Bismuthide

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The bismuthide ion is Bi3−.

Bismuthides are compounds of bismuth with more electropositive elements. They are intermetallic compounds, containing partially metallic and partially ionic bonds. [1] The majority of bismuthides adopt efficient packing arrangements and become densely packed structures, which is a characteristic of intermetallic compounds.

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Bismanol is an magnetic alloy of bismuth and manganese developed by the US Naval Ordnance Laboratory.

<span class="mw-page-title-main">Intermetallic</span> Type of metallic alloy

An intermetallic is a type of metallic alloy that forms an ordered solid-state compound between two or more metallic elements. Intermetallics are generally hard and brittle, with good high-temperature mechanical properties. They can be classified as stoichiometric or nonstoichiometic intermetallic compounds.

Magnesium aluminide is an intermetallic compound of magnesium and aluminium. Common phases (molecular structures) include the beta phase (Mg2Al3) and the gamma phase (Mg17Al12), which both have cubic crystal structures. Magnesium aluminides are important constituents of 5XXX aluminium alloys (aluminium-magnesium) and magnesium-aluminium alloys, determining many of their engineering properties. Due to the advantage of low density and being strong, magnesium aluminide is important for aircraft engines. MgAl has also been investigated for use as a reactant to produce metal hydrides in hydrogen storage technology. Like many intermetallics, MgAl compounds often have unusual stoichiometries with large and complex unit cells.

Titanium aluminide, commonly gamma titanium, is an intermetallic chemical compound. It is lightweight and resistant to oxidation and heat, but has low ductility. The density of γ-TiAl is about 4.0 g/cm3. It finds use in several applications including aircraft, jet engines, sporting equipment and automobiles. The development of TiAl based alloys began circa 1970. The alloys have been used in these applications only since about 2000.

Complex metallic alloys (CMAs) or complex intermetallics (CIMs) are intermetallic compounds characterized by the following structural features:

  1. large unit cells, comprising some tens up to thousands of atoms,
  2. the presence of well-defined atom clusters, frequently of icosahedral point group symmetry,
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Nickel aluminide refers to either of two widely used intermetallic compounds, Ni3Al or NiAl, but the term is sometimes used to refer to any nickel–aluminium alloy. These alloys are widely used because of their high strength even at high temperature, low density, corrosion resistance, and ease of production. Ni3Al is of specific interest as a precipitate in nickel-based superalloys, where it is called the γ' (gamma prime) phase. It gives these alloys high strength and creep resistance up to 0.7–0.8 of its melting temperature. Meanwhile, NiAl displays excellent properties such as lower density and higher melting temperature than those of Ni3Al, and good thermal conductivity and oxidation resistance. These properties make it attractive for special high-temperature applications like coatings on blades in gas turbines and jet engines. However, both these alloys have the disadvantage of being quite brittle at room temperature, with Ni3Al remaining brittle at high temperatures as well. To address this problem, has been shown that Ni3Al can be made ductile when manufactured in single-crystal form rather than in polycrystalline form.

<span class="mw-page-title-main">Gold–aluminium intermetallic</span> Any intermetallic compound of gold and aluminium

Gold–aluminium intermetallic is a type of intermetallic compound of gold and aluminium that usually forms at contacts between the two metals. Gold–aluminium intermetallic have different properties from the individual metals, such as low conductivity and high melting point depending on their composition. Due to the difference of density between the metals and intermetallics, the growth of the intermetallic layers causes reduction in volume, and therefore creates gaps in the metal near the interface between gold and aluminium.

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A chemical compound is a chemical substance composed of many identical molecules containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element is therefore not a compound. A compound can be transformed into a different substance by a chemical reaction, which may involve interactions with other substances. In this process, bonds between atoms may be broken and/or new bonds formed.

<span class="mw-page-title-main">Plumbide</span> Compound containing a plumbide anion

Plumbide is an anion of lead atoms. There are three plumbide anions, written as Pb, Pb2− and Pb4− with 3 oxidation states, -1, -2 and -4, respectively. A plumbide can refer to one of two things: an intermetallic compound that contains lead, or a Zintl phase compound with lead as the anion.

<span class="mw-page-title-main">Sodium polonide</span> Chemical compound

Sodium polonide is a radioactive chemical compound with the formula Na2Po. This salt is a polonide, a set of very chemically stable compounds of polonium. Due to the difference in electronegativity (ΔEN) between sodium and polonium and the slight non-metallic character of polonium, it is intermediate between intermetallic phases and ionic compounds.

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Oxybismuthides or bismuthide oxides are chemical compounds formally containing the group BiO, with one bismuth and one oxygen atom. The bismuth and oxygen are not bound together as in bismuthates, instead they make a separate presence bound to the cations (metals), and could be considered as a mixed bismuthide-oxide compound. So a compound with OmBin requires cations to balance a negative charge of 2m+3n. The cations will have charges of +2 or +3. The trications are often rare earth elements or actinides. They are in the category of oxypnictide compounds.

Platinum-samarium is a binary inorganic compound of platinum and samarium with the chemical formula PtSm. This intermetallic compound forms crystals.

Lithium phosphide is an inorganic compound of lithium and phosphorus with the chemical formula Li
3
P
. This dark colored compound is formally the Li+ salt of P3-. It is a hazardous to handle because of its high reactivity toward air.

<span class="mw-page-title-main">Neodymium bismuthide</span> Chemical compound

Neodymium bismuthide or Bismuth-Neodymium is a binary inorganic compound of neodymium and bismuth with the formula NdBi. It forms crystals.

<span class="mw-page-title-main">Bismuth compounds</span>

Bismuth forms mainly trivalent and a few pentavalent compounds. Many of its chemical properties are similar to those of arsenic and antimony, although much less toxic.

References

  1. "bismuthide". Your Dictionary. Retrieved 2020-04-07.