Nickel sulfide

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Nickel sulfide
Nickel-sulfide-xtal-unit-cell-3D-bs-17.png
Names
IUPAC name
Nickel(II) sulfide
Other names
nickel sulfide, nickel monosulfide, nickelous sulfide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.037.113 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 234-349-7
PubChem CID
RTECS number
  • QR9705000
UNII
  • [Ni]=S
  • [Ni+2].[S-2]
Properties
NiS
Molar mass 90.7584 g mol−1
Appearanceblack solid
Odor Odorless
Density 5.87 g/cm3
Melting point 797 °C (1,467 °F; 1,070 K)
Boiling point 1,388 °C (2,530 °F; 1,661 K)
insoluble
Solubility degraded by nitric acid
+190.0·10−6 cm3/mol
Structure
hexagonal
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
may cause cancer by inhalation
GHS labelling:
GHS-pictogram-exclam.svg
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Nickel sulfide is any inorganic compound with the formula NiSx. These compounds range in color from bronze (Ni3S2) to black (NiS2). The nickel sulfide with simplest stoichiometry is NiS, also known as the mineral millerite. From the economic perspective, Ni9S8, the mineral pentlandite, is the chief source of mined nickel. Other minerals include heazlewoodite (Ni3S2) and polydymite (Ni3S4), and the mineral Vaesite (NiS2). [1] Some nickel sulfides are used commercially as catalysts.

Contents

Structure

Like many related materials, nickel sulfide adopts the nickel arsenide motif. In this structure, nickel is octahedral and the sulfide centers are in trigonal prismatic sites. [2]

Coordination environments in nickel sulfide
NickelSulfur
Nickel-sulfide-xtal-Ni-coordination-3D-bs-17.png Nickel-sulfide-xtal-S-coordination-3D-bs-17.png
octahedral trigonal prismatic

NiS has two polymorphs. The α-phase has a hexagonal unit cell, while the β-phase has a rhombohedral cell. The α-phase is stable at temperatures above 379 °C (714 °F), and converts into the β-phase at lower temperatures. That phase transition causes an increase in volume by 2–4%. [3] [4] [5]

Synthesis and reactions

The precipitation of solid black nickel sulfide is a mainstay of traditional qualitative inorganic analysis schemes, which begins with the separation of metals on the basis of the solubility of their sulfides. Such reactions are written: [6]

Ni2+ + H2S → NiS + 2 H+

Many other more controlled methods have been developed, including solid state metathesis reactions (from NiCl2 and Na2S) and high temperature reactions of the elements. [7]

The most commonly practiced reaction of nickel sulfides involves conversion to nickel oxides. This conversion involves heating the sulfide ores in air: [1]

NiS + 1.5 O2 → NiO + SO2

Occurrence

Natural

The mineral millerite is also a nickel sulfide with the molecular formula NiS, although its structure differs from synthetic stoichiometric NiS due to the conditions under which it forms. It occurs naturally in low temperature hydrothermal systems, in cavities of carbonate rocks, and as a byproduct of other nickel minerals. [8]

Millerite crystals Millerite-Chalcopyrite-Calcite-284770.jpg
Millerite crystals

In glass manufacturing

Float glass contains a small amount of nickel sulfide, formed from the sulfur in the fining agent Na
2
SO
4
and the nickel contained in metallic alloy contaminants. [9]

Nickel sulfide inclusions are a problem for tempered glass applications. After the tempering process, nickel sulfide inclusions are in the metastable alpha phase. The inclusions eventually convert to the beta phase (stable at low temperature), increasing in volume and causing cracks in the glass. In the middle of tempered glass, the material is under tension, which causes the cracks to propagate and leads to spontaneous glass fracture. [10] That spontaneous fracture occurs years or decades after glass manufacturing. [9]

Related Research Articles

Nickel hydride is either an inorganic compound of the formula NiHx or any of a variety of coordination complexes. It was discovered by Polish chemist Bogdan Baranowski in 1958.

Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. Sulfide also refers to large families of inorganic and organic compounds, e.g. lead sulfide and dimethyl sulfide. Hydrogen sulfide (H2S) and bisulfide (SH) are the conjugate acids of sulfide.

The iron–sulfur world hypothesis is a set of proposals for the origin of life and the early evolution of life advanced in a series of articles between 1988 and 1992 by Günter Wächtershäuser, a Munich patent lawyer with a degree in chemistry, who had been encouraged and supported by philosopher Karl R. Popper to publish his ideas. The hypothesis proposes that early life may have formed on the surface of iron sulfide minerals, hence the name. It was developed by retrodiction from extant biochemistry in conjunction with chemical experiments.

