Indium antimonide

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Indium antimonide
Sphalerite-unit-cell-3D-balls.png
Indium antimonide.jpg
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.013.812 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 215-192-3
PubChem CID
RTECS number
  • NL1105000
UNII
UN number 1549
  • InChI=1S/In.Sb Yes check.svgY
    Key: WPYVAWXEWQSOGY-UHFFFAOYSA-N Yes check.svgY
  • [In]#[Sb]
Properties
InSb
Molar mass 236.578 g·mol−1
AppearanceDark grey, metallic crystals
Density 5.7747 g⋅cm−3 [1]
Melting point 524 °C (975 °F; 797 K) [1]
Band gap 0.17 eV
Electron mobility 7.7 mC⋅s⋅g−1 (at 27 °C)
Thermal conductivity 180 mW⋅K−1⋅cm−1 (at 27 °C)
4 [2]
Structure
Zincblende
T2d-F-43m
a = 0.648 nm
Tetrahedral
Thermochemistry [3]
49.5 J·K−1·mol−1
Std molar
entropy
(S298)
86.2 J·K−1·mol−1
−30.5 kJ·mol−1
−25.5 kJ·mol−1
Hazards
GHS labelling:
GHS-pictogram-exclam.svg GHS-pictogram-pollu.svg [4]
Warning
H302, H332, H411
P273
Safety data sheet (SDS) External SDS
Related compounds
Other anions
Indium nitride
Indium phosphide
Indium arsenide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Indium antimonide (InSb) is a crystalline compound made from the elements indium (In) and antimony (Sb). It is a narrow-gap semiconductor material from the III-V group used in infrared detectors, including thermal imaging cameras, FLIR systems, infrared homing missile guidance systems, and in infrared astronomy. Indium antimonide detectors are sensitive to infrared wavelengths between 1 and 5 μm.

Contents

Indium antimonide was a very common detector in the old, single-detector mechanically scanned thermal imaging systems. Another application is as a terahertz radiation source as it is a strong photo-Dember emitter.

History

The intermetallic compound was first reported by Liu and Peretti in 1951, who gave its homogeneity range, structure type, and lattice constant. [5] Polycrystalline ingots of InSb were prepared by Heinrich Welker in 1952, although they were not very pure by today's semiconductor standards. Welker was interested in systematically studying the semiconducting properties of the III-V compounds. He noted how InSb appeared to have a small direct band gap and a very high electron mobility. [6] InSb crystals have been grown by slow cooling from liquid melt at least since 1954. [7]

In 2018, a research team at Delft University of Technology claimed that indium antimonide nanowires showed potential application in creating Majorana zero mode quasiparticles for use in quantum computing; Microsoft opened a laboratory at the university to further this research, however Delft later retracted the paper. [8] [9]

Physical properties

InSb has the appearance of dark-grey silvery metal pieces or powder with vitreous lustre. When subjected to temperatures over 500 °C, it melts and decomposes, liberating antimony and antimony oxide vapors.

The crystal structure is zincblende with a 0.648 nm lattice constant. [10]

Electronic properties

InSb infrared detector manufactured by Mullard in the 1960s. InSb IR detector.jpg
InSb infrared detector manufactured by Mullard in the 1960s.

InSb is a narrow direct band gap semiconductor with an energy band gap of 0.17  eV at 300  K and 0.23 eV at 80 K. [10]

Undoped InSb possesses the largest ambient-temperature electron mobility of 78000 cm2/(V⋅s), [11] electron drift velocity, and ballistic length (up to 0.7 μm at 300 K) [10] of any known semiconductor, except for carbon nanotubes.

Indium antimonide photodiode detectors are photovoltaic, generating electric current when subjected to infrared radiation. InSb's internal quantum efficiency is effectively 100% but is a function of the thickness particularly for near bandedge photons. [12] Like all narrow bandgap materials InSb detectors require periodic recalibrations, increasing the complexity of the imaging system. This added complexity is worthwhile where extreme sensitivity is required, e.g. in long-range military thermal imaging systems. InSb detectors also require cooling, as they have to operate at cryogenic temperatures (typically 80 K). Large arrays (up to 2048×2048  pixels) are available. [13] HgCdTe and PtSi are materials with similar use.

