![]() Sodium chloride crystals in a form of halite | |
![]() Crystal structure with sodium in purple and chloride in green [1] | |
Names | |
---|---|
IUPAC name Sodium chloride | |
Other names
| |
Identifiers | |
3D model (JSmol) | |
3534976 | |
ChEBI | |
ChEMBL | |
ChemSpider | |
ECHA InfoCard | 100.028.726 |
EC Number |
|
13673 | |
KEGG | |
MeSH | Sodium+chloride |
PubChem CID | |
RTECS number |
|
UNII | |
CompTox Dashboard (EPA) | |
| |
| |
Properties | |
NaCl | |
Molar mass | 58.443 g/mol [2] |
Appearance | Colorless cubic crystals [2] |
Odor | Odorless |
Density | 2.17 g/cm3 [2] |
Melting point | 800.7 °C (1,473.3 °F; 1,073.8 K) [2] |
Boiling point | 1,465 °C (2,669 °F; 1,738 K) [2] |
360 g/L (25°C) [2] | |
Solubility in ammonia | 21.5 g/L |
Solubility in methanol | 14.9 g/L |
−30.2·10−6 cm3/mol [3] | |
Refractive index (nD) | 1.5441 (at 589 nm) [4] |
Structure [5] | |
Face-centered cubic (see text), cF8 | |
Fm3m (No. 225) | |
a = 564.02 pm | |
Formula units (Z) | 4 |
octahedral at Na+ octahedral at Cl− | |
Thermochemistry [6] | |
Heat capacity (C) | 50.5 J/(K·mol) |
Std molar entropy (S⦵298) | 72.10 J/(K·mol) |
Std enthalpy of formation (ΔfH⦵298) | −411.120 kJ/mol |
Pharmacology | |
A12CA01 ( WHO ) B05CB01 ( WHO ), B05XA03 ( WHO ), S01XA03 ( WHO ) | |
Hazards | |
NFPA 704 (fire diamond) | |
Lethal dose or concentration (LD, LC): | |
LD50 (median dose) | 3 g/kg (oral, rats) [7] |
Related compounds | |
Other anions | Sodium fluoride Sodium bromide Sodium iodide Sodium astatide |
Other cations | Lithium chloride Potassium chloride Rubidium chloride Caesium chloride Francium chloride |
Supplementary data page | |
Sodium chloride (data page) | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Sodium chloride /ˌsoʊdiəmˈklɔːraɪd/ , [8] commonly known as edible salt, is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chlorine ions. It is transparent or translucent, brittle, hygroscopic, and occurs as the mineral halite. In its edible form, it is commonly used as a condiment and food preservative. Large quantities of sodium chloride are used in many industrial processes, and it is a major source of sodium and chlorine compounds used as feedstocks for further chemical syntheses. Another major application of sodium chloride is deicing of roadways in sub-freezing weather.
In addition to the familiar domestic uses of salt, more dominant applications of the approximately 250 million tonnes per year production (2008 data) include chemicals and de-icing. [9]
Salt is used, directly or indirectly, in the production of many chemicals, which consume most of the world's production. [10]
It is the starting point for the chloralkali process, the industrial process to produce chlorine and sodium hydroxide, according to the chemical equation
This electrolysis is conducted in either a mercury cell, a diaphragm cell, or a membrane cell. Each of those uses a different method to separate the chlorine from the sodium hydroxide. Other technologies are under development due to the high energy consumption of the electrolysis, whereby small improvements in the efficiency can have large economic paybacks. Some applications of chlorine include PVC thermoplastics production, disinfectants, and solvents.
Sodium hydroxide is extensively used in many different industries enabling production of paper, soap, and aluminium etc.
Sodium chloride is used in the Solvay process to produce sodium carbonate and calcium chloride. Sodium carbonate, in turn, is used to produce glass, sodium bicarbonate, and dyes, as well as a myriad of other chemicals. In the Mannheim process, sodium chloride is used for the production of sodium sulfate and hydrochloric acid.
