Dysprosium phosphide

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Dysprosium phosphide
Names
Other names
Dysprosium monophosphide, phosphanylidynedysprosium
Identifiers
3D model (JSmol)
EC Number
  • 234-650-3
PubChem CID
  • InChI=1S/Dy.P
    Key: NAUXLTDHJZDBHT-UHFFFAOYSA-N
  • P#[Dy]
Properties
DyP
Molar mass 193.474
AppearanceCrystals
Density 7.06 g/cm3
Structure
Cubic
Hazards
GHS labelling:
GHS-pictogram-exclam.svg
Warning
H315, H319, H335
P261, P280, P304, P305, P338, P340, P351, P405, P501
Related compounds
Other anions
Dysprosium nitride
Dysprosium arsenide
Dysprosium antimonide
Dysprosium bismuthide
Other cations
Terbium phosphide
Holmium phosphide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Dysprosium phosphide is an inorganic compound of dysprosium and phosphorus with the chemical formula DyP. [1] [2] [3]

Contents

Synthesis

The compound can be obtained by the reaction of phosphorus and dysprosium at high temperature.

4 Dy + P4 → 4 DyP

Physical properties

DyP has a NaCl structure (a=5.653 Å), [4] where dysprosium is +3 valence. Its band gap is 1.15 eV, and the Hall mobility (μH) is 8.5 cm3/V·s. [5]

DyP forms crystals of a cubic system, space group Fm3m. [6]

Uses

The compound is a semiconductor used in high power, high frequency applications and in laser diodes. [1] [7]

Related Research Articles

<span class="mw-page-title-main">Dysprosium</span> Chemical element, symbol Dy and atomic number 66

Dysprosium is a chemical element; it has symbol Dy and atomic number 66. It is a rare-earth element in the lanthanide series with a metallic silver luster. Dysprosium is never found in nature as a free element, though, like other lanthanides, it is found in various minerals, such as xenotime. Naturally occurring dysprosium is composed of seven isotopes, the most abundant of which is 164Dy.

<span class="mw-page-title-main">Phosphorus</span> Chemical element, symbol P and atomic number 15

Phosphorus is a chemical element; it has symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Earth. It has a concentration in the Earth's crust of about one gram per kilogram. In minerals, phosphorus generally occurs as phosphate.

<span class="mw-page-title-main">Phosphine</span> Chemical compound hydrogen phosphide

Phosphine (IUPAC name: phosphane) is a colorless, flammable, highly toxic compound with the chemical formula PH3, classed as a pnictogen hydride. Pure phosphine is odorless, but technical grade samples have a highly unpleasant odor like rotting fish, due to the presence of substituted phosphine and diphosphane (P2H4). With traces of P2H4 present, PH3 is spontaneously flammable in air (pyrophoric), burning with a luminous flame. Phosphine is a highly toxic respiratory poison, and is immediately dangerous to life or health at 50 ppm. Phosphine has a trigonal pyramidal structure.

<span class="mw-page-title-main">Indium phosphide</span> Chemical compound

Indium phosphide (InP) is a binary semiconductor composed of indium and phosphorus. It has a face-centered cubic ("zincblende") crystal structure, identical to that of GaAs and most of the III-V semiconductors.

<span class="mw-page-title-main">Phosphide</span>

In chemistry, a phosphide is a compound containing the P3− ion or its equivalent. Many different phosphides are known, with widely differing structures. Most commonly encountered on the binary phosphides, i.e. those materials consisting only of phosphorus and a less electronegative element. Numerous are polyphosphides, which are solids consisting of anionic chains or clusters of phosphorus. Phosphides are known with the majority of less electronegative elements with the exception of Hg, Pb, Sb, Bi, Te, and Po. Finally, some phosphides are molecular.

<span class="mw-page-title-main">Boron phosphide</span> Chemical compound

Boron phosphide (BP) (also referred to as boron monophosphide, to distinguish it from boron subphosphide, B12P2) is a chemical compound of boron and phosphorus. It is a semiconductor.

