Pentlandite is an iron–nickel sulfide with the chemical formula (Fe,Ni)9S8. Pentlandite has a narrow variation range in nickel to iron ratios (Ni:Fe), but it is usually described as 1:1. In some cases, this ratio is skewed by the presence of pyrrhotite inclusions. It also contains minor cobalt, usually at low levels as a fraction of weight.
Nickeline or niccolite is a mineral consisting primarily of nickel arsenide (NiAs). The naturally-occurring mineral contains roughly 43.9% nickel and 56.1% arsenic by mass, but composition of the mineral may vary slightly.
Ullmannite or Nickel glance is a nickel antimony sulfide mineral with formula: NiSbS. Considerable substitution occurs with cobalt and iron in the nickel site along with bismuth and arsenic in the antimony site. A solid solution series exists with the high cobalt willyamite.
Skutterudite is a cobalt arsenide mineral containing variable amounts of nickel and iron substituting for cobalt with the ideal formula CoAs3. Some references give the arsenic a variable formula subscript of 2–3. High nickel varieties are referred to as nickel-skutterudite, previously chloanthite. It is a hydrothermal ore mineral found in moderate to high temperature veins with other Ni-Co minerals. Associated minerals are arsenopyrite, native silver, erythrite, annabergite, nickeline, cobaltite, silver sulfosalts, native bismuth, calcite, siderite, barite and quartz. It is mined as an ore of cobalt and nickel with a by-product of arsenic.
Erythrite, also known as red cobalt, is a secondary hydrated cobalt arsenate mineral with the formula Co
3(AsO
4)
2•8H
2O. Erythrite and annabergite, chemical formula Ni
3(AsO
4)
2•8H
2O, or nickel arsenate form a complete series with the general formula (Co,Ni)
3(AsO
4)
2•8H
2O.
Adamite is a zinc arsenate hydroxide mineral, Zn2AsO4OH. It is a mineral that typically occurs in the oxidized or weathered zone above zinc ore occurrences. Pure adamite is colorless, but usually it possess yellow color due to Fe compounds admixture. Tints of green also occur and are connected with copper substitutions in the mineral structure. Olivenite is a copper arsenate that is isostructural with adamite and there is considerable substitution between zinc and copper resulting in an intermediate called cuproadamite. Zincolivenite is a recently discovered mineral being an intermediate mineral with formula CuZn(AsO4)(OH). Manganese, cobalt, and nickel also substitute in the structure. An analogous zinc phosphate, tarbuttite, is known.
Cobaltite is an arsenide and sulfide mineral with the mineral formula CoAsS. It is the naming mineral of the cobaltite group of minerals, whose members structurally resemble pyrite (FeS2).
Maucherite is a grey to reddish silver white nickel arsenide mineral. It crystallizes in the tetragonal crystal system. It occurs in hydrothermal veins alongside other nickel arsenide and sulfide minerals. It is metallic and opaque with a hardness of 5 and a specific gravity of 7.83. It is also known as placodine and Temiskamite. The unit cell is of symmetry group P41212 or P43212.
Annabergite is an arsenate mineral consisting of a hydrous nickel arsenate. It is considered a member of the vivianite group and known for its ability to form crystals in a characteristic apple-green color.
Loellingite, also spelled löllingite, is an iron arsenide mineral with formula FeAs2. It is often found associated with arsenopyrite (FeAsS) from which it is hard to distinguish. Cobalt, nickel and sulfur substitute in the structure. The orthorhombic lollingite group includes the nickel iron arsenide rammelsbergite and the cobalt iron arsenide safflorite. Leucopyrite is an old synonym for loellingite.
Glaucodot is a cobalt iron arsenic sulfide mineral with formula (Co,Fe)AsS. The cobalt:iron(II) ratio is typically 3:1 with minor nickel substituting. It forms a series with arsenopyrite (FeAsS). It is an opaque grey to tin-white typically found as massive forms without external crystal form. It crystallizes in the orthorhombic system. The locality at Håkansboda, Sweden has rare twinned dipyramidal crystals. It is brittle with a Mohs hardness of 5 and a specific gravity of 5.95. It occurs in high temperature hydrothermal deposits with pyrrhotite and chalcopyrite. Glaucodot is classed as a sulfide in the arsenopyrite löllingite group.
Geigerite is a mineral, a complex hydrous manganese arsenate with formula: Mn5(AsO3OH)2(AsO4)2·10H2O. It forms triclinic pinacoidal, vitreous, colorless to red to brown crystals. It has a Mohs hardness of 3 and a specific gravity of 3.05.
Spherocobaltite or sphaerocobaltite is a cobalt carbonate mineral with chemical composition CoCO3. In its (rare) pure form, it is typically a rose-red color, but impure specimens can be shades of pink to pale brown. It crystallizes in the trigonal crystal system.
Linnaeite is a cobalt sulfide mineral with the composition Co+2Co+32S4. It was discovered in 1845 in Västmanland, Sweden, and was named to honor Carl Linnaeus (1707–1778).
Vladimirite is a rare calcium arsenate mineral with a formula of Ca5(HAsO4)2(AsO4)2·5H2O. It is named after the Vladimirovskoye deposit in Russia, where it was discovered in the 1950s.
Köttigite is a rare hydrated zinc arsenate which was discovered in 1849 and named by James Dwight Dana in 1850 in honour of Otto Friedrich Köttig (1824–1892), a German chemist from Schneeberg, Saxony, who made the first chemical analysis of the mineral. It has the formula Zn3(AsO4)2·8H2O and it is a dimorph of metaköttigite, which means that the two minerals have the same formula, but a different structure: köttigite is monoclinic and metaköttigite is triclinic. There are several minerals with similar formulae but with other cations in place of the zinc. Iron forms parasymplesite Fe2+3(AsO4)2·8H2O; cobalt forms the distinctively coloured pinkish purple mineral erythrite Co3(AsO4)2·8H2O and nickel forms annabergite Ni3(AsO4)2·8H2O. Köttigite forms series with all three of these minerals and they are all members of the vivianite group.
Talmessite is a hydrated calcium magnesium arsenate, often with significant amounts of cobalt or nickel. It was named in 1960 for the type locality, the Talmessi mine, Anarak district, Iran. It forms a series with β-Roselite, where cobalt replaces some of the magnesium, and with gaitite, where zinc replaces the magnesium. All these minerals are members of the fairfieldite group. Talmessite is dimorphic with wendwilsonite.
Moorhouseite is a rare mineral with the formula CoSO4•6H2O, a naturally occurring cobalt(II) sulfate hexahydrate. It is the lower-hydrate-equivalent of bieberite (heptahydrate) and aplowite (hexahydrate). It is also hydrated equivalent of cobaltkieserite. It occurs together with moorhouseite within efflorescences found in the Magnet Cove Barium Corporation mine in Walton, Nova Scotia, Canada.
Asbolane is a manganese (IV) oxy-hydroxide mineral containing also cobalt, nickel, magnesium, and calcium ions. It crystallizes in the hexagonal crystal system. Its chemical formula is Mn4+(O,OH)2·(Co,Ni,Mg,Ca)x(OH)2x·nH2O.
Ferronickel platinum is a very rarely occurring minerals from the mineral class of elements (including natural alloys, intermetallic compounds, carbides, nitrides, phosphides and silicides) with the chemical composition Pt2FeNi and thus is chemically seen as a natural alloy, more precisely an intermetallic compound of platinum, nickel and iron in a ratio of 2:1:1.
