Praseodymium monosulfide

Last updated
Praseodymium monosulfide
NaCl bonds.svg
Names
IUPAC name
sulfanylidenepraseodymium(1+)
Other names
Praseodymium(II) sulfide
Identifiers
3D model (JSmol)
  • InChI=1S/Pr.S/q+2;-2
    Key: AESILDUJSAGKHP-UHFFFAOYSA-N
  • [S-2].[Pr+2]
Properties
PrS
Molar mass 172.97 g·mol−1
AppearanceCrystalline solid
Density 6.1 g/cm3
Melting point 2,230 °C (4,050 °F; 2,500 K)
Related compounds
Related compounds
Samarium monosulfide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Praseodymium monosulfide is a binary inorganic chemical compound of praseodymium metal and sulfur with the chemical formula PrS. [1] [2]

Contents

Synthesis

Fusion of stoichiometric amounts of pure substances:

Pr + S → PrS

Physical properties

Praseodymium monosulfide forms crystals of the cubic system, space group Fm3m, cell parameters a = 0.5727 nm, Z = 4, structurally isomorphous with NaCl. [3] [4] [5]

The compound melts at a temperature of 2230 °C and has a homogeneity range of PrS0.75–1.

Related Research Articles

<span class="mw-page-title-main">Neodymium</span> Chemical element with atomic number 60 (Nd)

Neodymium is a chemical element; it has symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth metals. It is a hard, slightly malleable, silvery metal that quickly tarnishes in air and moisture. When oxidized, neodymium reacts quickly producing pink, purple/blue and yellow compounds in the +2, +3 and +4 oxidation states. It is generally regarded as having one of the most complex spectra of the elements. Neodymium was discovered in 1885 by the Austrian chemist Carl Auer von Welsbach, who also discovered praseodymium. It is present in significant quantities in the minerals monazite and bastnäsite. Neodymium is not found naturally in metallic form or unmixed with other lanthanides, and it is usually refined for general use. Neodymium is fairly common—about as common as cobalt, nickel, or copper—and is widely distributed in the Earth's crust. Most of the world's commercial neodymium is mined in China, as is the case with many other rare-earth metals.

<span class="mw-page-title-main">Sulfur</span> Chemical element with atomic number 16 (S)

Sulfur (also spelled sulphur in British English) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with the chemical formula S8. Elemental sulfur is a bright yellow, crystalline solid at room temperature.

<span class="mw-page-title-main">Praseodymium</span> Chemical element with atomic number 59 (Pr)

Praseodymium is a chemical element; it has symbol Pr and the atomic number 59. It is the third member of the lanthanide series and is considered one of the rare-earth metals. It is a soft, silvery, malleable and ductile metal, valued for its magnetic, electrical, chemical, and optical properties. It is too reactive to be found in native form, and pure praseodymium metal slowly develops a green oxide coating when exposed to air.

<span class="mw-page-title-main">Praseodymium(III) chloride</span> Chemical compound

Praseodymium(III) chloride is the inorganic compound with the formula PrCl3. Like other lanthanide trichlorides, it exists both in the anhydrous and hydrated forms. It is a blue-green solid that rapidly absorbs water on exposure to moist air to form a light green heptahydrate.

<span class="mw-page-title-main">Chemical substance</span> Form of matter

A chemical substance is a unique form of matter with constant chemical composition and characteristic properties. Chemical substances may take the form of a single element or chemical compounds. If two or more chemical substances can be combined without reacting, they may form a chemical mixture. If a mixture is separated to isolate one chemical substance to a desired degree, the resulting substance is said to be chemically pure.

<span class="mw-page-title-main">Praseodymium(III) sulfate</span> Chemical compound

Praseodymium(III) sulfate is a praseodymium compound with formula Pr2(SO4)3. It is an odourless whitish-green crystalline compound. The anhydrous substance readily absorbs water forming pentahydrate and octahydrate.