A layer of indium antimonide sandwiched between layers of aluminium indium antimonide can act as a quantum well. In such a heterostructure InSb/AlInSb has recently been shown to exhibit a robust quantum Hall effect. [14] This approach is studied in order to construct very fast transistors. [15] Bipolar transistors operating at frequencies up to 85 GHz were constructed from indium antimonide in the late 1990s; field-effect transistors operating at over 200 GHz have been reported more recently (Intel/QinetiQ).[ citation needed ] Some models suggest that terahertz frequencies are achievable with this material. Indium antimonide semiconductor devices are also capable of operating with voltages under 0.5 V, reducing their power requirements.[ citation needed ]

Growth methods

InSb can be grown by solidifying a melt from the liquid state (Czochralski process), or epitaxially by liquid phase epitaxy, hot wall epitaxy or molecular beam epitaxy. It can also be grown from organometallic compounds by MOVPE.[ citation needed ]

Device applications

Related Research Articles

A semiconductor is a material that has an electrical conductivity value falling between that of a conductor, such as copper, and an insulator, such as glass. Its resistivity falls as its temperature rises; metals behave in the opposite way. Its conducting properties may be altered in useful ways by introducing impurities ("doping") into the crystal structure. When two differently doped regions exist in the same crystal, a semiconductor junction is created. The behavior of charge carriers, which include electrons, ions, and electron holes, at these junctions is the basis of diodes, transistors, and most modern electronics. Some examples of semiconductors are silicon, germanium, gallium arsenide, and elements near the so-called "metalloid staircase" on the periodic table. After silicon, gallium arsenide is the second-most common semiconductor and is used in laser diodes, solar cells, microwave-frequency integrated circuits, and others. Silicon is a critical element for fabricating most electronic circuits.

<span class="mw-page-title-main">Gallium arsenide</span> Chemical compound

Gallium arsenide (GaAs) is a III-V direct band gap semiconductor with a zinc blende crystal structure.

<span class="mw-page-title-main">Terahertz radiation</span> Range 300-3000 GHz of the electromagnetic spectrum

Terahertz radiation – also known as submillimeter radiation, terahertz waves, tremendously high frequency (THF), T-rays, T-waves, T-light, T-lux or THz – consists of electromagnetic waves within the ITU-designated band of frequencies from 0.3 to 3 terahertz (THz), although the upper boundary is somewhat arbitrary and is considered by some sources as 30 THz. One terahertz is 1012 Hz or 1000 GHz. Wavelengths of radiation in the terahertz band correspondingly range from 1 mm to 0.1 mm = 100 µm. Because terahertz radiation begins at a wavelength of around 1 millimeter and proceeds into shorter wavelengths, it is sometimes known as the submillimeter band, and its radiation as submillimeter waves, especially in astronomy. This band of electromagnetic radiation lies within the transition region between microwave and far infrared, and can be regarded as either.

<span class="mw-page-title-main">Photocathode</span>

A photocathode is a surface engineered to convert light (photons) into electrons using the photoelectric effect. Photocathodes are important in accelerator physics where they are utilised in a photoinjector to generate high brightness electron beams. Electron beams generated with photocathodes are commonly used for free electron lasers and for ultrafast electron diffraction. Photocathodes are also commonly used as the negatively charged electrode in a light detection device such as a photomultiplier, phototube and image intensifier.

