Holmium bismuthide

Last updated
Holmium bismuthide
NaCl polyhedra.png
Names
Other names
Holmium monobismuthide
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 234-552-0
PubChem CID
  • InChI=1S/Bi.Ho
    Key: ZENJQEGOGPMIBF-UHFFFAOYSA-N
  • [Ho].[Bi]
Properties
HoSb
Molar mass 286.690 g·mol−1
Related compounds
Other anions
Holmium nitride
Holmium phosphide
Holmium arsenide
Holmium antimonide
Other cations
Dysprosium phosphide
Erbium phosphide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Holmium bismuthide is a binary inorganic compound of holmium and bismuth with the chemical formula HoBi. [1] [2]

Contents

Physical properties

The compound is rock-salt structured, crystallizing in the cubic cF8 space group. [3]

The bismuthide oxide compound Ho2BiO2 has a tetragonal structure. [4]

Related Research Articles

<span class="mw-page-title-main">Holmium</span> Chemical element, symbol Ho and atomic number 67

Holmium is a chemical element; it has symbol Ho and atomic number 67. It is a rare-earth element and the eleventh member of the lanthanide series. It is a relatively soft, silvery, fairly corrosion-resistant and malleable metal. Like many other lanthanides, holmium is too reactive to be found in native form, as pure holmium slowly forms a yellowish oxide coating when exposed to air. When isolated, holmium is relatively stable in dry air at room temperature. However, it reacts with water and corrodes readily, and also burns in air when heated.

<span class="mw-page-title-main">Holmium(III) oxide</span> Chemical compound

Holmium(III) oxide, or holmium oxide is a chemical compound of the rare-earth element holmium and oxygen with the formula Ho2O3. Together with dysprosium(III) oxide (Dy2O3), holmium oxide is one of the most powerfully paramagnetic substances known. The oxide, also called holmia, occurs as a component of the related erbium oxide mineral called erbia. Typically, the oxides of the trivalent lanthanides coexist in nature, and separation of these components requires specialized methods. Holmium oxide is used in making specialty colored glasses. Glass containing holmium oxide and holmium oxide solutions have a series of sharp optical absorption peaks in the visible spectral range. They are therefore traditionally used as a convenient calibration standard for optical spectrophotometers.

<span class="mw-page-title-main">Bismuth</span> Chemical element, symbol Bi and atomic number 83

Bismuth is a chemical element; it has symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs naturally, and its sulfide and oxide forms are important commercial ores. The free element is 86% as dense as lead. It is a brittle metal with a silvery-white color when freshly produced. Surface oxidation generally gives samples of the metal a somewhat rosy cast. Further oxidation under heat can give bismuth a vividly iridescent appearance due to thin-film interference. Bismuth is both the most diamagnetic element and one of the least thermally conductive metals known.

Oxybismuthides or bismuthide oxides are chemical compounds formally containing the group BiO, with one bismuth and one oxygen atom. The bismuth and oxygen are not bound together as in bismuthates, instead they make a separate presence bound to the cations (metals), and could be considered as a mixed bismuthide-oxide compound. So a compound with OmBin requires cations to balance a negative charge of 2m+3n. The cations will have charges of +2 or +3. The trications are often rare earth elements or actinides. They are in the category of oxypnictide compounds.

Holmium(III) fluoride is an inorganic compound with a chemical formula of HoF3.

Lithium phosphide is an inorganic compound of lithium and phosphorus with the chemical formula Li
3
P
. This dark colored compound is formally the Li+ salt of P3-. It is a hazardous to handle because of its high reactivity toward air.

Praseodymium monophosphide is an inorganic compound of praseodymium and phosphorus with the chemical formula PrP. The compound forms crystals.

<span class="mw-page-title-main">Lanthanum phosphide</span> Chemical compound

Lanthanum phosphide is an inorganic compound of lanthanum and phosphorus with the chemical formula LaP.

Thulium phosphide is an inorganic compound of thulium and phosphorus with the chemical formula TmP.

Holmium phosphide is a binary inorganic compound of holmium and phosphorus with the chemical formula HoP. The compound forms dark crystals and does not dissolve in water.

Samarium(III) arsenide is a binary inorganic compound of samarium and arsenic with the chemical formula SmAs.

<span class="mw-page-title-main">Neodymium bismuthide</span> Chemical compound

Neodymium bismuthide or Bismuth-Neodymium is a binary inorganic compound of neodymium and bismuth with the formula NdBi. It forms crystals.

<span class="mw-page-title-main">Holmium(III) iodide</span> Chemical compound

Holmium(III) iodide is an iodide of holmium, with the chemical formula of HoI3. It is used as a component of metal halide lamps.

Erbium compounds are compounds containing the element erbium (Er). These compounds are usually dominated by erbium in the +3 oxidation state, although the +2, +1 and 0 oxidation states have also been reported.

Ytterbium compounds are chemical compounds that contain the element ytterbium (Yb). The chemical behavior of ytterbium is similar to that of the rest of the lanthanides. Most ytterbium compounds are found in the +3 oxidation state, and its salts in this oxidation state are nearly colorless. Like europium, samarium, and thulium, the trihalides of ytterbium can be reduced to the dihalides by hydrogen, zinc dust, or by the addition of metallic ytterbium. The +2 oxidation state occurs only in solid compounds and reacts in some ways similarly to the alkaline earth metal compounds; for example, ytterbium(II) oxide (YbO) shows the same structure as calcium oxide (CaO).

<span class="mw-page-title-main">Bismuth compounds</span>

Bismuth forms mainly trivalent and a few pentavalent compounds. Many of its chemical properties are similar to those of arsenic and antimony, although much less toxic.

<span class="mw-page-title-main">Praseodymium bismuthide</span> Binary inorganic compound of praseodymium and bismuth with the chemical formula of PrBi

Praseodymium bismuthide is a binary inorganic compound of praseodymium and bismuth with the chemical formula of PrBi. It forms crystals.

Holmium nitride is a binary inorganic compound of holmium and nitrogen with the chemical formula HoN.

<span class="mw-page-title-main">Holmium arsenide</span> Chemical compound

Holmium arsenide is a binary inorganic compound of holmium and arsenide with the chemical formula HoAs.

<span class="mw-page-title-main">Holmium antimonide</span> Chemical compound

Holmium antimonide is a binary inorganic compound of holmium and antimony with the chemical formula HoSb.

References

  1. Fente, A.; Suderow, H.; Vieira, S.; Nemes, N.M.; García-Hernández, M.; Bud'ko, S.L.; Canfield, P.C. (October 2013). "Low temperature magnetic transitions of single crystal HoBi". Solid State Communications . 171: 59–63. doi:10.1016/j.ssc.2013.07.027 . Retrieved 27 May 2024.
  2. Toxic Substances Control Act (TCSA) Chemical Substance Inventory: Cumulative Supplement to the Original Inventory. User Guide and Indices. U.S. Environment Protection Agency, Office of Toxic Substances. 1980. p. 170. Retrieved 27 May 2024.
  3. "HoBi Crystal Structure - SpringerMaterials". materials.springer.com. Retrieved 27 May 2024.
  4. Mizoguchi, Hiroshi; Hosono, Hideo (2 March 2011). "A Metal−Insulator Transition in R 2 O 2 Bi with an Unusual Bi 2− Square Net (R = Rare Earth or Y)". Journal of the American Chemical Society. 133 (8): 2394–2397. doi:10.1021/ja111015p.