Sodium chloride is heavily used, so even relatively minor applications can consume massive quantities. In oil and gas exploration, salt is an important component of drilling fluids in well drilling. [11] It is used to flocculate and increase the density of the drilling fluid to overcome high downwell gas pressures. Whenever a drill hits a salt formation, salt is added to the drilling fluid to saturate the solution in order to minimize the dissolution within the salt stratum. [9] Salt is also used to increase the curing of concrete in cemented casings. [10]
In textiles and dyeing, salt is used as a brine rinse to separate organic contaminants, [12] to promote "salting out" of dyestuff precipitates, and to blend with concentrated dyes to increase yield in dyebaths and make the colors look sharper. One of its main roles is to provide the positive ion charge to promote the absorption of negatively charged ions of dyes. [10]
For use in the pulp and paper industry, it is used to manufacture sodium chlorate, which is then reacted with sulfuric acid and a reducing agent such as methanol to manufacture chlorine dioxide, a bleaching chemical that is widely used to bleach wood pulp.
In tanning and leather treatment, salt is added to animal hides to inhibit microbial activity on the underside of the hides and to attract moisture back into the hides. [10]
In rubber manufacture, salt is used to make buna, neoprene, and white rubber types. Salt brine and sulfuric acid are used to coagulate an emulsified latex made from chlorinated butadiene. [10] [9]
Salt also is added to secure the soil and to provide firmness to the foundation on which highways are built. The salt acts to minimize the effects of shifting caused in the subsurface by changes in humidity and traffic load. [10]
Hard water contains calcium and magnesium ions that interfere with action of soap and contribute to the buildup of a scale or film of alkaline mineral deposits in household and industrial equipment and pipes. Commercial and residential water-softening units use ion-exchange resins to remove ions that cause the hardness. These resins are generated and regenerated using sodium chloride. [10] [9]
The second major application of salt is for deicing and anti-icing of roads, both in grit bins and spread by winter service vehicles. In anticipation of snowfall, roads are optimally "anti-iced" with brine (concentrated solution of salt in water), which prevents bonding between the snow-ice and the road surface. This procedure obviates the heavy use of salt after the snowfall. For de-icing, mixtures of brine and salt are used, sometimes with additional agents such as calcium chloride and/or magnesium chloride. The use of salt or brine becomes ineffective below −10 °C (14 °F).
Salt for de-icing in the United Kingdom predominantly comes from a single mine in Winsford in Cheshire. Prior to distribution it is mixed with <100 ppm of sodium ferrocyanide as an anticaking agent, which enables rock salt to flow freely out of the gritting vehicles despite being stockpiled prior to use. In recent years this additive has also been used in table salt. Other additives had been used in road salt to reduce the total costs. For example, in the US, a byproduct carbohydrate solution from sugar-beet processing was mixed with rock salt and adhered to road surfaces about 40% better than loose rock salt alone. Because it stayed on the road longer, the treatment did not have to be repeated several times, saving time and money. [10]
In the technical terms of physical chemistry, the minimum freezing point of a water-salt mixture is −21.12 °C (−6.02 °F) for 23.31 wt% of salt. Freezing near this concentration is however so slow that the eutectic point of −22.4 °C (−8.3 °F) can be reached with about 25 wt% of salt. [13]
Road salt ends up in fresh-water bodies and could harm aquatic plants and animals by disrupting their osmoregulation ability. [14] The omnipresence of salt in coastal areas poses a problem in any coating application, because trapped salts cause great problems in adhesion. Naval authorities and ship builders monitor the salt concentrations on surfaces during construction. Maximal salt concentrations on surfaces are dependent on the authority and application. The IMO regulation is mostly used and sets salt levels to a maximum of 50 mg/m2 soluble salts measured as sodium chloride. These measurements are done by means of a Bresle test. Salinization (increasing salinity, aka freshwater salinization syndrome) and subsequent increased metal leaching is an ongoing problem throughout North America and European fresh waterways. [15]
In highway de-icing, salt has been associated with corrosion of bridge decks, motor vehicles, reinforcement bar and wire, and unprotected steel structures used in road construction. Surface runoff, vehicle spraying, and windblown salt also affect soil, roadside vegetation, and local surface water and groundwater supplies. Although evidence of environmental loading of salt has been found during peak usage, the spring rains and thaws usually dilute the concentrations of sodium in the area where salt was applied. [10] A 2009 study found that approximately 70% of the road salt being applied in the Minneapolis-St Paul metro area is retained in the local watershed. [16]
Some agencies are substituting beer, molasses, and beet juice instead of road salt. [17] Airlines utilize more glycol and sugar rather than salt-based solutions for deicing. [18]
Salt is added to food, either by the food producer or by the consumer, as a flavor enhancer, preservative, binder, fermentation-control additive, texture-control agent, and color developer. The salt consumption in the food industry is subdivided, in descending order of consumption, into other food processing, meat packers, canning, baking, dairy, and grain mill products. Salt is added to promote color development in bacon, ham and other processed meat products. As a preservative, salt inhibits the growth of bacteria. Salt acts as a binder in sausages to form a binding gel made up of meat, fat, and moisture. Salt also acts as a flavor enhancer and as a tenderizer. [10]
It is used as a cheap and safe desiccant because of its hygroscopic properties, making salting an effective method of food preservation historically; the salt draws water out of bacteria through osmotic pressure, keeping it from reproducing, a major source of food spoilage. Even though more effective desiccants are available, few are safe for humans to ingest. Many microorganisms cannot live in a salty environment: water is drawn out of their cells by osmosis. For this reason salt is used to preserve some foods, such as bacon, fish, or cabbage.
