Polonium monoxide

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Polonium monoxide
Names
Systematic IUPAC name
Polonium monoxide
Identifiers
3D model (JSmol)
  • [Po+2].[O-2]
Properties
PoO
Molar mass 224.98 g/mol
Appearanceblack solid [1] [2]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Polonium monoxide (also known as polonium(II) oxide) is a chemical compound with the formula Po O . It is one of three oxides of polonium, the other two being polonium dioxide (PoO2) and polonium trioxide (PoO3). It is an interchalcogen.

Contents

Appearance and preparation

Polonium monoxide is a black solid. It is formed during the radiolysis of polonium sulfite (PoSO3) and polonium selenite (PoSeO3). [1] [2]

Chemistry

On contact with oxygen or water, both polonium monoxide and its related hydroxide (polonium(II) hydroxide, Po(OH)2) are oxidized quickly to Po(IV). [2]

Related Research Articles

In chemistry, perxenates are salts of the yellow xenon-containing anion XeO4−
6
. This anion has octahedral molecular geometry, as determined by Raman spectroscopy, having O–Xe–O bond angles varying between 87° and 93°. The Xe–O bond length was determined by X-ray crystallography to be 1.875 Å.

<span class="mw-page-title-main">Tellurium dioxide</span> Chemical compound

Tellurium dioxide (TeO2) is a solid oxide of tellurium. It is encountered in two different forms, the yellow orthorhombic mineral tellurite, β-TeO2, and the synthetic, colourless tetragonal (paratellurite), α-TeO2. Most of the information regarding reaction chemistry has been obtained in studies involving paratellurite, α-TeO2.

<span class="mw-page-title-main">Titanium oxide</span> Index of chemical compounds with the same name

Titanium oxide may refer to:

In chemistry, a plumbate often refers to compounds that can be viewed as derivatives of the hypothetical PbO2−3 anion. The term also refers to any anion of lead or any salt thereof. So the term is vague and somewhat archaic.

<span class="mw-page-title-main">Tin(II) hydroxide</span> Chemical compound

Tin(II) hydroxide, Sn(OH)2, also known as stannous hydroxide, is an inorganic compound tin(II). The only related material for which definitive information is available is the oxy hydroxide Sn6O4(OH)4, but other related materials are claimed. They are all white solids that are insoluble in water.

Lead(II) hydroxide, Pb(OH)2, is a hydroxide of lead, with lead in oxidation state +2. In 1964 it was believed that such a simple compound did not exist, as lead basic carbonate (2PbCO3·Pb(OH)2) or lead(II) oxide (PbO) was encountered where lead hydroxide was expected. This has been a subject of considerable confusion in the past. However, subsequent research has demonstrated that lead(II) hydroxide does indeed exist as one of a series of lead hydroxides.

<span class="mw-page-title-main">Rubidium oxide</span> Chemical compound

Rubidium oxide is the chemical compound with the formula Rb2O. Rubidium oxide is highly reactive towards water, and therefore it would not be expected to occur naturally. The rubidium content in minerals is often calculated and quoted in terms of Rb2O. In reality, the rubidium is typically present as a component of (actually, an impurity in) silicate or aluminosilicate. A major source of rubidium is lepidolite, KLi2Al(Al,Si)3O10(F,OH)2, wherein Rb sometimes replaces K.

<span class="mw-page-title-main">Xenon trioxide</span> Chemical compound

Xenon trioxide is an unstable compound of xenon in its +6 oxidation state. It is a very powerful oxidizing agent, and liberates oxygen from water slowly, accelerated by exposure to sunlight. It is dangerously explosive upon contact with organic materials. When it detonates, it releases xenon and oxygen gas.

<span class="mw-page-title-main">Cobalt(II) hydroxide</span> Chemical compound

Cobalt(II) hydroxide or cobaltous hydroxide is the inorganic compound with the formula Co(OH)
2
, consisting of divalent cobalt cations Co2+
and hydroxide anions OH
. The pure compound, often called the "beta form" is a pink solid insoluble in water.

