Praseodymium antimonide

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Praseodymium antimonide
NaCl polyhedra.svg
Names
Other names
  • Praseodymium(III) antimony
  • Antimony-Praseodymium
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.871 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 235-071-9
PubChem CID
  • InChI=1S/Pr.Sb
    Key: MHUUNPRVUKWBIV-UHFFFAOYSA-N
  • [Pr].[Sb]
Properties
PrSb
Molar mass 262.67 g/mol
Density 6.7 g/cm3
Melting point 2161 or 2170 °C
Related compounds
Other anions
PrN, PrP, PrAs, PrBi, Pr2O3
Other cations
CeSb, NdSb
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Praseodymium antimonide is a binary inorganic compound of praseodymium and antimony with the formula PrSb.

Contents

Preparation

Praseodymium antimonide can be prepared by heating praseodymium and antimony in a vacuum:

Physical properties

Praseodymium antimonide forms cubic crystals, space group Fm3m, cell parameters a = 0.638 nm, Z = 4, and structure like sodium chloride. [1] [2] [3]

The compound melts congruently at 2170 °C [1] or 2161 °C. [2] At a temperature of 1950 °C, a phase transition occurs in the crystals. At a pressure of 13 GPa, a phase transition also occurs. [4]

See also

Related Research Articles

<span class="mw-page-title-main">Antimony</span> Chemical element with atomic number 51 (Sb)

Antimony is a chemical element; it has symbol Sb (from Latin stibium) and atomic number 51. A lustrous grey metal or metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3). Antimony compounds have been known since ancient times and were powdered for use as medicine and cosmetics, often known by the Arabic name kohl. The earliest known description of this metalloid in the West was written in 1540 by Vannoccio Biringuccio.

<span class="mw-page-title-main">Cubic crystal system</span> Crystallographic system where the unit cell is in the shape of a cube

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<span class="mw-page-title-main">Indium antimonide</span> Chemical compound

Indium antimonide (InSb) is a crystalline compound made from the elements indium (In) and antimony (Sb). It is a narrow-gap semiconductor material from the III-V group used in infrared detectors, including thermal imaging cameras, FLIR systems, infrared homing missile guidance systems, and in infrared astronomy. Indium antimonide detectors are sensitive to infrared wavelengths between 1 and 5 μm.

<span class="mw-page-title-main">Gallium antimonide</span> Chemical compound

Gallium antimonide (GaSb) is a semiconducting compound of gallium and antimony of the III-V family. It has a room temperature lattice constant of about 0.610 nm. It has a room temperature direct bandgap of approximately 0.73 eV.

<span class="mw-page-title-main">Tin telluride</span> Chemical compound

Tin telluride is a compound of tin and tellurium (SnTe); is a IV-VI narrow band gap semiconductor and has direct band gap of 0.18 eV. It is often alloyed with lead to make lead tin telluride, which is used as an infrared detector material.

Binary compounds of hydrogen are binary chemical compounds containing just hydrogen and one other chemical element. By convention all binary hydrogen compounds are called hydrides even when the hydrogen atom in it is not an anion. These hydrogen compounds can be grouped into several types.

<span class="mw-page-title-main">Binary compounds of silicon</span> Any binary chemical compound containing just silicon and another chemical element

Binary compounds of silicon are binary chemical compounds containing silicon and one other chemical element. Technically the term silicide is reserved for any compounds containing silicon bonded to a more electropositive element. Binary silicon compounds can be grouped into several classes. Saltlike silicides are formed with the electropositive s-block metals. Covalent silicides and silicon compounds occur with hydrogen and the elements in groups 10 to 17.

<span class="mw-page-title-main">Stibarsen</span> Native element mineral

Stibarsen or allemontite is a natural form of arsenic antimonide (AsSb) or antimony arsenide (SbAs). The name stibarsen is derived from Latin stibium (antimony) and arsenic, whereas allemonite refers to the locality Allemont in France where the mineral was discovered. It is found in veins at Allemont, Isère, France; Valtellina, Italy; and the Comstock Lode, United States; and in a lithium pegmatites at Varuträsk, Sweden. Stibarsen is often mixed with pure arsenic or antimony, and the original description in 1941 proposed to use stibarsen for AsSb and allemontite for the mixtures. Since 1982, the International Mineralogical Association considers stibarsen as the correct mineral name.