In many dairy industries, salt is added to cheese as a color-, fermentation-, and texture-control agent. The dairy subsector includes companies that manufacture creamery butter, condensed and evaporated milk, frozen desserts, ice cream, natural and processed cheese, and specialty dairy products. In canning, salt is primarily added as a flavor enhancer and preservative. It also is used as a carrier for other ingredients, dehydrating agent, enzyme inhibitor and tenderizer. In baking, salt is added to control the rate of fermentation in bread dough. It also is used to strengthen the gluten (the elastic protein-water complex in certain doughs) and as a flavor enhancer, such as a topping on baked goods. The food-processing category also contains grain mill products. These products consist of milling flour and rice and manufacturing cereal breakfast food and blended or prepared flour. Salt is also used a seasoning agent, e.g. in potato chips, pretzels, and cat and dog food. [10]
Sodium chloride is used in veterinary medicine as emesis-causing agent. It is given as warm saturated solution. Emesis can also be caused by pharyngeal placement of small amount of plain salt or salt crystals.
Sodium chloride is used together with water as one of the primary solutions for intravenous therapy. Nasal spray often contains a saline solution.
Sodium chloride is also available as an oral tablet, and is taken to treat low sodium levels. [19]
Sodium chloride is the principal extinguishing agent in dry-powder fire extinguishers that are used on combustible metal fires, for metals such as magnesium, zirconium, titanium, and lithium (Class D extinguishers). The salt forms an oxygen-excluding crust that smothers the fire. [20]
Since at least medieval times, people have used salt as a cleansing agent rubbed on household surfaces. It is also used in many brands of shampoo, toothpaste, and popularly to de-ice driveways and patches of ice.
Sodium chloride crystals have a transmittance of at least 90% (through 1 mm) for infrared light having wavelengths in the range 0.2– 18 μm. [21] They were used in optical components such as windows and lenses, where few non-absorbing alternatives existed in that spectral range. While inexpensive, NaCl crystals are soft and hygroscopic – when exposed to the water in ambient air, they gradually cover with "frost". This limits application of NaCl to dry environments, vacuum-sealed areas, or short-term uses such as prototyping. Materials that are mechanically stronger and less sensitive to moisture, such as zinc selenide and chalcogenide glasses, more widely used than NaCl.
In solid sodium chloride, each ion is surrounded by six ions of the opposite charge as expected on electrostatic grounds. The surrounding ions are located at the vertices of a regular octahedron. In the language of close-packing, the larger chloride ions (167 pm in size [22] ) are arranged in a cubic array whereas the smaller sodium ions (116 pm [22] ) fill all the cubic gaps (octahedral voids) between them. This same basic structure is found in many other compounds and is commonly known as the NaCl structure or rock salt crystal structure. It can be represented as a face-centered cubic (fcc) lattice with a two-atom basis or as two interpenetrating face centered cubic lattices. The first atom is located at each lattice point, and the second atom is located halfway between lattice points along the fcc unit cell edge.
