Samarium(III) antimonide

Last updated
Samarium(III) antimonide
NaCl polyhedra.svg
Names
Other names
  • Samarium(III) antimony
  • Antimony-Samarium
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.045.224 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 249-762-8
PubChem CID
  • InChI=1S/Sb.Sm
    Key: JQVBLEDYHQAMKN-UHFFFAOYSA-N
  • [Sb].[Sm]
Properties
PrSb
Molar mass 272.12 g/mol
Density 7.3 g/cm3
Melting point 1922 °C
Related compounds
Other anions
SmN, SmP, SmAs, SmBi, Sm2O3
Other cations
PrSb, NdSb
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Samarium antimonide is a binary inorganic compound of samarium and antimony with the formula SmSb. It forms crystals.

Contents

Preparation

Samarium antimonide can be prepared by heating samarium and antimony in a vacuum:

Physical properties

Samarium antimonide forms cubic crystals, space group Fm3m, cell parameters a = 0.6271 nm, Z = 4, and structure like sodium chloride. [1] [2] [3]

The compound melts congruently at a temperature of ≈2000 °C [1] or 1922 °C. [3]

Related Research Articles

<span class="mw-page-title-main">Antimony</span> Chemical element, symbol Sb and atomic number 51

Antimony ( AN-tih-moh-nee, AN-tih-mə-nee) is a chemical element; it has symbol Sb (from Latin stibium) and atomic number 51. A lustrous gray metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3). Antimony compounds have been known since ancient times and were powdered for use as medicine and cosmetics, often known by the Arabic name kohl. The earliest known description of the metalloid in the West was written in 1540 by Vannoccio Biringuccio.

<span class="mw-page-title-main">Samarium</span> Chemical element, symbol Sm and atomic number 62

Samarium is a chemical element; it has symbol Sm and atomic number 62. It is a moderately hard silvery metal that slowly oxidizes in air. Being a typical member of the lanthanide series, samarium usually has the oxidation state +3. Compounds of samarium(II) are also known, most notably the monoxide SmO, monochalcogenides SmS, SmSe and SmTe, as well as samarium(II) iodide.

<span class="mw-page-title-main">Pnictogen</span> Group 15 elements of the periodic table with valency 5

A pnictogen is any of the chemical elements in group 15 of the periodic table. Group 15 is also known as the nitrogen group or nitrogen family. Group 15 consists of the elements nitrogen (N), phosphorus (P), arsenic (As), antimony (Sb), bismuth (Bi), and moscovium (Mc).

<span class="mw-page-title-main">Samarium(II) iodide</span> Chemical compound

Samarium(II) iodide is an inorganic compound with the formula SmI2. When employed as a solution for organic synthesis, it is known as Kagan's reagent. SmI2 is a green solid and solutions are green as well. It is a strong one-electron reducing agent that is used in organic synthesis.

<span class="mw-page-title-main">Antimony trisulfide</span> Chemical compound

Antimony trisulfide is found in nature as the crystalline mineral stibnite and the amorphous red mineral metastibnite. It is manufactured for use in safety matches, military ammunition, explosives and fireworks. It also is used in the production of ruby-colored glass and in plastics as a flame retardant. Historically the stibnite form was used as a grey pigment in paintings produced in the 16th century. In 1817, the dye and fabric chemist, John Mercer discovered the non-stoichiometric compound Antimony Orange, the first good orange pigment available for cotton fabric printing.

<span class="mw-page-title-main">Indium antimonide</span> Chemical compound

Indium antimonide (InSb) is a crystalline compound made from the elements indium (In) and antimony (Sb). It is a narrow-gap semiconductor material from the III-V group used in infrared detectors, including thermal imaging cameras, FLIR systems, infrared homing missile guidance systems, and in infrared astronomy. Indium antimonide detectors are sensitive to infrared wavelengths between 1 and 5 μm.

<span class="mw-page-title-main">Antimony trioxide</span> Chemical compound

Antimony(III) oxide is the inorganic compound with the formula Sb2O3. It is the most important commercial compound of antimony. It is found in nature as the minerals valentinite and senarmontite. Like most polymeric oxides, Sb2O3 dissolves in aqueous solutions with hydrolysis. A mixed arsenic-antimony oxide occurs in nature as the very rare mineral stibioclaudetite.

