Neodymium(III) oxide

Neodymium(III) oxide

Names
IUPAC name Neodymium(III) oxide
Other names Neodymium oxide, Neodymium sesquioxide
Identifiers
CAS Number	1313-97-9  Y
3D model (JSmol)	Interactive image
ChemSpider	3407022
ECHA InfoCard	100.013.832
EC Number	215-214-1
PubChem CID	4196641
UNII	AYT3H319PN  Y
CompTox Dashboard (EPA)	DTXSID2051479
InChI InChI=1S/2Nd.3O Key: HBPPDPSYLUIKHU-UHFFFAOYSA-N
SMILES O=[Nd]O[Nd]=O
Properties
Chemical formula	Nd2O3
Molar mass	336.48 g/mol
Appearance	light bluish gray hexagonal crystals
Density	7.24 g/cm3
Melting point	2,233 °C (4,051 °F; 2,506 K)
Boiling point	3,760 °C (6,800 °F; 4,030 K) [1]
Solubility in water	.0003 g/100 mL (75 °C)
Magnetic susceptibility (χ)	+10,200.0·10−6 cm3/mol
Structure
Crystal structure	Hexagonal, hP5
Space group	P-3m1, No. 164
Thermochemistry
Heat capacity (C)	111.3 J·mol−1·K−1 [1]
Std molar entropy (S⦵298)	158.6 J·mol−1·K−1
Std enthalpy of formation (ΔfH⦵298)	−1807.9 kJ·mol−1
Related compounds
Other anions	Neodymium(II) chloride Neodymium(III) chloride
Other cations	Uranium(VI) oxide Praseodymium(III) oxide Promethium(III) oxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Y  verify  (what is  YN ?) Infobox references

Neodymium(III) oxide or neodymium sesquioxide is the chemical compound composed of neodymium and oxygen with the formula Nd₂O₃. It forms very light grayish-blue hexagonal crystals. ^[1] The rare-earth mixture didymium, previously believed to be an element, partially consists of neodymium(III) oxide. ^[2]

Uses

Neodymium(III) oxide is used to dope glass, including sunglasses, to make solid-state lasers, and to color glasses and enamels. ^[3] Neodymium-doped glass turns purple due to the absorbance of yellow and green light, and is used in welding goggles. ^[4] Some neodymium-doped glass is dichroic; that is, it changes color depending on the lighting. One kind of glass named for the mineral alexandrite appears blue in sunlight and red in artificial light. ^[5] About 7000 tonnes of neodymium(III) oxide are produced worldwide each year. Neodymium(III) oxide is also used as a polymerization catalyst. ^[4]

Reactions

Neodymium(III) oxide is formed when neodymium(III) nitride or neodymium(III) hydroxide is roasted in air. ^[6]

Structure

Neodymium(III) oxide has a low-temperature trigonal A form in space group P3m1. ^[7] This structure type is favoured by the early lanthanides. ^{[8] [9]} At higher temperatures it adopts two other forms, the hexagonal H form in space group P6₃/mmc and the cubic X form in Im3m. The high-temperature forms exhibit crystallographic disorder. ^{[10] [11]}

Crystal structure of the A form of neodymium(III) oxide

Packing	Neodymium coordination	Oxygen O1 coordination	Oxygen O2 coordination
A-M2O3 structure type	approximately capped octahedral	octahedral	approximately tetrahedral

References

1. Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, FL: CRC Press, pp. 471, 552, ISBN   0-8493-0594-2
2. Brady, George Stuart; Clauser, Henry R.; Vaccari, John A. (2002), Materials Handbook (15 ed.), New York: McGraw-Hill Professional, p. 779, ISBN   978-0-07-136076-0 , retrieved 2009-03-18
3. Eagleson, Mary (1994), Concise Encyclopedia of Chemistry, Springer, p. 680, ISBN   978-3-11-011451-5 , retrieved 2009-03-18
4. Emsley, John (2003), Nature's Building Blocks, Oxford University Press, pp. 268–9, ISBN   978-0-19-850340-8 , retrieved 2009-03-18
5. Bray, Charles (2001), Dictionary of Glass (2 ed.), University of Pennsylvania Press, p. 103, ISBN   978-0-8122-3619-4 , retrieved 2009-03-18
6. Spencer, James Frederick (1919), The Metals of the Rare Earths, London: Longmans, Green, and Co, p. 115, retrieved 2009-03-18
7. D. Taylor (1984). "Thermal Expansion Data: III Sesquioxides, U₂N₃, with the corundum and the A-, B- and C-M₂O₃ structures". Trans. J. Br. Ceram. Soc. 83: 92–98.
8. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 1238-1239. doi:10.1016/C2009-0-30414-6. ISBN   978-0-08-037941-8.
9. A. F. Wells (1984). Structural Inorganic Chemistry (5th ed.). Oxford University Press. pp. 544–547.
10. Müller-Buschbaum, H. (1966). "Zur Struktur der A-Form der Sesquioxide der Seltenen Erden. II. Strukturuntersuchung an Nd₂O₃". Z. Anorg. Allg. Chem. 343 (1–2): 6–10. doi:10.1002/zaac.19663430103.
11. Aldebert, P.; Traverse, J. P. (1979). "Etude par diffraction neutronique des structures de haute temperature de La₂O₃ et Nd₂O₃". Mater. Res. Bull. 14 (3): 303–323. doi:10.1016/0025-5408(79)90095-3.