Solid sodium chloride has a melting point of 801 °C and liquid sodium chloride boils at 1465 °C. Atomic-resolution real-time video imaging allows visualization of the initial stage of crystal nucleation of sodium chloride. [23]
The Thermal conductivity of sodium chloride as a function of temperature has a maximum of 2.03 W/(cm K) at 8 K (−265.15 °C; −445.27 °F) and decreases to 0.069 at 314 K (41 °C; 106 °F). It also decreases with doping. [24]
From cold (sub-freezing) solutions, salt crystallises with water of hydration as hydrohalite (the dihydrate NaCl·2H2O). [26]
In 2023, it was discovered that under pressure, sodium chloride can form the hydrates NaCl·8.5H2O and NaCl·13H2O. [27]
The attraction between the Na+ and Cl− ions in the solid is so strong that only highly polar solvents like water dissolve NaCl well.
When dissolved in water, the sodium chloride framework disintegrates as the Na+ and Cl− ions become surrounded by polar water molecules. These solutions consist of metal aquo complex with the formula [Na(H2O)8]+, with the Na–O distance of 250 pm. The chloride ions are also strongly solvated, each being surrounded by an average of six molecules of water. [28] Solutions of sodium chloride have very different properties from pure water. The eutectic point is −21.12 °C (−6.02 °F) for 23.31% mass fraction of salt, and the boiling point of saturated salt solution is near 108.7 °C (227.7 °F). [13]
The pH of a sodium chloride solution remains ≈7 due to the extremely weak basicity of the Cl− ion, which is the conjugate base of the strong acid HCl. In other words, NaCl has no effect on system pH [29] in diluted solutions where the effects of ionic strength and activity coefficients are negligible.
Solubility of NaCl (g NaCl / 1 kg of solvent at 25 °C (77 °F)) [30] | |
---|---|
Water | 360 |
Formamide | 94 |
Glycerin | 83 |
Propylene glycol | 71 |
Formic acid | 52 |
Liquid ammonia | 30.2 |
Methanol | 14 |
Ethanol | 0.65 |
Dimethylformamide | 0.4 |
Propan-1-ol | 0.124 |
Sulfolane | 0.05 |
Butan-1-ol | 0.05 |
Propan-2-ol | 0.03 |
Pentan-1-ol | 0.018 |
Acetonitrile | 0.003 |
Acetone | 0.00042 |
Common salt has a 1:1 molar ratio of sodium and chlorine. In 2013, compounds of sodium and chloride of different stoichiometries have been discovered; five new compounds were predicted (e.g., Na3Cl, Na2Cl, Na3Cl2, NaCl3, and NaCl7). The existence of some of them has been experimentally confirmed at high pressures and other conditions: cubic and orthorhombic NaCl3, two-dimensional metallic tetragonal Na3Cl and exotic hexagonal NaCl. [31] This indicates that compounds violating chemical intuition are possible, in simple systems under non-ambient conditions. [32]
Salt is found in the Earth's crust as the mineral halite (rock salt), and a tiny amount exists as suspended sea salt particles in the atmosphere. [33] These particles are the dominant cloud condensation nuclei far out at sea, which allow the formation of clouds in otherwise non-polluted air. [34]
Salt is currently mass-produced by evaporation of seawater or brine from brine wells and salt lakes. Mining of rock salt is also a major source. China is the world's main supplier of salt. [10] In 2017, world production was estimated at 280 million tonnes, the top five producers (in million tonnes) being China (68.0), United States (43.0), India (26.0), Germany (13.0), and Canada (13.0). [35] Salt is also a byproduct of potassium mining.
Chlorine is a chemical element; it has symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is a yellow-green gas at room temperature. It is an extremely reactive element and a strong oxidising agent: among the elements, it has the highest electron affinity and the third-highest electronegativity on the revised Pauling scale, behind only oxygen and fluorine.
Sodium is a chemical element; it has symbol Na and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable isotope is 23Na. The free metal does not occur in nature and must be prepared from compounds. Sodium is the sixth most abundant element in the Earth's crust and exists in numerous minerals such as feldspars, sodalite, and halite (NaCl). Many salts of sodium are highly water-soluble: sodium ions have been leached by the action of water from the Earth's minerals over eons, and thus sodium and chlorine are the most common dissolved elements by weight in the oceans.
Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations Na+ and hydroxide anions OH−.
The term chloride refers to a compound or molecule that contains either a chlorine ion, which is a negatively charged chlorine atom, or a non-charged chlorine atom covalently bonded to the rest of the molecule by a single bond. Many inorganic chlorides are salts. Many organic compounds are chlorides. The pronunciation of the word "chloride" is.