<span class="mw-page-title-main">High-electron-mobility transistor</span> Type of field-effect transistor

A high-electron-mobility transistor, also known as heterostructure FET (HFET) or modulation-doped FET (MODFET), is a field-effect transistor incorporating a junction between two materials with different band gaps as the channel instead of a doped region. A commonly used material combination is GaAs with AlGaAs, though there is wide variation, dependent on the application of the device. Devices incorporating more indium generally show better high-frequency performance, while in recent years, gallium nitride HEMTs have attracted attention due to their high-power performance. Like other FETs, HEMTs are used in integrated circuits as digital on-off switches. FETs can also be used as amplifiers for large amounts of current using a small voltage as a control signal. Both of these uses are made possible by the FET’s unique current–voltage characteristics. HEMT transistors are able to operate at higher frequencies than ordinary transistors, up to millimeter wave frequencies, and are used in high-frequency products such as cell phones, satellite television receivers, voltage converters, and radar equipment. They are widely used in satellite receivers, in low power amplifiers and in the defense industry.

<span class="mw-page-title-main">Photodetector</span> Sensors of light or other electromagnetic energy

Photodetectors, also called photosensors, are sensors of light or other electromagnetic radiation. There are a wide variety of photodetectors which may be classified by mechanism of detection, such as photoelectric or photochemical effects, or by various performance metrics, such as spectral response. Semiconductor-based photodetectors typically use a p–n junction that converts photons into charge. The absorbed photons make electron–hole pairs in the depletion region. Photodiodes and photo transistors are a few examples of photo detectors. Solar cells convert some of the light energy absorbed into electrical energy.

Indium gallium arsenide (InGaAs) is a ternary alloy of indium arsenide (InAs) and gallium arsenide (GaAs). Indium and gallium are group III elements of the periodic table while arsenic is a group V element. Alloys made of these chemical groups are referred to as "III-V" compounds. InGaAs has properties intermediate between those of GaAs and InAs. InGaAs is a room-temperature semiconductor with applications in electronics and photonics.

<span class="mw-page-title-main">Mercury cadmium telluride</span> Alloy

Hg1−xCdxTe or mercury cadmium telluride is a chemical compound of cadmium telluride (CdTe) and mercury telluride (HgTe) with a tunable bandgap spanning the shortwave infrared to the very long wave infrared regions. The amount of cadmium (Cd) in the alloy can be chosen so as to tune the optical absorption of the material to the desired infrared wavelength. CdTe is a semiconductor with a bandgap of approximately 1.5 electronvolts (eV) at room temperature. HgTe is a semimetal, which means that its bandgap energy is zero. Mixing these two substances allows one to obtain any bandgap between 0 and 1.5 eV.

<span class="mw-page-title-main">Infrared detector</span>

An infrared detector is a detector that reacts to infrared (IR) radiation. The two main types of detectors are thermal and photonic (photodetectors).

<span class="mw-page-title-main">Indium arsenide</span> Chemical compound

Indium arsenide, InAs, or indium monoarsenide, is a narrow-bandgap semiconductor composed of indium and arsenic. It has the appearance of grey cubic crystals with a melting point of 942 °C.

Charles Thomas Elliott, , is a scientist in the fields of narrow gap semiconductor and infrared detector research.

<span class="mw-page-title-main">Zinc telluride</span> Chemical compound

Zinc telluride is a binary chemical compound with the formula ZnTe. This solid is a semiconductor material with a direct band gap of 2.26 eV. It is usually a p-type semiconductor. Its crystal structure is cubic, like that for sphalerite and diamond.

Lead selenide (PbSe), or lead(II) selenide, a selenide of lead, is a semiconductor material. It forms cubic crystals of the NaCl structure; it has a direct bandgap of 0.27 eV at room temperature. A grey solid, it is used for manufacture of infrared detectors for thermal imaging. The mineral clausthalite is a naturally occurring lead selenide.

<span class="mw-page-title-main">Aluminium antimonide</span> Chemical compound

Aluminium antimonide (AlSb) is a semiconductor of the group III-V family containing aluminium and antimony. The lattice constant is 0.61 nm. The indirect bandgap is approximately 1.6 eV at 300 K, whereas the direct band gap is 2.22 eV.

