Dysprosium(III) sulfide

Last updated
Dysprosium(III) sulfide
Names
Other names
Didysprosium trisulfide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.995 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 235-208-2
PubChem CID
  • InChI=1S/3Dy.3S/q;2*+3;3*-2
    Key: SVCBLQQYIMDMCB-UHFFFAOYSA-N
  • [Dy+3].[Dy+3].[S-2].[S-2].[S-2]
Properties
Dy2S3
Molar mass 421.18 g·mol−1
Appearancebrown crystals
Density 6.08 g/cm3
moderately soluble
Related compounds
Related compounds
Lanthanum(III) sulfide
Hazards
GHS labelling:
GHS-pictogram-flamme.svg GHS-pictogram-exclam.svg
Danger
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Dysprosium(III) sulfide is a binary inorganic compound of dysprosium and sulfur with the chemical formula Dy2S3. [1] [2] [3] [4]

Contents

Synthesis

Heating of pure substances in an inert atmosphere or vacuum:

2Dy + 3S → Dy2S3

The effect of hydrogen sulfide on dysprosium(III) oxide:

Dy2O3 + 3H2S → Dy2S3 + 3H2O

Physical properties

Didysprosium trisulfide forms yellow-orange-brown crystals of two modifications: cubic and monoclinic systems. [5]

There is evidence that Dy2S3 forms crystals of brown-red, black, or green color.

The crystals are stable in dry air, but in humid air they are slowly hydrolyzed. The compound is moderately soluble in water and acids. [6]

Chemical properties

Dy2S3 oxidizes when strongly heated in air:

Dy2S3 + 3O2 → Dy2O2S + 2SO2

Related Research Articles

<span class="mw-page-title-main">Dysprosium</span> Chemical element with atomic number 66 (Dy)

Dysprosium is a chemical element; it has symbol Dy and atomic number 66. It is a rare-earth element in the lanthanide series with a metallic silver luster. Dysprosium is never found in nature as a free element, though, like other lanthanides, it is found in various minerals, such as xenotime. Naturally occurring dysprosium is composed of seven isotopes, the most abundant of which is 164Dy.

<span class="mw-page-title-main">Holmium</span> Chemical element with atomic number 67 (Ho)

Holmium is a chemical element; it has symbol Ho and atomic number 67. It is a rare-earth element and the eleventh member of the lanthanide series. It is a relatively soft, silvery, fairly corrosion-resistant and malleable metal. Like many other lanthanides, holmium is too reactive to be found in native form, as pure holmium slowly forms a yellowish oxide coating when exposed to air. When isolated, holmium is relatively stable in dry air at room temperature. However, it reacts with water and corrodes readily, and also burns in air when heated.

<span class="mw-page-title-main">Thallium</span> Chemical element with atomic number 81 (Tl)

Thallium is a chemical element; it has symbol Tl and atomic number 81. It is a gray post-transition metal that is not found free in nature. When isolated, thallium resembles tin, but discolors when exposed to air. Chemists William Crookes and Claude-Auguste Lamy discovered thallium independently in 1861, in residues of sulfuric acid production. Both used the newly developed method of flame spectroscopy, in which thallium produces a notable green spectral line. Thallium, from Greek θαλλός, thallós, meaning "green shoot" or "twig", was named by Crookes. It was isolated by both Lamy and Crookes in 1862; Lamy by electrolysis, and Crookes by precipitation and melting of the resultant powder. Crookes exhibited it as a powder precipitated by zinc at the international exhibition, which opened on 1 May that year.

<span class="mw-page-title-main">Pnictogen</span> Group 15 elements of the periodic table with valency 5

A pnictogen is any of the chemical elements in group 15 of the periodic table. Group 15 is also known as the nitrogen group or nitrogen family. Group 15 consists of the elements nitrogen (N), phosphorus (P), arsenic (As), antimony (Sb), bismuth (Bi), and moscovium (Mc).

<span class="mw-page-title-main">Lead(II) sulfide</span> Chemical compound

Lead(II) sulfide is an inorganic compound with the formula PbS. Galena is the principal ore and the most important compound of lead. It is a semiconducting material with niche uses.

<span class="mw-page-title-main">Mercury(II) oxide</span> Chemical compound

Mercury(II) oxide, also called mercuric oxide or simply mercury oxide, is the inorganic compound with the formula HgO. It has a red or orange color. Mercury(II) oxide is a solid at room temperature and pressure. The mineral form montroydite is very rarely found.