Samarium monochalcogenides are chemical compounds with the composition SmX, where Sm stands for the lanthanide element samarium and X denotes any one of three chalcogen elements, sulfur, selenium or tellurium, resulting in the compounds SmS, SmSe or SmTe. In these compounds, samarium formally exhibits oxidation state +2, whereas it usually assumes the +3 state, resulting in chalcogenides with the chemical formula Sm2X3.

<span class="mw-page-title-main">Samarium monosulfide</span> Chemical compound

Samarium monosulfide is a binary inorganic chemical compound of samarium metal and sulfur with the chemical formula SmS.

<span class="mw-page-title-main">Silicon monosulfide</span> Chemical compound

Silicon monosulfide is a chemical compound of silicon and sulfur. The chemical formula is SiS. Molecular SiS has been detected at high temperature in the gas phase. The gas phase molecule has an Si-S bondlength of 192.93 pm, this compares to the normal single bond length of 216 pm, and is shorter than the Si=S bond length of around 201 pm reported in an organosilanethione. Historically a pale yellow-red amorphous solid compound has been reported. The behavior of silicon can be contrasted with germanium which forms a stable solid monosulfide.

Praseodymium(III) fluoride is an inorganic compound with the formula PrF3, being the most stable fluoride of praseodymium.

Praseodymium(III) nitride is a binary inorganic compound of praseodymium and nitrogen. Its chemical formula is PrN. The compound forms black crystals, and reacts with water.

Praseodymium monophosphide is an inorganic compound of praseodymium and phosphorus with the chemical formula PrP. The compound forms crystals.

Praseodymium compounds are compounds formed by the lanthanide metal praseodymium (Pr). In these compounds, praseodymium generally exhibits the +3 oxidation state, such as PrCl3, Pr(NO3)3 and Pr(CH3COO)3. However, compounds with praseodymium in the +2 and +4 oxidation states, and unlike other lanthanides, the +5 oxidation state, are also known.

Cerium monosulfide is a binary inorganic compound of cerium and sulfur with the chemical formula CeS. This is the simplest of cerium sulfides.

Neodymium(II) sulfide is a binary inorganic chemical compound of Neodymium metal and sulfur with the chemical formula NdS.

<span class="mw-page-title-main">Lanthanum monosulfide</span> Chemical compound

Lanthanum monosulfide is a binary inorganic chemical compound of lanthanum metal and sulfur with the chemical formula LaS.

<span class="mw-page-title-main">Holmium monosulfide</span> Chemical compound

Holmium monosulfide is a binary inorganic compound of holmium and sulfur with the chemical formula HoS.

<span class="mw-page-title-main">Dysprosium monosulfide</span> Chemical compound

Dysprosium monosulfide is a binary inorganic compound of dysprosium and sulfur with the chemical formula DyS.

<span class="mw-page-title-main">Gadolinium monosulfide</span> Chemical compound

Gadolinium monosulfide is a binary inorganic compound of gadolinium and sulfur with the chemical formula GdS.

<span class="mw-page-title-main">Terbium monosulfide</span> Chemical compound

Terbium monosulfide is a binary inorganic compound of terbium and sulfur with the chemical formula TbS.

References

  1. "WebElements Periodic Table » Praseodymium » praseodymium sulphide". webelements.com. Retrieved 25 July 2024.
  2. "Praseodymium(II) Sulfide". American Elements . Retrieved 25 July 2024.
  3. Okamoto, H. (1 October 1991). "Pr-S (Praseodymium-Sulfur)". Journal of Phase Equilibria. 12 (5): 618–619. doi:10.1007/BF02645088. ISSN   1054-9714 . Retrieved 25 July 2024.
  4. Predel, B. (1998). "Pr-S (Praseodymium-Sulfur)". Ni-Np – Pt-Zr. I: 1–2. doi:10.1007/10542753_2497 . Retrieved 25 July 2024.
  5. Swanson, Howard Eugene (1962). Standard X-ray Diffraction Powder Patterns: Data for 46 substances. National Bureau of Standards. p. 67. Retrieved 25 July 2024.