<span class="mw-page-title-main">Silver sulfide</span> Chemical compound

Silver sulfide is an inorganic compound with the formula Ag
2
S
. A dense black solid, it is the only sulfide of silver. It is useful as a photosensitizer in photography. It constitutes the tarnish that forms over time on silverware and other silver objects. Silver sulfide is insoluble in most solvents, but is degraded by strong acids. Silver sulfide is a network solid made up of silver and sulfur where the bonds have low ionic character.

<span class="mw-page-title-main">Arsenic trisulfide</span> Chemical compound

Arsenic trisulfide is the inorganic compound with the formula As2S3. It is a dark yellow solid that is insoluble in water. It also occurs as the mineral orpiment, which has been used as a pigment called King's yellow. It is produced in the analysis of arsenic compounds. It is a group V/VI, intrinsic p-type semiconductor and exhibits photo-induced phase-change properties.

<span class="mw-page-title-main">Polysulfide</span>

Polysulfides are a class of chemical compounds derived from anionic chains of sulfur atoms. There are two main classes of polysulfides: inorganic and organic. The inorganic polysulfides have the general formula S2−
n
. These anions are the conjugate bases of polysulfanes H2Sn. Organic polysulfides generally have the formulae R1SnR2, where R = alkyl or aryl.

<span class="mw-page-title-main">Chalcogenide</span>

A chalcogenide is a chemical compound consisting of at least one chalcogen anion and at least one more electropositive element. Although all group 16 elements of the periodic table are defined as chalcogens, the term chalcogenide is more commonly reserved for sulfides, selenides, tellurides, and polonides, rather than oxides. Many metal ores exist as chalcogenides. Photoconductive chalcogenide glasses are used in xerography. Some pigments and catalysts are also based on chalcogenides. The metal dichalcogenide MoS2 is a common solid lubricant.

<span class="mw-page-title-main">Iron(III) fluoride</span> Chemical compound

Iron(III) fluoride, also known as ferric fluoride, are inorganic compounds with the formula FeF3(H2O)x where x = 0 or 3. They are mainly of interest by researchers, unlike the related iron(III) chloride. Anhydrous iron(III) fluoride is white, whereas the hydrated forms are light pink.

<span class="mw-page-title-main">Copper monosulfide</span> Chemical compound

Copper monosulfide is a chemical compound of copper and sulfur. It was initially thought to occur in nature as the dark indigo blue mineral covellite. However, it was later shown to be rather a cuprous compound, formula Cu+3S(S2). CuS is a moderate conductor of electricity. A black colloidal precipitate of CuS is formed when hydrogen sulfide, H2S, is bubbled through solutions of Cu(II) salts. It is one of a number of binary compounds of copper and sulfur (see copper sulfide for an overview of this subject), and has attracted interest because of its potential uses in catalysis and photovoltaics.

<span class="mw-page-title-main">Siegenite</span>

Siegenite (also called grimmite, or nickel cobalt sulfide) is a ternary transition metal dichalcogenide compound with the chemical formula (Ni,Co)3S4. It has been actively studied as a promising material system for electrodes in electrochemical energy applications due to its better conductivity, greater mechanical and thermal stability, and higher performance compared to metal oxides currently in use. Potential applications of this material system include supercapacitors, batteries, electrocatalysis, dye-sensitized solar cells, photocatalysis, glucose sensors, and microwave absorption.

Indium(III) sulfide (Indium sesquisulfide, Indium sulfide (2:3), Indium (3+) sulfide) is the inorganic compound with the formula In2S3.

<span class="mw-page-title-main">Nickel(II) hydroxide</span> Chemical compound

Nickel(II) hydroxide is the inorganic compound with the formula Ni(OH)2. It is a lime-green solid that dissolves with decomposition in ammonia and amines and is attacked by acids. It is electroactive, being converted to the Ni(III) oxy-hydroxide, leading to widespread applications in rechargeable batteries.

Nickel aluminide refers to either of two widely used intermetallic compounds, Ni3Al or NiAl, but the term is sometimes used to refer to any nickel–aluminium alloy. These alloys are widely used because of their high strength even at high temperature, low density, corrosion resistance, and ease of production. Ni3Al is of specific interest as a precipitate in nickel-based superalloys, where it is called the γ' (gamma prime) phase. It gives these alloys high strength and creep resistance up to 0.7–0.8 of its melting temperature. Meanwhile, NiAl displays excellent properties such as lower density and higher melting temperature than those of Ni3Al, and good thermal conductivity and oxidation resistance. These properties make it attractive for special high-temperature applications like coatings on blades in gas turbines and jet engines. However, both these alloys have the disadvantage of being quite brittle at room temperature, with Ni3Al remaining brittle at high temperatures as well. To address this problem, has been shown that Ni3Al can be made ductile when manufactured in single-crystal form rather than in polycrystalline form.

