Samarium(III) phosphide

Last updated
Samarium(III) phosphide
Names
Other names
Phosphanylidynesamarium, samarium monophosphide
Identifiers
3D model (JSmol)
ECHA InfoCard 100.031.869 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 235-069-8
PubChem CID
  • InChI=1S/P.Sm
    Key: QRVXKVFNBYFEOG-UHFFFAOYSA-N
  • P#[Sm]
Properties
PSm
Molar mass 181.3
AppearanceCrystals
Density 6.3 g/cm3
Insoluble
Structure
Cubic
Related compounds
Other anions
Samarium nitride
Samarium arsenide
Samarium antimonide
Samarium bismuthide
Other cations
Neodymium phosphide
Europium phosphide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Samarium(III) phosphide is an inorganic compound of samarium and phosphorus with the chemical formula SmP. [1] [2] [3]

Contents

Synthesis

Samarium(III) phosphide can be obtained by heating samarium and phosphorus:

4 Sm + P4 → 4 SmP

Physical properties

Samarium(III) phosphide forms crystals of a cubic system, space group Fm3m, cell size a = 0.5760 nm, Z = 4, with a structure similar to sodium chloride NaCl. [4]

The compound exists in the temperature range of 1315–2020 °C and has a homogeneity region described by the SmP1÷0.982. [5]

Chemical properties

Samarium(III) phosphide readily dissolves in nitric acid. [6]

Uses

Samarium(III) phosphide compound is a semiconductor used in high power, high frequency applications and in laser diodes. [1]

Related Research Articles

<span class="mw-page-title-main">Samarium</span> Chemical element, symbol Sm and atomic number 62

Samarium is a chemical element; it has symbol Sm and atomic number 62. It is a moderately hard silvery metal that slowly oxidizes in air. Being a typical member of the lanthanide series, samarium usually has the oxidation state +3. Compounds of samarium(II) are also known, most notably the monoxide SmO, monochalcogenides SmS, SmSe and SmTe, as well as samarium(II) iodide.

Titanium(III) phosphide (TiP) is an inorganic chemical compound of titanium and phosphorus. Normally encountered as a grey powder, it is a metallic conductor with a high melting point. It is not attacked by common acids or water. Its physical properties stand in contrast to the group 1 and group 2 phosphides that contain the P3− anion (such as Na3P), which are not metallic and are readily hydrolysed. Titanium phosphide is classified as a "metal-rich phosphide", where extra valence electrons from the metal are delocalised.

Strontium phosphide is an inorganic compound of strontium and phosphorus with the chemical formula Sr
3
P
2
. The compound looks like black crystalline material.

Samarium(III) bromide is a crystalline compound of one samarium and three bromine atoms with the chemical formula of SmBr3. Samarium(III) bromide is a dark brown powder at room temperature. The compound has a crystal structure isotypic to that of plutonium(III) bromide.

<span class="mw-page-title-main">Yttrium phosphide</span> Chemical compound

Yttrium phosphide is an inorganic compound of yttrium and phosphorus with the chemical formula YP. The compound may be also classified as yttrium(III) phosphide.

Lithium phosphide is an inorganic compound of lithium and phosphorus with the chemical formula Li
3
P
.

<span class="mw-page-title-main">Scandium phosphide</span> Chemical compound

Scandium phosphide is an inorganic compound of scandium and phosphorus with the chemical formula ScP.

Lutetium phosphide is an inorganic compound of lutetium and phosphorus with the chemical formula LuP. The compound forms dark crystals, does not dissolve in water.

Praseodymium monophosphide is an inorganic compound of praseodymium and phosphorus with the chemical formula PrP. The compound forms crystals.

Neodymium phosphide is an inorganic compound of neodymium and phosphorus with the chemical formula NdP.

Europium phosphide is an inorganic compound of europium and phosphorus with the chemical formula EuP. Other phosphides are also known.

<span class="mw-page-title-main">Lanthanum phosphide</span> Chemical compound

Lanthanum phosphide is an inorganic compound of lanthanum and phosphorus with the chemical formula LaP.

Ytterbium(III) phosphide is an inorganic compound of ytterbium and phosphorus with the chemical formula YbP. This is one of the phosphides of ytterbium.

Thulium phosphide is an inorganic compound of thulium and phosphorus with the chemical formula TmP.

Holmium phosphide is a binary inorganic compound of holmium and phosphorus with the chemical formula HoP. The compound forms dark crystals and does not dissolve in water.

Dysprosium phosphide is an inorganic compound of dysprosium and phosphorus with the chemical formula DyP.

Samarium(III) arsenide is a binary inorganic compound of samarium and arsenic with the chemical formula SmAs.

Samarium compounds are compounds formed by the lanthanide metal samarium (Sm). In these compounds, samarium generally exhibits the +3 oxidation state, such as SmCl3, Sm(NO3)3 and Sm(C2O4)3. Compounds with samarium in the +2 oxidation state are also known, for example SmI2.

Erbium compounds are compounds containing the element erbium (Er). These compounds are usually dominated by erbium in the +3 oxidation state, although the +2, +1 and 0 oxidation states have also been reported.

Ytterbium compounds are chemical compounds that contain the element ytterbium (Yb). The chemical behavior of ytterbium is similar to that of the rest of the lanthanides. Most ytterbium compounds are found in the +3 oxidation state, and its salts in this oxidation state are nearly colorless. Like europium, samarium, and thulium, the trihalides of ytterbium can be reduced to the dihalides by hydrogen, zinc dust, or by the addition of metallic ytterbium. The +2 oxidation state occurs only in solid compounds and reacts in some ways similarly to the alkaline earth metal compounds; for example, ytterbium(II) oxide (YbO) shows the same structure as calcium oxide (CaO).

References

  1. 1 2 "Samarium Phosphide". American Elements . Retrieved 21 December 2021.
  2. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. U.S. Government Printing Office. 1979. p. 49. Retrieved 21 December 2021.
  3. Freeman, A. J. (2 December 2012). The Actinides: Electronic Structure and Related Properties. Elsevier. p. 201. ISBN   978-0-323-15304-1 . Retrieved 21 December 2021.
  4. Donnay, Joseph Désiré Hubert (1963). Crystal Data; Determinative Tables. American Crystallographic Association. p. 888. Retrieved 21 December 2021.
  5. Predel, B. (1998). "P-Sm (Phosphorus-Samarium)". Ni-Np – Pt-Zr. Landolt-Börnstein - Group IV Physical Chemistry. p. 1. doi:10.1007/10542753_2381. ISBN   3-540-61712-4 . Retrieved 21 December 2021.{{cite book}}: |website= ignored (help)
  6. Soviet Progress in Chemistry. Faraday Press. 1966. p. 91. Retrieved 21 December 2021.