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Cerium compounds are compounds containing the element cerium (Ce), a lanthanide. Cerium exists in two main oxidation states, Ce(III) and Ce(IV). This pair of adjacent oxidation states dominates several aspects of the chemistry of this element. Cerium(IV) aqueous solutions may be prepared by reacting cerium(III) solutions with the strong oxidizing agents peroxodisulfate or bismuthate. The value of E⦵(Ce4+/Ce3+) varies widely depending on conditions due to the relative ease of complexation and hydrolysis with various anions, although +1.72 V is representative. Cerium is the only lanthanide which has important aqueous and coordination chemistry in the +4 oxidation state.
Cerium monoselenide is an inorganic compound with the chemical formula CeSe. It exists in the form of Ce3+Se2−(e−).
References
- ↑ Perry, Dale L. (19 April 2016). Handbook of Inorganic Compounds. CRC Press. p. 105. ISBN 978-1-4398-1462-8 . Retrieved 4 April 2023.
- ↑ Pauling, Linus (24 November 2014). General Chemistry. Courier Corporation. p. 635. ISBN 978-0-486-13465-9 . Retrieved 4 April 2023.
- ↑ Kariper, İshak Afşin (1 December 2014). "Synthesis and characterization of cerium sulfide thin film". Progress in Natural Science: Materials International. 24 (6): 663–670. doi: 10.1016/j.pnsc.2014.10.005 . ISSN 1002-0071.
- ↑ "Cerium Monosulfide". American Elements . Retrieved 4 April 2023.
- 1 2 Gibbard, Kevin B.; Allahar, Kerry N.; Kolman, David; Butt, Darryl P. (September 2008). "Kinetics of thermal synthesis of cerium sulfides". Journal of Nuclear Materials . 378 (3): 291–298. Bibcode:2008JNuM..378..291G. doi:10.1016/j.jnucmat.2008.05.013 . Retrieved 4 April 2023.
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