Praseodymium(III) sulfide

Last updated
Praseodymium(III) sulfide
Identifiers
3D model (JSmol)
ECHA InfoCard 100.031.691 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 234-874-1
PubChem CID
  • InChI=1S/2Pr.3S/q2*+3;3*-2
    Key: VUXGXCBXGJZHNB-UHFFFAOYSA-N
  • [S-2].[S-2].[S-2].[Pr+3].[Pr+3]
Properties
Pr2S3
Molar mass 378.00 g/mol
Appearancebrown powder
Odor rotten egg
Density 5.042 g/cm3, solid (11°C)
+10,770·10−6 cm3/mol
Hazards
NFPA 704 (fire diamond)
NFPA 704.svgHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 3: Liquids and solids that can be ignited under almost all ambient temperature conditions. Flash point between 23 and 38 °C (73 and 100 °F). E.g. gasolineInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
3
0
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Praseodymium(III) sulfide is an inorganic chemical compound with chemical formula Pr2 S3.

Preparation

Praseodymium(III) sulfide can be obtained by reacting praseodymium(III) oxide and hydrogen sulfide at 1320 °C: [1]

Pr2O3 + 3H2S → Pr2S3 + 3H2O

It could also be obtained by directly reacting sulfur with metallic praseodymium: [2]

2Pr + 3S → Pr2S3

Related Research Articles

<span class="mw-page-title-main">Praseodymium</span> Chemical element, symbol Pr and atomic number 59

Praseodymium is a chemical element; it has symbol Pr and the atomic number 59. It is the third member of the lanthanide series and is considered one of the rare-earth metals. It is a soft, silvery, malleable and ductile metal, valued for its magnetic, electrical, chemical, and optical properties. It is too reactive to be found in native form, and pure praseodymium metal slowly develops a green oxide coating when exposed to air.

<span class="mw-page-title-main">Iron(II) sulfide</span> Chemical compound

Iron(II) sulfide or ferrous sulfide is one of a family of chemical compounds and minerals with the approximate formula FeS. Iron sulfides are often iron-deficient non-stoichiometric. All are black, water-insoluble solids.

Indium(III) sulfide (Indium sesquisulfide, Indium sulfide (2:3), Indium (3+) sulfide) is the inorganic compound with the formula In2S3.

<span class="mw-page-title-main">Bismuth(III) sulfide</span> Chemical compound

Bismuth(III) sulfide is a chemical compound of bismuth and sulfur. It occurs in nature as the mineral bismuthinite.

Praseodymium(III) fluoride is an inorganic compound with the formula PrF3, being the most stable fluoride of praseodymium.

<span class="mw-page-title-main">Praseodymium(III) hydroxide</span> Chemical compound

Praseodymium(III) hydroxide is an inorganic compound with a chemical formula Pr(OH)3.

<span class="mw-page-title-main">Cerium(III) sulfide</span> Chemical compound

Cerium(III) sulfide, also known as cerium sesquisulfide, is an inorganic compound with the formula Ce2S3. It is the sulfide salt of cerium(III) and exists as three polymorphs with different crystal structures.

Praseodymium(III) nitride is a binary inorganic compound of praseodymium and nitrogen. Its chemical formula is PrN. The compound forms black crystals, and reacts with water.

<span class="mw-page-title-main">Chromium(II) sulfide</span> Chemical compound

Chromium(II) sulfide is an inorganic compound of chromium and sulfur with the chemical formula CrS. The compound forms black hexagonal crystals, insoluble in water.

<span class="mw-page-title-main">Neodymium(III) acetate</span> Compound of neodymium

Neodymium(III) acetate is an inorganic salt composed of a neodymium atom trication and three acetate groups as anions where neodymium exhibits the +3 oxidation state. It has a chemical formula of Nd(CH3COO)3 although it can be informally referred to as NdAc because Ac is an informal symbol for acetate. It commonly occurs as a light purple powder.

Praseodymium compounds are compounds formed by the lanthanide metal praseodymium (Pr). In these compounds, praseodymium generally exhibits the +3 oxidation state, such as PrCl3, Pr(NO3)3 and Pr(CH3COO)3. However, compounds with praseodymium in the +2 and +4 oxidation states, and unlike other lanthanides, the +5 oxidation state, are also known.

Neodymium(III) sulfide is a inorganic chemical compound with the formula Nd2S3 composed of a two neodymium atoms in the +3 oxidation state and three sulfur atoms in the +2 oxidation state. Like other rare earth sulfides, neodymium(III) sulfide is used as a high-performance inorganic pigment.

<span class="mw-page-title-main">Praseodymium(III) iodide</span> Chemical compound

Praseodymium(III) iodide is an inorganic salt, consisting of the rare-earth metal praseodymium and iodine, with the chemical formula PrI3. It forms green crystals. It is soluble in water.

<span class="mw-page-title-main">Neodymium(III) acetylacetonate</span> Chemical compound

Neodymium(III) acetylacetonate is a coordination compound of neodymium and acetylacetone, with the chemical formula Nd(O2C5H7)3(H2O)2, although some sources ignore the aquo ligands. It commonly occurs as a white powder. Its instablility constants (logYn) are 2.89, 4.15 and 5.26 (corresponding to n = 1, 2, 3). Its dihydrate reacts with carbonyl rhenium complex Re(CO)3X(4,4'-bipy) (X=Cl, Br) to obtain Re(CO)3X(4,4'-bipy)Nd(acac)3.

<span class="mw-page-title-main">Praseodymium diiodide</span> Chemical compound

Praseodymium diiodide is a chemical compound with the empirical formula of PrI2, consisting of praseodymium and iodine. It is an electride, with the ionic formula of Pr3+(I)2e, and therefore not a true praseodymium(II) compound.

Praseodymium(III) carbonate is an inorganic compound, with a chemical formula of Pr2(CO3)3. The anhydrous form is olive green, and many of its hydrates such as heptahydrate and octahydrate are known. They are all insoluble in water.

<span class="mw-page-title-main">Europium compounds</span> Compounds with at least one europium atom

Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Many europium compounds fluoresce under ultraviolet light due to the excitation of electrons to higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.

Praseodymium orthoscandate is a chemical compound, a rare-earth oxide with a perovskite structure. It has the chemical formula of PrScO3.

<span class="mw-page-title-main">Terbium compounds</span> Chemical compounds with at least one terbium atom

Terbium compounds are compounds formed by the lanthanide metal terbium (Tb). Terbium generally exhibits the +3 oxidation state in these compounds, such as in TbCl3, Tb(NO3)3 and Tb(CH3COO)3. Compounds with terbium in the +4 oxidation state are also known, such as TbO2 and BaTbF6. Terbium can also form compounds in the 0, +1 and +2 oxidation states.

<span class="mw-page-title-main">Praseodymium(III) phosphate</span> Chemical compound

Praseodymium phosphate is an inorganic compound with the chemical formula PrPO4. Its hemihydrate can be obtained by reacting praseodymium chloride and phosphoric acid. It can also be produced by reacting silicon pyrophosphate (SiP2O7) and praseodymium(III,IV) oxide (Pr6O11) at 1200 °C. It reacts with sodium fluoride to obtain Na2PrF2(PO4).

References

  1. Georg Brauer (1975). Handbuch der präparativen anorganischen Chemie (in German). Enke. ISBN   978-3-432-02328-1.
  2. A. W. Sleight and D. P. Kelly (1973), Aaron Wold and John K. Ruff (ed.), Rare-earth sesquisulfides, Ln2S3, Inorganic Syntheses (in German), vol. 14, McGraw-Hill Book Company, Inc., pp. 152–155