<span class="mw-page-title-main">Gallium antimonide</span> Chemical compound

Gallium antimonide (GaSb) is a semiconducting compound of gallium and antimony of the III-V family. It has a lattice constant of about 0.61 nm. It has a band gap of 0.67 eV.

<span class="mw-page-title-main">Zinc antimonide</span> Chemical compound

Zinc antimonide (ZnSb), (Zn3Sb2), (Zn4Sb3) is an inorganic chemical compound. The Zn-Sb system contains six intermetallics. Like indium antimonide, aluminium antimonide, and gallium antimonide, it is a semiconducting intermetallic compound. It is used in transistors, infrared detectors and thermal imagers, as well as magnetoresistive devices.

IQE PLC is a British semiconductor company founded 1988 in Cardiff, Wales, which manufactures advanced epitaxial wafers for a wide range of technology applications for wireless, optoelectronic, electronic and solar devices. IQE specialises in advanced silicon and compound semiconductor materials based on gallium arsenide (GaAs), indium phosphide (InP), gallium nitride (GaN) and silicon. The company is the largest independent outsource producer of epiwafers manufactured by metalorganic vapour phase epitaxy (MOCVD), molecular beam epitaxy (MBE) and chemical vapor deposition (CVD).

Indium arsenide antimonide phosphide is a semiconductor material.

Roger John Malik is a physicist, engineer and inventor.

References

  1. 1 2 Haynes, p. 4.66
  2. Haynes, pp. 12.156
  3. Haynes, pp. 5.22
  4. "Indium Antimonde". American Elements . Retrieved June 20, 2019.
  5. Liu, T.S.; Peretti, E.A. (1951). "The Lattice Parameter of InSb". Trans AIME. 191: 791.
  6. Orton, J.W. (2009). Semiconductors and the Information Revolution: Magic Crystals that Made IT Happen. Academic Press. pp. 138–9. ISBN   9780444532404.
  7. Avery, D G; Goodwin, D W; Lawson, W D; Moss, T S (1954). "Optical and Photo-Electrical Properties of Indium Antimonide". Proceedings of the Physical Society. Series B. 67 (10): 761. Bibcode:1954PPSB...67..761A. doi:10.1088/0370-1301/67/10/304.
  8. Dedezade, Esat (2019-02-21). "Microsoft's new quantum computing lab in Delft opens its doors to a world of possibilities". Microsoft News Centre Europe.
  9. Kaku, Michio (2023). Quantum Supremacy (1st ed.). New York: Doubleday. p. 96. ISBN   978-0-385-54836-6.
  10. 1 2 3 Properties of Indium Antimonide (InSb). ioffe.ru
  11. Rode, D. L. (1971). "Electron Transport in InSb, InAs, and InP". Physical Review B. 3 (10): 3287–3299. Bibcode:1971PhRvB...3.3287R. doi:10.1103/PhysRevB.3.3287.
  12. Avery, D G; Goodwin, D W; Rennie, Miss A E (1957). "New infra-red detectors using indium antimonide". Journal of Scientific Instruments. 34 (10): 394. Bibcode:1957JScI...34..394A. doi:10.1088/0950-7671/34/10/305.
  13. Beckett, M.G. (1995). "3. Camera". High Resolution Infrared Imaging (PhD). Cambridge University. uk.bl.ethos.388828.
  14. Alexander-Webber, J. A.; Baker, A. M. R.; Buckle, P. D.; Ashley, T.; Nicholas, R. J. (2012-07-05). "High-current breakdown of the quantum Hall effect and electron heating in InSb/AlInSb". Physical Review B. American Physical Society (APS). 86 (4): 045404. Bibcode:2012PhRvB..86d5404A. doi:10.1103/physrevb.86.045404.
  15. Will Knight (2005-02-10). "'Quantum well' transistor promises lean computing". New Scientist. Retrieved 2020-01-11.

Cited sources