<span class="mw-page-title-main">Zinc phosphide</span> Chemical compound

Zinc phosphide (Zn3P2) is an inorganic chemical compound. It is a grey solid, although commercial samples are often dark or even black. It is used as a rodenticide. Zn3P2 is a II-V semiconductor with a direct band gap of 1.5 eV and may have applications in photovoltaic cells. A second compound exists in the zinc-phosphorus system, zinc diphosphide (ZnP2).

Dysprosium(III) fluoride is an inorganic compound of dysprosium with a chemical formula DyF3.

Dysprosium(II) chloride (DyCl2), also known as dysprosium dichloride, is an ionic chemical compound of dysprosium and chlorine. This salt is a reduced compound, as the normal oxidation state of dysprosium in dysprosium compounds is +3.

<span class="mw-page-title-main">Dysprosium(III) nitrate</span> Chemical compound

Dysprosium(III) nitrate is an inorganic compound, a salt of dysprosium and nitric acid with the chemical formula Dy(NO3)3. The compound forms yellowish crystals, dissolves in water, forms a crystalline hydrate.

Phosphide silicides or silicide phosphides or silicophosphides are compounds containing anions composed of silicide (Si4−) and phosphide (P3−). They can be considered as mixed anion compounds. They are distinct from the phosphidosilicates, which have the phosphorus bonded to the silicon. Related compounds include the phosphide carbides, germanide phosphides, nitride silicides, and antimonide silicides.

Lithium phosphide is an inorganic compound of lithium and phosphorus with the chemical formula Li
3
P
.

<span class="mw-page-title-main">Scandium phosphide</span> Chemical compound

Scandium phosphide is an inorganic compound of scandium and phosphorus with the chemical formula ScP.

Praseodymium phosphide is an inorganic compound of praseodymium and phosphorus with the chemical formula PrP. The compound forms crystals.

Neodymium phosphide is an inorganic compound of neodymium and phosphorus with the chemical formula NdP.

Niobium phosphide is an inorganic compound of niobium and phosphorus with the chemical formula NbP.

Samarium phosphide is an inorganic compound of samarium and phosphorus with the chemical formula SmP.

<span class="mw-page-title-main">Lanthanum phosphide</span> Chemical compound

Lanthanum phosphide is an inorganic compound of lanthanum and phosphorus with the chemical formula LaP.

Holmium phosphide is a binary inorganic compound of holmium and phosphorus with the chemical formula HoP. The compound forms dark crystals and does not dissolve in water.

<span class="mw-page-title-main">Terbium compounds</span> Chemical compounds with at least one terbium atom

Terbium compounds are compounds formed by the lanthanide metal terbium (Tb). Terbium generally exhibits the +3 oxidation state in these compounds, such as in TbCl3, Tb(NO3)3 and Tb(CH3COO)3. Compounds with terbium in the +4 oxidation state are also known, such as TbO2 and BaTbF6. Terbium can also form compounds in the 0, +1 and +2 oxidation states.

References

  1. 1 2 "Dysprosium Phosphide". American Elements . Retrieved 5 January 2022.
  2. Ganjali, Mohammad Reza; Gupta, Vinod Kumar; Faridbod, Farnoush; Norouzi, Parviz (25 February 2016). Lanthanides Series Determination by Various Analytical Methods. Elsevier. p. 49. ISBN   978-0-12-420095-1 . Retrieved 5 January 2022.
  3. Terahertz and Gigahertz Photonics. SPIE. 1999. p. 217. ISBN   978-0-8194-3281-0 . Retrieved 5 January 2022.
  4. Busch, G.; Junod, P.; Vogt, O.; Hulliger, F. (15 August 1963). "Ferro- and metamagnetism of rare earth compounds" . Physics Letters. 6 (1): 79–80. Bibcode:1963PhL.....6...79B. doi:10.1016/0031-9163(63)90228-2 . Retrieved 5 January 2022.
  5. Ren, Yufang; Meng, Jian (1988). "On the Optical and Electrical Properties of Dysprosium and Ytterbium Monophosphides". Chinese Journal of Applied Chemistry (in Chinese). 5 (3): 39–42. Retrieved 5 January 2022.
  6. "Dysprosium Phosphide DyP". materialsproject.org . Retrieved 24 December 2021.
  7. "Dysprosium - an overview | ScienceDirect Topics". sciencedirect.com . Retrieved 5 January 2022.