A nickel sulfide inclusion,, occurs during the process of manufacturing float glass.

Tin(II) sulfide is a chemical compound of tin and sulfur. The chemical formula is SnS. Its natural occurrence concerns herzenbergite (α-SnS), a rare mineral. At elevated temperatures above 905 K, SnS undergoes a second order phase transition to β-SnS (space group: Cmcm, No. 63). In recent years, it has become evident that a new polymorph of SnS exists based upon the cubic crystal system, known as π-SnS (space group: P213, No. 198).

<span class="mw-page-title-main">Barium borate</span> Chemical compound

Barium borate is an inorganic compound, a borate of barium with a chemical formula BaB2O4 or Ba(BO2)2. It is available as a hydrate or dehydrated form, as white powder or colorless crystals. The crystals exist in the high-temperature α phase and low-temperature β phase, abbreviated as BBO; both phases are birefringent, and BBO is a common nonlinear optical material.

<span class="mw-page-title-main">Cerium</span> Chemical element, symbol Ce and atomic number 58

Cerium is a chemical element; it has symbol Ce and atomic number 58. Cerium is a soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it often shows the oxidation state of +3 characteristic of the series, it also has a stable +4 state that does not oxidize water. It is also considered one of the rare-earth elements. Cerium has no known biological role in humans but is not particularly toxic, except with intense or continued exposure.

<span class="mw-page-title-main">Gallium(III) sulfide</span> Chemical compound

Gallium(III) sulfide, Ga2S3, is a compound of sulfur and gallium, that is a semiconductor that has applications in electronics and photonics.

Nickel compounds are chemical compounds containing the element nickel which is a member of the group 10 of the periodic table. Most compounds in the group have an oxidation state of +2. Nickel is classified as a transition metal with nickel(II) having much chemical behaviour in common with iron(II) and cobalt(II). Many salts of nickel(II) are isomorphous with salts of magnesium due to the ionic radii of the cations being almost the same. Nickel forms many coordination complexes. Nickel tetracarbonyl was the first pure metal carbonyl produced, and is unusual in its volatility. Metalloproteins containing nickel are found in biological systems.

<span class="mw-page-title-main">Cerium(III) sulfide</span> Chemical compound

Cerium(III) sulfide, also known as cerium sesquisulfide, is an inorganic compound with the formula Ce2S3. It is the sulfide salt of cerium(III) and exists as three polymorphs with different crystal structures.

References

  1. 1 2 Kerfoot, Derek G. E. (2005). "Nickel". Ullmann's Encyclopedia of Industrial Chemistry . Weinheim: Wiley-VCH. doi:10.1002/14356007.a17_157. ISBN   978-3527306732.
  2. Wells, A.F. (1984) Structural Inorganic Chemistry, Oxford: Clarendon Press. ISBN   0-19-855370-6.
  3. Bishop, D.W.; Thomas, P.S.; Ray, A.S. (1998). "Raman spectra of nickel(II) sulfide". Materials Research Bulletin. 33 (9): 1303. doi:10.1016/S0025-5408(98)00121-4.
  4. "NiS and Spontaneous Breakage". Glass on Web. Nov 2012. Archived from the original on 2013-06-12.
  5. Bonati, Antonio; Pisano, Gabriele; Royer Carfagni, Gianni (12 October 2018). "A statistical model for the failure of glass plates due to nickel sulfide inclusions". Journal of the American Ceramic Society. 102 (5): 2506–2521. doi:10.1111/jace.16106. S2CID   140055629.
  6. O.Glemser "Nickel Sulfide" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 2. p. 1551.
  7. leading reference can be found in: Shabnam Virji, Richard B. Kaner, Bruce H. Weiller "Direct Electrical Measurement of the Conversion of Metal Acetates to Metal Sulfides by Hydrogen Sulfide" Inorg. Chem., 2006, 45 (26), pp 10467–10471. doi : 10.1021/ic0607585
  8. Gamsjager H. C., Bugajski J., Gajda T., Lemire R. J., Preis W. (2005) Chemical Thermodynamics of Nickel, Amsterdam, Elsevier B.V.
  9. 1 2 Karlsson, Stefan (30 April 2017). "Spontaneous fracture in thermally strengthened glass – A review & outlook". Ceramics – Silikaty: 188–201. doi: 10.13168/cs.2017.0016 . Retrieved 16 August 2019.
  10. Barry, John (12 January 2006). "The Achille Heel of a Wonderful Material: Toughened Glass". Glass on Web. Retrieved 16 August 2019.