Praseodymium(III) selenate

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Praseodymium(III) selenate
Names
Other names
Praseodymium(III) selenate(VI)
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/3H2O4Se.2Pr/c3*1-5(2,3)4;;/h3*(H2,1,2,3,4);;/q;;;2*+3/p-6
    Key: RAKZQMKNASWERS-UHFFFAOYSA-H
  • [O-][Se](=O)(=O)[O-].[O-][Se](=O)(=O)[O-].[O-][Se](=O)(=O)[O-].[Pr+3].[Pr+3]
Properties
Pr2(SeO4)3
Molar mass 710.6868 g/mol (anhydrous)
782.74792 g/mol (tetrahydrate)
800.7632 g/mol (pentahydrate)
836.79376 g/mol (heptahydrate)
854.80904 g/mol (octahydrate)
926.87016 g/mol (dodecahydrate)
Appearancepale green crystals (heptahydrate) [1]
Density 4.3 g/cm3 (anhydrous)
3.85 g/cm3 (tetrahydrate) [2]
3.094 g/cm3 (octahydrate)
36 g/100 mL (0 °C)
3 g/100 mL (92 °C)
Related compounds
Other anions
Praseodymium(III) sulfate
Other cations
Cerium(III) selenate
Neodymium(III) selenate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Praseodymium(III) selenate is an inorganic compound, the salt of praseodymium and selenic acid with the chemical formula Pr2(SeO4)3. It forms green crystals when hydrated.

Contents

Preparation

Praseodymium(III) selenate can be obtained by dissolving praseodymium(III) oxide in a solution of selenic acid: [3]

Pr2O3 + 3 H2SeO4 → Pr2(SeO4)3 + 3 H2O

Properties

Praseodymium(III) selenate dissolves in water, and forms green crystals when hydrated. These crystals are of Pr2(SeO4)3·nH2O, where n = 4, 5, 7, 8 and 12. During crystallization from cold solutions, the octahydrate is formed, and the pentahydrate can be formed from hot solutions.

With potassium selenate and many other selenate salts, it forms double salts such as Pr2(SeO4)3·nK2SeO4·4H2O (n = 1 and 3).

Related Research Articles

In chemistry, a salt is a chemical compound consisting of an ionic assembly of positively charged cations and negatively charged anions, which results in a compound with no net electric charge. A common example is table salt, with positively charged sodium ions and negatively charged chloride ions.

<span class="mw-page-title-main">Praseodymium(III) chloride</span> Chemical compound

Praseodymium(III) chloride is the inorganic compound with the formula PrCl3. Like other lanthanide trichlorides, it exists both in the anhydrous and hydrated forms. It is a blue-green solid that rapidly absorbs water on exposure to moist air to form a light green heptahydrate.

<span class="mw-page-title-main">Chromium(III) chloride</span> Chemical compound

Chromium(III) chloride (also called chromic chloride) is an inorganic chemical compound with the chemical formula CrCl3. It forms several hydrates with the formula CrCl3·nH2O, among which are hydrates where n can be 5 (chromium(III) chloride pentahydrate CrCl3·5H2O) or 6 (chromium(III) chloride hexahydrate CrCl3·6H2O). The anhydrous compound with the formula CrCl3 are violet crystals, while the most common form of the chromium(III) chloride are the dark green crystals of hexahydrate, CrCl3·6H2O. Chromium chlorides find use as catalysts and as precursors to dyes for wool.

Selenic acid is the inorganic compound with the formula H2SeO4. It is an oxoacid of selenium, and its structure is more accurately described as O2Se(OH)2. It is a colorless compound. Although it has few uses, one of its salts, sodium selenate is used in the production of glass and animal feeds.

<span class="mw-page-title-main">Iron(III) nitrate</span> Chemical compound

Iron(III) nitrate, or ferric nitrate, is the name used for a series of inorganic compounds with the formula Fe(NO3)3.(H2O)n. Most common is the nonahydrate Fe(NO3)3.(H2O)9. The hydrates are all pale colored, water-soluble paramagnetic salts.

<span class="mw-page-title-main">Selenium compounds</span> Chemical compounds containing selenium

Selenium compounds are compounds containing the element selenium (Se). Among these compounds, selenium has various oxidation states, the most common ones being −2, +4, and +6. Selenium compounds exist in nature in the form of various minerals, such as clausthalite, guanajuatite, tiemannite, crookesite etc., and can also coexist with sulfide minerals such as pyrite and chalcopyrite. For many mammals, selenium compounds are essential. For example, selenomethionine and selenocysteine are selenium-containing amino acids present in the human body. Selenomethionine participates in the synthesis of selenoproteins. The reduction potential and pKa (5.47) of selenocysteine are lower than those of cysteine, making some proteins have antioxidant activity. Selenium compounds have important applications in semiconductors, glass and ceramic industries, medicine, metallurgy and other fields.

