Praseodymium bismuthide

Last updated
Praseodymium bismuthide
NaCl polyhedra.svg
Names
Other names
Praseodymium(III) bismuthide
Bismuth-Praseodymium
Identifiers
3D model (JSmol)
EC Number
  • 234-981-3
PubChem CID
  • InChI=1S/Bi.Pr
    Key: GXEWOMCEINAZJT-UHFFFAOYSA-N
  • [Pr].[Bi]
Properties
BiPr
Molar mass 349.89 g/mol
Density 8.6 g/cm3
Melting point 1800 °C
Critical point (T, P)-111 kJ/mol [1]
Structure
cubic
Fm3m
Related compounds
Other anions
PrN, PrP, PrAs, PrSb, Pr2O3
Other cations
CeBi, NdBi
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Praseodymium bismuthide is a binary inorganic compound of praseodymium and bismuth with the chemical formula of PrBi. It forms crystals.

Contents

Preparation

Praseodymium bismuthide can be prepared by reacting stoichiometric amounts of praseodymium and bismuth at 1800 °C:[ citation needed ]

Physical properties

Praseodymium bismuthide forms crystals of the cubic crystal system, with space group Fm3m, cell parameters a = 0.64631 nm, Z = 4, and a structure like sodium chloride NaCl. [2] [3] [4] The compound melts congruently at a temperature of roughly 1800 °С. [5] [6] At a pressure of 14 GPa, it undergoes a phase transition. [7]

See also

Related Research Articles

<span class="mw-page-title-main">Cubic crystal system</span> Crystallographic system where the unit cell is in the shape of a cube

In crystallography, the cubiccrystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals.

<span class="mw-page-title-main">Praseodymium(III) chloride</span> Chemical compound

Praseodymium(III) chloride is the inorganic compound with the formula PrCl3. Like other lanthanide trichlorides, it exists both in the anhydrous and hydrated forms. It is a blue-green solid that rapidly absorbs water on exposure to moist air to form a light green heptahydrate.

<span class="mw-page-title-main">Tin telluride</span> Chemical compound

Tin telluride is a compound of tin and tellurium (SnTe); is a IV-VI narrow band gap semiconductor and has direct band gap of 0.18 eV. It is often alloyed with lead to make lead tin telluride, which is used as an infrared detector material.

<span class="mw-page-title-main">Bismuth</span> Chemical element with atomic number 83 (Bi)

Bismuth is a chemical element with the symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs naturally, and its sulfide and oxide forms are important commercial ores. The free element is 86% as dense as lead. It is a brittle metal with a silvery-white color when freshly produced. Surface oxidation generally gives samples of the metal a somewhat rosy cast. Further oxidation under heat can give bismuth a vividly iridescent appearance due to thin-film interference. Bismuth is both the most diamagnetic element and one of the least thermally conductive metals known.

Binary compounds of hydrogen are binary chemical compounds containing just hydrogen and one other chemical element. By convention all binary hydrogen compounds are called hydrides even when the hydrogen atom in it is not an anion. These hydrogen compounds can be grouped into several types.

<span class="mw-page-title-main">Binary compounds of silicon</span> Any binary chemical compound containing just silicon and another chemical element

Binary compounds of silicon are binary chemical compounds containing silicon and one other chemical element. Technically the term silicide is reserved for any compounds containing silicon bonded to a more electropositive element. Binary silicon compounds can be grouped into several classes. Saltlike silicides are formed with the electropositive s-block metals. Covalent silicides and silicon compounds occur with hydrogen and the elements in groups 10 to 17.

Oxybismuthides or bismuthide oxides are chemical compounds formally containing the group BiO, with one bismuth and one oxygen atom. The bismuth and oxygen are not bound together as in bismuthates, instead they make a separate presence bound to the cations (metals), and could be considered as a mixed bismuthide-oxide compound. So a compound with OmBin requires cations to balance a negative charge of 2m+3n. The cations will have charges of +2 or +3. The trications are often rare earth elements or actinides. They are in the category of oxypnictide compounds.

Praseodymium monophosphide is an inorganic compound of praseodymium and phosphorus with the chemical formula PrP. The compound forms crystals.

Praseodymium compounds are compounds formed by the lanthanide metal praseodymium (Pr). In these compounds, praseodymium generally exhibits the +3 oxidation state, such as PrCl3, Pr(NO3)3 and Pr(CH3COO)3. However, compounds with praseodymium in the +2 and +4 oxidation states, and unlike other lanthanides, the +5 oxidation state, are also known.

