Antimonide

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Antimonides (sometimes called stibnides or stibinides) are compounds of antimony with more electropositive elements. The antimonide ion is Sb3−.

Reduction of antimony by alkali metals or by other methods leads to alkali metal antimonides of various types. [1] Known antimonides include isolated Sb3− ions (in Li3Sb, Na3Sb), dumbbells Sb4−2 in Cs4Sb2, discrete antimony chains, for example, Sb8−6 in SrSb3, infinite spirals (Sb)n (in NaSb, RbSb), planar four-membered rings Sb2−4, Sb3−7 cages in Cs3Sb, and net shaped anions Sb2−3 in BaSb3.

Some antimonides are semiconductors, e.g. those of the boron group such as indium antimonide. Many antimonides are flammable or decomposed by oxygen when heated since the antimonide ion is a reducing agent.

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<span class="mw-page-title-main">Alkali metal</span> Group of highly reactive chemical elements

The alkali metals consist of the chemical elements lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs), and francium (Fr). Together with hydrogen they constitute group 1, which lies in the s-block of the periodic table. All alkali metals have their outermost electron in an s-orbital: this shared electron configuration results in their having very similar characteristic properties. Indeed, the alkali metals provide the best example of group trends in properties in the periodic table, with elements exhibiting well-characterised homologous behaviour. This family of elements is also known as the lithium family after its leading element.

<span class="mw-page-title-main">Antimony</span> Chemical element with atomic number 51 (Sb)

Antimony is a chemical element; it has symbol Sb (from Latin stibium) and atomic number 51. A lustrous grey metal or metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3). Antimony compounds have been known since ancient times and were powdered for use as medicine and cosmetics, often known by the Arabic name kohl. The earliest known description of this metalloid in the West was written in 1540 by Vannoccio Biringuccio.

SB or Sb may refer to:

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<span class="mw-page-title-main">Indium antimonide</span> Chemical compound

Indium antimonide (InSb) is a crystalline compound made from the elements indium (In) and antimony (Sb). It is a narrow-gap semiconductor material from the III-V group used in infrared detectors, including thermal imaging cameras, FLIR systems, infrared homing missile guidance systems, and in infrared astronomy. Indium antimonide detectors are sensitive to infrared wavelengths between 1 and 5 μm.

<span class="mw-page-title-main">Stibine</span> Chemical compound

Stibine (IUPAC name: stibane) is a chemical compound with the formula SbH3. A pnictogen hydride, this colourless, highly toxic gas is the principal covalent hydride of antimony, and a heavy analogue of ammonia. The molecule is pyramidal with H–Sb–H angles of 91.7° and Sb–H distances of 170.7 pm (1.707 Å). The smell of this compound from usual sources (like from reduction of antimony compounds) is reminiscent of arsine, id est garlic-like.

In chemistry an antimonate is a compound which contains a metallic element, oxygen, and antimony in an oxidation state of +5. These compounds adopt polymeric structures with M-O-Sb linkages. They can be considered to be derivatives of the hypothetical antimonic acid H3SbO4, or combinations of metal oxides and antimony pentoxide, Sb2O5.

<span class="mw-page-title-main">Aluminium antimonide</span> Chemical compound

Aluminium antimonide (AlSb) is a semiconductor of the group III-V family containing aluminium and antimony. The lattice constant is 0.61 nm. The indirect bandgap is approximately 1.6 eV at 300 K, whereas the direct band gap is 2.22 eV.

<span class="mw-page-title-main">Gallium antimonide</span> Chemical compound

Gallium antimonide (GaSb) is a semiconducting compound of gallium and antimony of the III-V family. It has a room temperature lattice constant of about 0.610 nm. It has a room temperature direct bandgap of approximately 0.73 eV.

<span class="mw-page-title-main">Zinc antimonide</span> Chemical compound

Zinc antimonide (ZnSb), (Zn3Sb2), (Zn4Sb3) is an inorganic chemical compound. The Zn-Sb system contains six intermetallics. Like indium antimonide, aluminium antimonide, and gallium antimonide, it is a semiconducting intermetallic compound. It is used in transistors, infrared detectors and thermal imagers, as well as magnetoresistive devices.

Arsenic trifluoride is a chemical compound of arsenic and fluorine with the chemical formula AsF3. It is a colorless liquid which reacts readily with water.

Organoantimony chemistry is the chemistry of compounds containing a carbon to antimony (Sb) chemical bond. Relevant oxidation states are SbV and SbIII. The toxicity of antimony limits practical application in organic chemistry.

<span class="mw-page-title-main">Antimony(III) sulfate</span> Chemical compound

Antimony sulfate, Sb2(SO4)3, is a hygroscopic salt formed by reacting antimony or its compounds with hot sulfuric acid. It is used in doping of semiconductors and in the production of explosives and fireworks.

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Antimony phosphate, is a chemical compound of antimony and phosphate with formula SbPO4. Antimony is in the form Sb(III) with +3 oxidation state. Antimony atoms have a lone pair of electrons.

Antimonide bromides or bromide antimonides are compounds containing anions composed of bromide (Br) and antimonide (Sb3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the antimonide chlorides, antimonide iodides, arsenide chlorides, arsenide bromides, arsenide iodides, phosphide chlorides, phosphide bromides, and phosphide iodides. The bromoantimonates have antimony in positive oxidation states.

Antimonide iodides or iodide antimonides are compounds containing anions composed of iodide (I) and antimonide (Sb3−). They can be considered as mixed anion compounds. They are in the category of pnictide halides. Related compounds include the antimonide chlorides, antimonide bromides, phosphide iodides, and arsenide iodides.

Holmium diantimonide is an inorganic compound with the chemical formula HoSb2. It is one of the antimonides of holmium. It can be obtained by reacting holmium and antimony at a certain temperature (1000~1500 °C) and pressure (30~65 kbar). X-ray diffraction shows its space group C222, unit cell parameters a=3.343 Å, b=5.790 Å, c=7.840 Å, Z=2.

<span class="mw-page-title-main">Samarium(III) antimonide</span> Chemical compound

Samarium antimonide is a binary inorganic compound of samarium and antimony with the formula SmSb. It forms crystals.

References

  1. King, R. Bruse (2005). Encyclopedia of Inorganic Chemistry, Second Edition (10 Volume Set) (2nd ed.). Wiley. p. 211. ISBN   9780470860786.

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