Names | |
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Other names Dysprosium monophosphide, phosphanylidynedysprosium | |
Identifiers | |
3D model (JSmol) | |
EC Number |
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PubChem CID | |
CompTox Dashboard (EPA) | |
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Properties | |
DyP | |
Molar mass | 193.474 |
Appearance | Crystals |
Density | 7.06 g/cm3 |
Structure | |
Cubic | |
Hazards | |
GHS labelling: | |
Warning | |
H315, H319, H335 | |
P261, P280, P304, P305, P338, P340, P351, P405, P501 | |
Related compounds | |
Other anions | Dysprosium nitride Dysprosium arsenide Dysprosium antimonide Dysprosium bismuthide |
Other cations | Terbium phosphide Holmium phosphide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Dysprosium phosphide is an inorganic compound of dysprosium and phosphorus with the chemical formula DyP. [1] [2] [3]
The compound can be obtained by the reaction of phosphorus and dysprosium at high temperature.
DyP has a NaCl structure (a=5.653 Å), [4] where dysprosium is +3 valence. Its band gap is 1.15 eV, and the Hall mobility (μH) is 8.5 cm3/V·s. [5]
DyP forms crystals of a cubic system, space group Fm3m. [6]
The compound is a semiconductor used in high power, high frequency applications and in laser diodes. [1] [7]
Dysprosium is a chemical element; it has symbol Dy and atomic number 66. It is a rare-earth element in the lanthanide series with a metallic silver luster. Dysprosium is never found in nature as a free element, though, like other lanthanides, it is found in various minerals, such as xenotime. Naturally occurring dysprosium is composed of seven isotopes, the most abundant of which is 164Dy.
Phosphorus is a chemical element; it has symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Earth. It has a concentration in the Earth's crust of about one gram per kilogram. In minerals, phosphorus generally occurs as phosphate.
Phosphine (IUPAC name: phosphane) is a colorless, flammable, highly toxic compound with the chemical formula PH3, classed as a pnictogen hydride. Pure phosphine is odorless, but technical grade samples have a highly unpleasant odor like rotting fish, due to the presence of substituted phosphine and diphosphane (P2H4). With traces of P2H4 present, PH3 is spontaneously flammable in air (pyrophoric), burning with a luminous flame. Phosphine is a highly toxic respiratory poison, and is immediately dangerous to life or health at 50 ppm. Phosphine has a trigonal pyramidal structure.
Dysprosium(III) chloride (DyCl3), also known as dysprosium trichloride, is a compound of dysprosium and chlorine. It is a white to yellow solid which rapidly absorbs water on exposure to moist air to form a hexahydrate, DyCl3·6H2O. Simple rapid heating of the hydrate causes partial hydrolysis to an oxychloride, DyOCl.
In chemistry, a phosphide is a compound containing the P3− ion or its equivalent. Many different phosphides are known, with widely differing structures. Most commonly encountered on the binary phosphides, i.e. those materials consisting only of phosphorus and a less electronegative element. Numerous are polyphosphides, which are solids consisting of anionic chains or clusters of phosphorus. Phosphides are known with the majority of less electronegative elements with the exception of Hg, Pb, Sb, Bi, Te, and Po. Finally, some phosphides are molecular.
Boron phosphide (BP) (also referred to as boron monophosphide, to distinguish it from boron subphosphide, B12P2) is a chemical compound of boron and phosphorus. It is a semiconductor.
Zinc phosphide (Zn3P2) is an inorganic chemical compound. It is a grey solid, although commercial samples are often dark or even black. It is used as a rodenticide. Zn3P2 is a II-V semiconductor with a direct band gap of 1.5 eV and may have applications in photovoltaic cells. A second compound exists in the zinc-phosphorus system, zinc diphosphide (ZnP2).
Dysprosium(III) fluoride is an inorganic compound of dysprosium with a chemical formula DyF3.
Dysprosium(II) chloride (DyCl2), also known as dysprosium dichloride, is an ionic chemical compound of dysprosium and chlorine. This salt is a reduced compound, as the normal oxidation state of dysprosium in dysprosium compounds is +3.
Dysprosium(III) nitrate is an inorganic compound, a salt of dysprosium and nitric acid with the chemical formula Dy(NO3)3. The compound forms yellowish crystals, dissolves in water, forms a crystalline hydrate.
Phosphide silicides or silicide phosphides or silicophosphides are compounds containing anions composed of silicide (Si4−) and phosphide (P3−). They can be considered as mixed anion compounds. They are distinct from the phosphidosilicates, which have the phosphorus bonded to the silicon. Related compounds include the phosphide carbides, germanide phosphides, nitride silicides, and antimonide silicides.
Phosphide carbides or carbide phosphides are compounds containing anions composed of carbide (C4−) and phosphide (P3−). They can be considered as mixed anion compounds. Related compounds include the phosphide silicides, germanide phosphides, arsenide carbides, nitride carbides and silicide carbides.
Lithium phosphide is an inorganic compound of lithium and phosphorus with the chemical formula Li
3P. This dark colored compound is formally the Li+ salt of P3-. It is a hazardous to handle because of its high reactivity toward air.
Scandium phosphide is an inorganic compound of scandium and phosphorus with the chemical formula ScP.
Neodymium phosphide is an inorganic compound of neodymium and phosphorus with the chemical formula NdP.
Niobium phosphide is an inorganic compound of niobium and phosphorus with the chemical formula NbP.
Samarium(III) phosphide is an inorganic compound of samarium and phosphorus with the chemical formula SmP.
Lanthanum phosphide is an inorganic compound of lanthanum and phosphorus with the chemical formula LaP.
Terbium compounds are compounds formed by the lanthanide metal terbium (Tb). Terbium generally exhibits the +3 oxidation state in these compounds, such as in TbCl3, Tb(NO3)3 and Tb(CH3COO)3. Compounds with terbium in the +4 oxidation state are also known, such as TbO2 and BaTbF6. Terbium can also form compounds in the 0, +1 and +2 oxidation states.
Dypsrosium nitride is a binary inorganic compound of dysprosium and nitride with the chemical formula DyN.