Praseodymium compounds are compounds formed by the lanthanide metal praseodymium (Pr). In these compounds, praseodymium generally exhibits the +3 oxidation state, such as PrCl3, Pr(NO3)3 and Pr(CH3COO)3. However, compounds with praseodymium in the +2 and +4 oxidation states, and unlike other lanthanides, the +5 oxidation state, are also known.

<span class="mw-page-title-main">Praseodymium bismuthide</span> Binary inorganic compound of praseodymium and bismuth with the chemical formula of PrBi

Praseodymium bismuthide is a binary inorganic compound of praseodymium and bismuth with the chemical formula of PrBi. It forms crystals.

<span class="mw-page-title-main">Praseodymium arsenide</span> Chemical compound

Praseodymium arsenide is a binary inorganic compound of praseodymium and arsenic with the formula PrAs.

Gallium arsenide antimonide, also known as gallium antimonide arsenide or GaAsSb, is a ternary III-V semiconductor compound; x indicates the fractions of arsenic and antimony in the alloy. GaAsSb refers generally to any composition of the alloy. It is an alloy of gallium arsenide (GaAs) and gallium antimonide (GaSb).

<span class="mw-page-title-main">Samarium(III) antimonide</span> Chemical compound

Samarium antimonide is a binary inorganic compound of samarium and antimony with the formula SmSb. It forms crystals.

Thulium monoselenide is a mixed valence compound of selenium and thulium with the chemical formula TmSe.

Praseodymium monoselenide is a compound with the chemical formula PrSe. It forms crystals.

Samarium(III) nitride is a binary inorganic compound of samarium and nitrogen with the chemical formula SmN.

Praseodymium pentaphosphide is a binary inorganic compound of praseodymium metal and phosphorus with the chemical formula PrP5.

<span class="mw-page-title-main">Samarium tetraboride</span> Chemical compound

Samarium tetraboride is a binary inorganic compound of samarium and boron with the formula SmB4. It forms black crystals.

<span class="mw-page-title-main">Praseodymium monosulfide</span> Chemical compound

Praseodymium monosulfide is a binary inorganic chemical compound of praseodymium metal and sulfur with the chemical formula PrS.

References

  1. 1 2 Diagrammy sostojanija dvojnych metalličeskich sistem: spravočnik v trech tomach. 3,2. Moskva: Mašinostroenie. 2001. ISBN   978-5-217-02932-7.
  2. 1 2 Franke, P.; Neuschütz, D.; Scientific Group Thermodata Europe (SGTE) (2006), Franke, P.; Neuschütz, D. (eds.), "Pr-Sb", Binary Systems. Part 4: Binary Systems from Mn-Mo to Y-Zr, vol. 19B4, Berlin/Heidelberg: Springer-Verlag, pp. 1–4, doi:10.1007/10757285_56, ISBN   978-3-540-25024-1 , retrieved 2023-06-20
  3. Predel, B. (1998), Madelung, O. (ed.), "Pr-Sb (Praseodymium-Antimony)", Ni-Np – Pt-Zr, Landolt-Börnstein - Group IV Physical Chemistry, vol. I, Berlin/Heidelberg: Springer-Verlag, pp. 1–2, doi:10.1007/10542753_2498, ISBN   978-3-540-61712-9 , retrieved 2023-06-20
  4. Gupta, Dinesh Chandra; Raypuria, Gajendra Singh (January 2013). "Phase Transition of Praseodymium Mono-Pnictides Under High Pressure". International Journal of Modern Physics: Conference Series. 22: 491–496. Bibcode:2013IJMPS..22..491G. doi: 10.1142/S2010194513010568 . ISSN   2010-1945.