, and varies in color from light gray to black and rarely pink or yellow.
The Leclanché cell is a battery invented and patented by the French scientist Georges Leclanché in 1866. The battery contained a conducting solution (electrolyte) of ammonium chloride, a cathode of carbon, a depolarizer of manganese dioxide (oxidizer), and an anode of zinc (reductant). The chemistry of this cell was later successfully adapted to manufacture a dry cell.
Alabandite or alabandine is a rarely occurring manganese sulfide mineral. It crystallizes in the cubic crystal system with the chemical composition Mn2+S and develops commonly massive to granular aggregates, but rarely also cubic or octahedral crystals to 1 cm.
Nomenclature of Inorganic Chemistry, IUPAC Recommendations 2005 is the 2005 version of Nomenclature of Inorganic Chemistry. It is a collection of rules for naming inorganic compounds, as recommended by the International Union of Pure and Applied Chemistry (IUPAC).
Compounds of lead exist with lead in two main oxidation states: +2 and +4. The former is more common. Inorganic lead(IV) compounds are typically strong oxidants or exist only in highly acidic solutions.
Brokenhillite is a rare mineral that is only found in the far-western regions of New South Wales in Broken Hill, Australia. Although it has been given a name and chemical formula, it has not been approved by the International Mineralogical Association primarily because it is a manganese silicate of the pyrosmalite group which means the compositional similarities are too great to be an approved mineral. Brokenhillite structure is either composed of iron or manganese with the formula (Mn+2,Fe+2)8Si6O15(OH,Cl)10. The actual components inside brokenhillite can be determined using a diffractometer. The structural basis of this mineral is determined to be phyllosilicate within the pyrosmalites due to the octahedral structure, with one perfect cleavage, a hardness of about 4.5, and a streak of light brown.
The sulfate chlorides are double salts containing both sulfate (SO42–) and chloride (Cl–) anions. They are distinct from the chlorosulfates, which have a chlorine atom attached to the sulfur as the ClSO3− anion.
Chromium(II) sulfide is an inorganic compound of chromium and sulfur with the chemical formula CrS. The compound forms black hexagonal crystals, insoluble in water.
Manganese(III) chloride is the hypothetical inorganic compound with the formula MnCl3.