<span class="mw-page-title-main">Antimony oxychloride</span> Chemical compound

Antimony oxychloride, known since the 15th century, has been known by a plethora of alchemical names. Since the compound functions as both an emetic and a laxative, it was originally used as a purgative.

<span class="mw-page-title-main">Gallium antimonide</span> Chemical compound

Gallium antimonide (GaSb) is a semiconducting compound of gallium and antimony of the III-V family. It has a room temperature lattice constant of about 0.610 nm. It has a room temperature direct bandgap of approximately 0.73 eV.

<span class="mw-page-title-main">Samarium(III) fluoride</span> Chemical compound

Samarium(III) fluoride (SmF3) is a slightly hygroscopic solid fluoride. Conditions/substances to avoid are: open flame, moisture, strong acids.

<span class="mw-page-title-main">Stibarsen</span> Native element mineral

Stibarsen or allemontite is a natural form of arsenic antimonide (AsSb) or antimony arsenide (SbAs). The name stibarsen is derived from Latin stibium (antimony) and arsenic, whereas allemonite refers to the locality Allemont in France where the mineral was discovered. It is found in veins at Allemont, Isère, France; Valtellina, Italy; and the Comstock Lode, Nevada; and in a lithium pegmatites at Varuträsk, Sweden. Stibarsen is often mixed with pure arsenic or antimony, and the original description in 1941 proposed to use stibarsen for AsSb and allemontite for the mixtures. Since 1982, the International Mineralogical Association considers stibarsen as the correct mineral name.

Bismuth antimonides, Bismuth-antimonys, or Bismuth-antimony alloys, (Bi1−xSbx) are binary alloys of bismuth and antimony in various ratios.

Samarium(III) oxalate is an inorganic compound, a salt of samarium and oxalic acid with the formula Sm2(C2O4)3. The compound does not dissolve in water, forms a crystalline hydrate with yellow crystals.

Platinum-samarium is a binary inorganic compound of platinum and samarium with the chemical formula PtSm. This intermetallic compound forms crystals.

Samarium(III) phosphide is an inorganic compound of samarium and phosphorus with the chemical formula SmP.

Samarium compounds are compounds formed by the lanthanide metal samarium (Sm). In these compounds, samarium generally exhibits the +3 oxidation state, such as SmCl3, Sm(NO3)3 and Sm(C2O4)3. Compounds with samarium in the +2 oxidation state are also known, for example SmI2.

Samarium(III) molybdate is an inorganic compound, with the chemical formula Sm2(MoO4)3. It is one of the compounds formed by the three elements samarium, molybdenum and oxygen.

<span class="mw-page-title-main">Samarium(III) phosphate</span> Chemical compound

Samarium(III) phosphate is an inorganic compound, with the chemical formula of SmPO4. It is one of the phosphates of samarium.

<span class="mw-page-title-main">Praseodymium antimonide</span> Chemical compound

Praseodymium antimonide is a binary inorganic compound of praseodymium and antimony with the formula PrSb.

Gallium arsenide antimonide, also known as gallium antimonide arsenide or GaAsSb (GaAs1-xSbx), is a ternary III-V semiconductor compound. x indicates the fractions of arsenic and antimony in the alloy according to the aforementioned formula; it can take on any value between 0 and 1. GaAsSb refers generally to any composition of the alloy. It is considered as an alloy between gallium arsenide (GaAs) and gallium antimonide (GaSb).

References

  1. 1 2 Диаграммы состояния двойных металлических систем. Vol. 3 Книга 2. М.: Машиностроение. Под ред. Н. П. Лякишева. 2000. ISBN   5-217-02932-3.
  2. B. Predel (1998). "Sb-Sm (Antimony-Samarium)". Landolt-Börnstein - Group IV Physical Chemistry. 5J: 1–2. doi:10.1007/10551312_2677. ISBN   3-540-61742-6.
  3. 1 2 H. Okamoto (2000). "Sb-Sm (Antimony-Samarium)". Journal of Phase Equilibria. 21 (4): 414–415. doi:10.1361/105497100770340002.