<span class="mw-page-title-main">Polonium dichloride</span> Chemical compound

Polonium dichloride is a chemical compound of the radioactive metalloid, polonium and chlorine. Its chemical formula is PoCl2. It is an ionic salt.

<span class="mw-page-title-main">Polonium hydride</span> Chemical compound

Polonium hydride (also known as polonium dihydride, hydrogen polonide, or polane) is a chemical compound with the formula PoH2. It is a liquid at room temperature, the second hydrogen chalcogenide with this property after water. It is very unstable chemically and tends to decompose into elemental polonium and hydrogen. It is a volatile and very labile compound, from which many polonides can be derived. Additionally, like all polonium compounds, it is highly radioactive.

<span class="mw-page-title-main">Polonium hexafluoride</span> Chemical compound

Polonium hexafluoride is a possible chemical compound of polonium and fluorine and one of the seventeen known binary hexafluorides.

The chalcogens react with each other to form interchalcogen compounds.

Polonium tetrachloride (also known as polonium(IV) chloride) is a chemical compound with the formula PoCl4. The salt is a hygroscopic bright yellow crystalline solid at room temperature. Above 200 °C, it tends to decompose into polonium dichloride and excess chlorine, similar to selenium tetrachloride and tellurium tetrachloride.

<span class="mw-page-title-main">Polonium dioxide</span> Chemical compound

Polonium dioxide (also known as polonium(IV) oxide) is a chemical compound with the formula PoO2. It is one of three oxides of polonium, the other two being polonium monoxide (PoO) and polonium trioxide (PoO3). It is a pale yellow crystalline solid at room temperature. Under lowered pressure (such as a vacuum), it decomposes into elemental polonium and oxygen at 500 °C. It is the most stable oxide of polonium and is an interchalcogen.

Polonium trioxide (also known as polonium(VI) oxide) is a chemical compound with the formula PoO3. It is one of three oxides of polonium, the other two being polonium monoxide (PoO) and polonium dioxide (PoO2). It is an interchalcogen that has so far only been detected in trace amounts.

Polonium dibromide (also known as polonium(II) bromide) is a chemical compound with the formula PoBr2. This salt is a purple-brown crystalline solid at room temperature. It sublimes (decomposing slightly) at 110 °C/30 μ and decomposes when melted in nitrogen gas at 270–280 °C.

<span class="mw-page-title-main">Post-transition metal</span> Category of metallic elements

The metallic elements in the periodic table located between the transition metals to their left and the chemically weak nonmetallic metalloids to their right have received many names in the literature, such as post-transition metals, poor metals, other metals, p-block metals and chemically weak metals. The most common name, post-transition metals, is generally used in this article.

<span class="mw-page-title-main">Dibromine monoxide</span> Chemical compound

Dibromine monoxide is the chemical compound composed of bromine and oxygen with the formula Br2O. It is a dark brown solid which is stable below −40 °C and is used in bromination reactions. It is similar to dichlorine monoxide, the monoxide of its halogen neighbor one period higher on the periodic table. The molecule is bent, with C2v molecular symmetry. The Br−O bond length is 1.85 Å and the Br−O−Br bond angle is 112°, similar to dichlorine monoxide.

Polonium sulfide is an inorganic compound of polonium and sulfur with the chemical formula PoS. The compound is radioactive and forms black crystals.

References

  1. 1 2 Holleman, Arnold Frederik; Wiberg, Egon (2001), Wiberg, Nils (ed.), Inorganic Chemistry, translated by Eagleson, Mary; Brewer, William, San Diego/Berlin: Academic Press/De Gruyter, p. 594, ISBN   0-12-352651-5
  2. 1 2 3 Bagnall, K. W. (1962). "The Chemistry of Polonium". Advances in Inorganic Chemistry and Radiochemistry. New York: Academic Press. pp. 197–230. ISBN   9780120236046 . Retrieved June 15, 2012.