<span class="mw-page-title-main">Thorium(IV) nitrate</span> Chemical compound

Thorium(IV) nitrate is a chemical compound, a salt of thorium and nitric acid with the formula Th(NO3)4. A white solid in its anhydrous form, it can form tetra- and pentahydrates. As a salt of thorium it is weakly radioactive.

Iron(II) selenate (ferrous selenate) is an inorganic compound with the formula FeSeO4. It has anhydrous and several hydrate forms. The pentahydrate has the structure, [Fe(H2O)4]SeO4•H2O, isomorphous to the corresponding iron(II) sulfate. Heptahydrate is also known, in form of unstable green crystalline solid.

Praseodymium(III) oxalate is an inorganic compound, a salt of praseodymium metal and oxalic acid with the chemical formula C6O12Pr2. The compound forms light green crystals, insoluble in water, also forms crystalline hydrates.

<span class="mw-page-title-main">Neodymium(III) acetate</span> Compound of neodymium

Neodymium(III) acetate is an inorganic salt composed of a neodymium atom trication and three acetate groups as anions where neodymium exhibits the +3 oxidation state. It has a chemical formula of Nd(CH3COO)3 although it can be informally referred to as NdAc because Ac is an informal symbol for acetate. It commonly occurs as a light purple powder.

Neodymium(III) carbonate is an inorganic compound, a salt, where neodymium is in the +3 oxidation state and the carbonate ion is in the -2 oxidation state. It has a chemical formula of Nd2(CO3)3. The anhydrous form is purple-red, while the octahydrate is a pink solid. Both of these salts are insoluble in water.

<span class="mw-page-title-main">Neodymium(III) perchlorate</span> Chemical compound

Neodymium(III) perchlorate is an inorganic compound. It is a salt of neodymium and perchloric acid with the chemical formula of Nd(ClO4)3 – it is soluble in water, forming purple-pink, hydrated crystals.

Praseodymium(III) carbonate is an inorganic compound, with a chemical formula of Pr2(CO3)3. The anhydrous form is olive green, and many of its hydrates such as heptahydrate and octahydrate are known. They are all insoluble in water.

Nickel(II) selenate is a selenate of nickel with the chemical formula NiSeO4.

<span class="mw-page-title-main">Erbium(III) selenate</span> Chemical compound

Erbium(III) selenate is an inorganic compound, with the chemical formula Er2(SeO4)3. It exists as an anhydrate or an octahydrate.

<span class="mw-page-title-main">Holmium(III) selenate</span> Chemical compound

Holmium(III) selenate is an inorganic compound with the chemical formula Ho2(SeO4)3. It exists in the anhydrous form and as an octahydrate. It can be obtained by dissolving holmium(III) oxide in selenic acid solution and evaporating and crystallizing it. It co-crystallizes with other selenates in solution to obtain complex salts such as K3Ho(SeO4)3·nH2O, NH4Ho(SeO4)2·3H2O and CH3NH3Ho(SeO4)2·5H2O.

Cerium(IV) selenate is an inorganic compound with the chemical formula Ce(SeO4)2.

<span class="mw-page-title-main">Zirconium selenate</span> Chemical compound

Zirconium selenate is an inorganic compound with the chemical formula Zr(SeO4)2. Its tetrahydrate can be obtained by the reaction of selenic acid and a saturated aqueous solution of zirconium oxychloride octahydrate (or zirconium hydroxide). The tetrahydrate belongs to the orthorhombic crystal system and is isostructural with Zr(SO4)2·4H2O. It loses water when heated and becomes anhydrous at 220-230 °C. It reacts with potassium fluoride to obtain K2Zr(SeO4)2F2·3H2O.

Cerium(III) selenate is an inorganic compound with the chemical formula Ce2(SeO4)3. It can be obtained by reacting selenic acid and cerium(III) carbonate, and the solvent is evaporated to precipitate crystals. The double salt CsCe(SeO4)2·4H2O can be obtained from mixing cerium(III) selenate and cesium selenate in an aqueous solution, and then evaporating and crystallizing the solution.

Caesium selanate is an inorganic compound, with the chemical formula of Cs2SeO4. It can form colourless crystals of the orthorhombic crystal system.

References

  1. Sc, Y, La-Lu Rare Earth Elements: C 9 Compounds with Se. Springer Science & Business Media. 2013-11-11. p. 455. ISBN   978-3-662-06345-3.
  2. Villars, Pierre; Cenzual, Karin; Gladyshevskii, Roman (2013-12-18). Handbook. Walter de Gruyter GmbH & Co KG. p. 1105. ISBN   978-3-11-029444-6.
  3. Friend, J. Newton (1932). "352. The solubility of praseodymium selenate in water". Journal of the Chemical Society (Resumed): 2410–2413. doi:10.1039/jr9320002410. ISSN   0368-1769.