<span class="mw-page-title-main">Cadmium fluoride</span> Chemical compound

Cadmium fluoride (CdF2) is a mostly water-insoluble source of cadmium used in oxygen-sensitive applications, such as the production of metallic alloys. In extremely low concentrations (ppm), this and other fluoride compounds are used in limited medical treatment protocols. Fluoride compounds also have significant uses in synthetic organic chemistry. The standard enthalpy has been found to be -167.39 kcal. mole−1 and the Gibbs energy of formation has been found to be -155.4 kcal. mole−1, and the heat of sublimation was determined to be 76 kcal. mole−1.

Dysprosium(II) chloride (DyCl2), also known as dysprosium dichloride, is an ionic chemical compound of dysprosium and chlorine. This salt is a reduced compound, as the normal oxidation state of dysprosium in dysprosium compounds is +3.

<span class="mw-page-title-main">Dysprosium(III) nitrate</span> Chemical compound

Dysprosium(III) nitrate is an inorganic compound, a salt of dysprosium and nitric acid with the chemical formula Dy(NO3)3. The compound forms yellowish crystals, dissolves in water, forms a crystalline hydrate.

Polonium tetraiodide is a binary inorganic compound of polonium and iodine with the chemical formula PoI
4
. The compound forms volatile black crystals.

Lutetium phosphide is an inorganic compound of lutetium and phosphorus with the chemical formula LuP. The compound forms dark crystals, does not dissolve in water.

Samarium(III) phosphide is an inorganic compound of samarium and phosphorus with the chemical formula SmP.

Ytterbium(III) phosphide is an inorganic compound of ytterbium and phosphorus with the chemical formula YbP. This is one of the phosphides of ytterbium.

Holmium phosphide is a binary inorganic compound of holmium and phosphorus with the chemical formula HoP. The compound forms dark crystals and does not dissolve in water.

Cobalt arsenide is a binary inorganic compound of cobalt and arsenic with the chemical formula CoAs. The compound occurs naturally as the mineral modderite.

Erbium compounds are compounds containing the element erbium (Er). These compounds are usually dominated by erbium in the +3 oxidation state, although the +2, +1 and 0 oxidation states have also been reported.

Ytterbium compounds are chemical compounds that contain the element ytterbium (Yb). The chemical behavior of ytterbium is similar to that of the rest of the lanthanides. Most ytterbium compounds are found in the +3 oxidation state, and its salts in this oxidation state are nearly colorless. Like europium, samarium, and thulium, the trihalides of ytterbium can be reduced to the dihalides by hydrogen, zinc dust, or by the addition of metallic ytterbium. The +2 oxidation state occurs only in solid compounds and reacts in some ways similarly to the alkaline earth metal compounds; for example, ytterbium(II) oxide (YbO) shows the same structure as calcium oxide (CaO).

Holmium nitride is a binary inorganic compound of holmium and nitrogen with the chemical formula HoN.

<span class="mw-page-title-main">Molybdenum monophosphide</span> Chemical compound

Molybdenum monophosphide is a binary inorganic compound of molybdenum metal and phosphorus with the chemical formula MoP.

<span class="mw-page-title-main">Dysprosium monosulfide</span> Chemical compound

Dysprosium monosulfide is a binary inorganic compound of dysprosium and sulfur with the chemical formula DyS.

References

  1. Bouroushian, Mirtat (23 April 2010). Electrochemistry of Metal Chalcogenides. Springer Science & Business Media. p. 32. ISBN   978-3-642-03967-6 . Retrieved 1 August 2024.
  2. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Cumulative Supplement to the Initial Inventory: User Guide and Indices. U.S. Environmental Protection Agency, Office of Toxic Substances. 1980. p. 128. Retrieved 1 August 2024.
  3. "Dysprosium Sulfide". American Elements . Retrieved 1 August 2024.
  4. "WebElements Periodic Table » Dysprosium » didysprosium trisulphide". webelements.com. Retrieved 1 August 2024.
  5. Haynes, William M. (4 June 2014). CRC Handbook of Chemistry and Physics. CRC Press. p. 4-63. ISBN   978-1-4822-0868-9 . Retrieved 1 August 2024.
  6. "Buy DYSPROSIUM SULFIDE | 12133-06-1 | BenchChem". benchchem.com. Retrieved 1 August 2024.