Neodymium phosphide

Last updated
Neodymium phosphide
Names
Other names
Neodymium monophosphide [1]
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.045.819 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 250-416-3
PubChem CID
  • InChI=1S/Nd.P
    Key: NCHWJDCPSSHPBO-UHFFFAOYSA-N
  • [Nd]#P
Properties
NdP
Molar mass 175.3 [2]
AppearanceCrystals
Density 5.68 g/cm3
Melting point 2,500 °C (4,530 °F; 2,770 K)
Structure
cubic
Related compounds
Other anions
Neodymium nitride
Neodymium arsenide
Neodymium antimonide
Neodymium bismuthide
Other cations
Praseodymium phosphide
Samarium phosphide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Neodymium phosphide is an inorganic compound of neodymium and phosphorus with the chemical formula NdP. [3] [4]

Contents

Preparation

Neodymium phosphide can be obtained by reacting neodymium and phosphorus in a stoichiometric ratio:

Physical properties

Neodymium phosphide forms cubic [5] crystals, space group Fm3m, cell parameters a = 0.5838 nm, Z = 4. [6]

Uses

The compound is a semiconductor used in high power, high frequency applications, and in laser diodes. [3] [7]

Related Research Articles

<span class="mw-page-title-main">Neodymium</span> Chemical element, symbol Nd and atomic number 60

Neodymium is a chemical element; it has symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth metals. It is a hard, slightly malleable, silvery metal that quickly tarnishes in air and moisture. When oxidized, neodymium reacts quickly producing pink, purple/blue and yellow compounds in the +2, +3 and +4 oxidation states. It is generally regarded as having one of the most complex spectra of the elements. Neodymium was discovered in 1885 by the Austrian chemist Carl Auer von Welsbach, who also discovered praseodymium. It is present in significant quantities in the minerals monazite and bastnäsite. Neodymium is not found naturally in metallic form or unmixed with other lanthanides, and it is usually refined for general use. Neodymium is fairly common—about as common as cobalt, nickel, or copper and is widely distributed in the Earth's crust. Most of the world's commercial neodymium is mined in China, as is the case with many other rare-earth metals.

Strontium phosphide is an inorganic compound of strontium and phosphorus with the chemical formula Sr
3
P
2
. The compound looks like black crystalline material.

<span class="mw-page-title-main">Yttrium phosphide</span> Chemical compound

Yttrium phosphide is an inorganic compound of yttrium and phosphorus with the chemical formula YP. The compound may be also classified as yttrium(III) phosphide.

Lithium phosphide is an inorganic compound of lithium and phosphorus with the chemical formula Li
3
P
.

<span class="mw-page-title-main">Scandium phosphide</span> Chemical compound

Scandium phosphide is an inorganic compound of scandium and phosphorus with the chemical formula ScP.

Lutetium phosphide is an inorganic compound of lutetium and phosphorus with the chemical formula LuP. The compound forms dark crystals, does not dissolve in water.

Praseodymium phosphide is an inorganic compound of praseodymium and phosphorus with the chemical formula PrP. The compound forms crystals.

Europium phosphide is an inorganic compound of europium and phosphorus with the chemical formula EuP. Other phosphides are also known.

Samarium(III) phosphide is an inorganic compound of samarium and phosphorus with the chemical formula SmP.

<span class="mw-page-title-main">Lanthanum phosphide</span> Chemical compound

Lanthanum phosphide is an inorganic compound of lanthanum and phosphorus with the chemical formula LaP.

Ytterbium(III) phosphide is an inorganic compound of ytterbium and phosphorus with the chemical formula YbP. This is one of the phosphides of ytterbium.

Thulium phosphide is an inorganic compound of thulium and phosphorus with the chemical formula TmP.

Holmium phosphide is a binary inorganic compound of holmium and phosphorus with the chemical formula HoP. The compound forms dark crystals and does not dissolve in water.

Erbium phosphide is a binary inorganic compound of erbium and phosphorus with the chemical formula ErP.

Dysprosium phosphide is an inorganic compound of dysprosium and phosphorus with the chemical formula DyP.

<span class="mw-page-title-main">Terbium phosphide</span> Erbium compound

Terbium phosphide is an inorganic compound of terbium and phosphorus with the chemical formula TbP.

Gadolinium phosphide is an inorganic compound of gadolinium and phosphorus with the chemical formula GdP.

<span class="mw-page-title-main">Neodymium(III) vanadate</span> Chemical compound

Neodymium(III) vanadate is an inorganic compound, a salt of neodymium and vanadic acid with the chemical formula of NdVO4. It forms pale-blue, hydrated crystals.

Erbium compounds are compounds containing the element erbium (Er). These compounds are usually dominated by erbium in the +3 oxidation state, although the +2, +1 and 0 oxidation states have also been reported.

Ytterbium compounds are chemical compounds that contain the element ytterbium (Yb). The chemical behavior of ytterbium is similar to that of the rest of the lanthanides. Most ytterbium compounds are found in the +3 oxidation state, and its salts in this oxidation state are nearly colorless. Like europium, samarium, and thulium, the trihalides of ytterbium can be reduced to the dihalides by hydrogen, zinc dust, or by the addition of metallic ytterbium. The +2 oxidation state occurs only in solid compounds and reacts in some ways similarly to the alkaline earth metal compounds; for example, ytterbium(II) oxide (YbO) shows the same structure as calcium oxide (CaO).

References

  1. "CAS Common Chemistry". commonchemistry.cas.org. Retrieved 14 December 2021.
  2. O'Bannon, Loran (6 December 2012). Dictionary of Ceramic Science and Engineering. Springer Science & Business Media. p. 174. ISBN   978-1-4613-2655-7 . Retrieved 14 December 2021.
  3. 1 2 "Neodymium Phosphide". American Elements . Retrieved 14 December 2021.
  4. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Cumulative Supplement to the Initial Inventory: User Guide and Indices. United States Environmental Protection Agency. 1980. p. 176. Retrieved 14 December 2021.
  5. Donnay, Joseph Désiré Hubert; Association, American Crystallographic (1963). Crystal Data; Determinative Tables. American Crystallographic Association. p. 891. Retrieved 14 December 2021.
  6. "mp-2823: NdP (cubic, Fm-3m, 225)". materialsproject.org . Retrieved 14 December 2021.
  7. Nilu, Nilesh Dhurve (20 September 2021). "Ground State and Electronic Properties of Neodymium Phosphide (NdP)". SPAST Abstracts. 1 (1). Retrieved 14 December 2021.