Praseodymium antimonide

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Praseodymium antimonide
NaCl polyhedra.svg
Names
Other names
  • Praseodymium(III) antimony
  • Antimony-Praseodymium
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.871 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 235-071-9
PubChem CID
  • InChI=1S/Pr.Sb
    Key: MHUUNPRVUKWBIV-UHFFFAOYSA-N
  • [Pr].[Sb]
Properties
PrSb
Molar mass 262.67 g/mol
Density 6.7 g/cm3
Melting point 2161 or 2170 °C
Related compounds
Other anions
PrN, PrP, PrAs, PrBi, Pr2O3
Other cations
CeSb, NdSb
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Praseodymium antimonide is a binary inorganic compound of praseodymium and antimony with the formula PrSb.

Contents

Preparation

Praseodymium antimonide can be prepared by heating praseodymium and antimony in a vacuum:

Physical properties

Praseodymium antimonide forms cubic crystals, space group Fm3m, cell parameters a = 0.638 nm, Z = 4, and structure like sodium chloride. [1] [2] [3]

The compound melts congruently at 2170 °C [1] or 2161 °C. [2] At a temperature of 1950 °C, a phase transition occurs in the crystals. At a pressure of 13 GPa, a phase transition also occurs. [4]

See also

Related Research Articles

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Antimony ( AN-tih-moh-nee, AN-tih-mə-nee) is a chemical element; it has symbol Sb (from Latin stibium) and atomic number 51. A lustrous gray metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3). Antimony compounds have been known since ancient times and were powdered for use as medicine and cosmetics, often known by the Arabic name kohl. The earliest known description of the metalloid in the West was written in 1540 by Vannoccio Biringuccio.

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<span class="mw-page-title-main">Gallium antimonide</span> Chemical compound

Gallium antimonide (GaSb) is a semiconducting compound of gallium and antimony of the III-V family. It has a room temperature lattice constant of about 0.610 nm. It has a room temperature direct bandgap of approximately 0.73 eV.

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Stibarsen or allemontite is a natural form of arsenic antimonide (AsSb) or antimony arsenide (SbAs). The name stibarsen is derived from Latin stibium (antimony) and arsenic, whereas allemonite refers to the locality Allemont in France where the mineral was discovered. It is found in veins at Allemont, Isère, France; Valtellina, Italy; and the Comstock Lode, Nevada; and in a lithium pegmatites at Varuträsk, Sweden. Stibarsen is often mixed with pure arsenic or antimony, and the original description in 1941 proposed to use stibarsen for AsSb and allemontite for the mixtures. Since 1982, the International Mineralogical Association considers stibarsen as the correct mineral name.

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<span class="mw-page-title-main">Praseodymium bismuthide</span> Binary inorganic compound of praseodymium and bismuth with the chemical formula of PrBi

Praseodymium bismuthide is a binary inorganic compound of praseodymium and bismuth with the chemical formula of PrBi. It forms crystals.

<span class="mw-page-title-main">Praseodymium arsenide</span> Chemical compound

Praseodymium arsenide is a binary inorganic compound of praseodymium and arsenic with the formula PrAs.

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Strontium selenide is an inorganic compound with the chemical formula SrSe.

Gallium arsenide antimonide, also known as gallium antimonide arsenide or GaAsSb (GaAs1-xSbx), is a ternary III-V semiconductor compound. x indicates the fractions of arsenic and antimony in the alloy according to the aforementioned formula; it can take on any value between 0 and 1. GaAsSb refers generally to any composition of the alloy. It is considered as an alloy between gallium arsenide (GaAs) and gallium antimonide (GaSb).

References

  1. 1 2 Diagrammy sostojanija dvojnych metalličeskich sistem: spravočnik v trech tomach. 3,2. Moskva: Mašinostroenie. 2001. ISBN   978-5-217-02932-7.
  2. 1 2 Franke, P.; Neuschütz, D.; Scientific Group Thermodata Europe (SGTE) (2006), Franke, P.; Neuschütz, D. (eds.), "Pr-Sb", Binary Systems. Part 4: Binary Systems from Mn-Mo to Y-Zr, Berlin/Heidelberg: Springer-Verlag, vol. 19B4, pp. 1–4, doi:10.1007/10757285_56, ISBN   978-3-540-25024-1 , retrieved 2023-06-20
  3. Predel, B. (1998), Madelung, O. (ed.), "Pr-Sb (Praseodymium-Antimony)", Ni-Np – Pt-Zr, Landolt-Börnstein - Group IV Physical Chemistry, Berlin/Heidelberg: Springer-Verlag, vol. I, pp. 1–2, doi:10.1007/10542753_2498, ISBN   978-3-540-61712-9 , retrieved 2023-06-20
  4. Gupta, Dinesh Chandra; Raypuria, Gajendra Singh (January 2013). "Phase Transition of Praseodymium Mono-Pnictides Under High Pressure". International Journal of Modern Physics: Conference Series. 22: 491–496. Bibcode:2013IJMPS..22..491G. doi: 10.1142/S2010194513010568 . ISSN   2010-1945.