Names | |
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Other names Praseodymium(III) bismuthide Bismuth-Praseodymium | |
Identifiers | |
3D model (JSmol) | |
EC Number |
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PubChem CID | |
CompTox Dashboard (EPA) | |
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Properties | |
BiPr | |
Molar mass | 349.89 g/mol |
Density | 8.6 g/cm3 |
Melting point | 1800 °C |
Critical point (T, P) | -111 kJ/mol [1] |
Structure | |
cubic | |
Fm3m | |
Related compounds | |
Other anions | PrN, PrP, PrAs, PrSb, Pr2O3 |
Other cations | CeBi, NdBi |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Praseodymium bismuthide is a binary inorganic compound of praseodymium and bismuth with the chemical formula of PrBi. It forms crystals.
Praseodymium bismuthide can be prepared by reacting stoichiometric amounts of praseodymium and bismuth at 1800 °C:[ citation needed ]
Praseodymium bismuthide forms crystals of the cubic crystal system, with space group Fm3m, cell parameters a = 0.64631 nm, Z = 4, and a structure like sodium chloride NaCl. [2] [3] [4] The compound melts congruently at a temperature of roughly 1800 °С. [5] [6] At a pressure of 14 GPa, it undergoes a phase transition. [7]
In crystallography, the cubiccrystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals.
Praseodymium(III) chloride is the inorganic compound with the formula PrCl3. Like other lanthanide trichlorides, it exists both in the anhydrous and hydrated forms. It is a blue-green solid that rapidly absorbs water on exposure to moist air to form a light green heptahydrate.
Tin telluride is a compound of tin and tellurium (SnTe); is a IV-VI narrow band gap semiconductor and has direct band gap of 0.18 eV. It is often alloyed with lead to make lead tin telluride, which is used as an infrared detector material.
Bismuth is a chemical element with the symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs naturally, and its sulfide and oxide forms are important commercial ores. The free element is 86% as dense as lead. It is a brittle metal with a silvery-white color when freshly produced. Surface oxidation generally gives samples of the metal a somewhat rosy cast. Further oxidation under heat can give bismuth a vividly iridescent appearance due to thin-film interference. Bismuth is both the most diamagnetic element and one of the least thermally conductive metals known.
Binary compounds of hydrogen are binary chemical compounds containing just hydrogen and one other chemical element. By convention all binary hydrogen compounds are called hydrides even when the hydrogen atom in it is not an anion. These hydrogen compounds can be grouped into several types.
Binary compounds of silicon are binary chemical compounds containing silicon and one other chemical element. Technically the term silicide is reserved for any compounds containing silicon bonded to a more electropositive element. Binary silicon compounds can be grouped into several classes. Saltlike silicides are formed with the electropositive s-block metals. Covalent silicides and silicon compounds occur with hydrogen and the elements in groups 10 to 17.
Oxybismuthides or bismuthide oxides are chemical compounds formally containing the group BiO, with one bismuth and one oxygen atom. The bismuth and oxygen are not bound together as in bismuthates, instead they make a separate presence bound to the cations (metals), and could be considered as a mixed bismuthide-oxide compound. So a compound with OmBin requires cations to balance a negative charge of 2m+3n. The cations will have charges of +2 or +3. The trications are often rare earth elements or actinides. They are in the category of oxypnictide compounds.
Praseodymium monophosphide is an inorganic compound of praseodymium and phosphorus with the chemical formula PrP. The compound forms crystals.
Praseodymium compounds are compounds formed by the lanthanide metal praseodymium (Pr). In these compounds, praseodymium generally exhibits the +3 oxidation state, such as PrCl3, Pr(NO3)3 and Pr(CH3COO)3. However, compounds with praseodymium in the +2 and +4 oxidation states, and unlike other lanthanides, the +5 oxidation state, are also known.
Neodymium bismuthide or Bismuth-Neodymium is a binary inorganic compound of neodymium and bismuth with the formula NdBi. It forms crystals.
Holmium(III) sulfide is the sulfide of holmium, with the chemical formula of Ho2S3. Like other rare earth sulfides, it is used as a high-performance inorganic pigment.
Samarium compounds are compounds formed by the lanthanide metal samarium (Sm). In these compounds, samarium generally exhibits the +3 oxidation state, such as SmCl3, Sm(NO3)3 and Sm(C2O4)3. Compounds with samarium in the +2 oxidation state are also known, for example SmI2.
Bismuth forms mainly trivalent and a few pentavalent compounds. Many of its chemical properties are similar to those of arsenic and antimony, although much less toxic.
UPt3 is an inorganic binary intermetallic crystalline compound of platinum and uranium.
Praseodymium antimonide is a binary inorganic compound of praseodymium and antimony with the formula PrSb.
Praseodymium arsenide is a binary inorganic compound of praseodymium and arsenic with the formula PrAs.
Samarium pentaphosphide is a binary inorganic compound of samarium metal and phosphorus with the chemical formula SmP5.
Dysprosium bismuthide is a binary inorganic compound of dysprosium and bismuth with the chemical formula DyBi.
Praseodymium monosulfide is a binary inorganic chemical compound of praseodymium metal and sulfur with the chemical formula PrS.
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