<span class="mw-page-title-main">Neodymium bismuthide</span> Chemical compound

Neodymium bismuthide or Bismuth-Neodymium is a binary inorganic compound of neodymium and bismuth with the formula NdBi. It forms crystals.

<span class="mw-page-title-main">Holmium(III) sulfide</span> Chemical compound

Holmium(III) sulfide is the sulfide of holmium, with the chemical formula of Ho2S3. Like other rare earth sulfides, it is used as a high-performance inorganic pigment.

Samarium compounds are compounds formed by the lanthanide metal samarium (Sm). In these compounds, samarium generally exhibits the +3 oxidation state, such as SmCl3, Sm(NO3)3 and Sm(C2O4)3. Compounds with samarium in the +2 oxidation state are also known, for example SmI2.

<span class="mw-page-title-main">Bismuth compounds</span>

Bismuth forms mainly trivalent and a few pentavalent compounds. Many of its chemical properties are similar to those of arsenic and antimony, although much less toxic.

UPt<sub>3</sub> Chemical compound

UPt3 is an inorganic binary intermetallic crystalline compound of platinum and uranium.

<span class="mw-page-title-main">Praseodymium antimonide</span> Chemical compound

Praseodymium antimonide is a binary inorganic compound of praseodymium and antimony with the formula PrSb.

<span class="mw-page-title-main">Praseodymium arsenide</span> Chemical compound

Praseodymium arsenide is a binary inorganic compound of praseodymium and arsenic with the formula PrAs.

Samarium pentaphosphide is a binary inorganic compound of samarium metal and phosphorus with the chemical formula SmP5.

<span class="mw-page-title-main">Dysprosium bismuthide</span> Chemical compound

Dysprosium bismuthide is a binary inorganic compound of dysprosium and bismuth with the chemical formula DyBi.

<span class="mw-page-title-main">Praseodymium monosulfide</span> Chemical compound

Praseodymium monosulfide is a binary inorganic chemical compound of praseodymium metal and sulfur with the chemical formula PrS.

References

  1. A. Borsese; R. Capelli; S. Delfino; R. Ferro (1974). "The heat of formation of neodymium-bismuth alloys". Thermochimica Acta. 8 (4): 393–397. Bibcode:1974TcAc....8..393B. doi:10.1016/0040-6031(74)85107-5.
  2. Диаграммы состояния двойных металлических систем. Vol. 1. М.: Машиностроение. 1996. ISBN   5-217-02688-X.{{cite book}}: Unknown parameter |agency= ignored (help)
  3. K. A. Gschneidner, F. W. Calderwood (1989). "The Bi−Pr (Bismuth-Praseodymium) system". Bulletin of Alloy Phase Diagrams. 10 (4) (Bulletin of Alloy Phase Diagrams ed.): 447–450. doi:10.1007/BF02882373.
  4. B. Predel (1992). "Bi-Pr (Bismuth-Praseodymium)". B-Ba – C-Zr. Landolt-Börnstein - Group IV Physical Chemistry. Vol. 5b (Landolt-Börnstein - Group IV Physical Chemistry ed.). pp. 1–3. doi:10.1007/10040476_575. ISBN   3-540-55115-8.
  5. Y. Castrillejo, M.R. Bermejo, P. Dı´az Arocas, A.M. Martı´nez, E. Barrado (2005). "The electrochemical behaviour of the Pr(III)/Pr redox system at Bi and Cd liquid electrodes in molten eutectic LiCl–KCl". Journal of Electroanalytical Chemistry. 579 (2) (Journal of Electroanalytical Chemistry ed.): 343–358. doi:10.1016/j.jelechem.2005.03.001.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  6. K.A. Gschneidner Jr., F.W. Calderwood, T.B. Massalski (1990). Binary alloy phase diagrams. ASM International. pp. 776–1015.{{cite book}}: CS1 maint: multiple names: authors list (link)
  7. Shirotani Ichimin, Hayashi Junichi, Yamanashi Keigo, Hirano Kouji, Adachi Takafumi, Ishimatsu Naoki, Shimomura Osamu, Kikegawa Takumi (2003). "X-ray study with synchrotron radiation of cerium and praseodymium monopnictides with the NaCl-type structure at high pressures". Physica B: Condensed Matter. 334 (1–2) (Physica B: Physics of Condensed Matter ed.): 167–174. Bibcode:2003PhyB..334..167S. doi:10.1016/S0921-4526(03)00042-5.{{cite journal}}: CS1 maint: multiple names: authors list (link)