Brine is water with a high-concentration solution of salt. In diverse contexts, brine may refer to the salt solutions ranging from about 3.5% up to about 26%. Brine forms naturally due to evaporation of ground saline water but it is also generated in the mining of sodium chloride. Brine is used for food processing and cooking, for de-icing of roads and other structures, and in a number of technological processes. It is also a by-product of many industrial processes, such as desalination, so it requires wastewater treatment for proper disposal or further utilization.
Sodium carbonate is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water. Historically, it was extracted from the ashes of plants grown in sodium-rich soils, and because the ashes of these sodium-rich plants were noticeably different from ashes of wood, sodium carbonate became known as "soda ash". It is produced in large quantities from sodium chloride and limestone by the Solvay process, as well as by carbonating sodium hydroxide which is made using the Chlor-alkali process.
Potassium chloride is a metal halide salt composed of potassium and chlorine. It is odorless and has a white or colorless vitreous crystal appearance. The solid dissolves readily in water, and its solutions have a salt-like taste. Potassium chloride can be obtained from ancient dried lake deposits. KCl is used as a fertilizer, in medicine, in scientific applications, domestic water softeners, and in food processing, where it may be known as E number additive E508.
Sodium hypochlorite is an alkaline inorganic chemical compound with the formula NaOCl. It is commonly known in a dilute aqueous solution as bleach or chlorine bleach. It is the sodium salt of hypochlorous acid, consisting of sodium cations and hypochlorite anions.
Calcium chloride is an inorganic compound, a salt with the chemical formula CaCl2. It is a white crystalline solid at room temperature, and it is highly soluble in water. It can be created by neutralising hydrochloric acid with calcium hydroxide.
Magnesium chloride is an inorganic compound with the formula MgCl2. It forms hydrates MgCl2·nH2O, where n can range from 1 to 12. These salts are colorless or white solids that are highly soluble in water. These compounds and their solutions, both of which occur in nature, have a variety of practical uses. Anhydrous magnesium chloride is the principal precursor to magnesium metal, which is produced on a large scale. Hydrated magnesium chloride is the form most readily available.
The chloralkali process is an industrial process for the electrolysis of sodium chloride (NaCl) solutions. It is the technology used to produce chlorine and sodium hydroxide, which are commodity chemicals required by industry. Thirty five million tons of chlorine were prepared by this process in 1987. The chlorine and sodium hydroxide produced in this process are widely used in the chemical industry.
Barium chloride is an inorganic compound with the formula BaCl2. It is one of the most common water-soluble salts of barium. Like most other water-soluble barium salts, it is a white powder, highly toxic, and imparts a yellow-green coloration to a flame. It is also hygroscopic, converting to the dihydrate BaCl2·2H2O, which are colourless crystals with a bitter salty taste. It has limited use in the laboratory and industry.
Water softening is the removal of calcium, magnesium, and certain other metal cations in hard water. The resulting soft water requires less soap for the same cleaning effort, as soap is not wasted bonding with calcium ions. Soft water also extends the lifetime of plumbing by reducing or eliminating scale build-up in pipes and fittings. Water softening is usually achieved using lime softening or ion-exchange resins, but is increasingly being accomplished using nanofiltration or reverse osmosis membranes.
Deicing is the process of removing snow, ice or frost from a surface. Anti-icing is the application of chemicals that not only deice but also remain on a surface and continue to delay the reformation of ice for a certain period of time, or prevent adhesion of ice to make mechanical removal easier.
Sodium bromide is an inorganic compound with the formula NaBr. It is a high-melting white, crystalline solid that resembles sodium chloride. It is a widely used source of the bromide ion and has many applications.
Saline water is water that contains a high concentration of dissolved salts. On the United States Geological Survey (USGS) salinity scale, saline water is saltier than brackish water, but less salty than brine. The salt concentration is usually expressed in parts per thousand and parts per million (ppm). The USGS salinity scale defines three levels of saline water. The salt concentration in slightly saline water is 1,000 to 3,000 ppm (0.1–0.3%); in moderately saline water is 3,000 to 10,000 ppm (0.3–1%); and in highly saline water is 10,000 to 35,000 ppm (1–3.5%). Seawater has a salinity of roughly 35,000 ppm, equivalent to 35 grams of salt per one liter of water. The saturation level is only nominally dependent on the temperature of the water. At 20 °C (68 °F) one liter of water can dissolve about 357 grams of salt, a concentration of 26.3 percent by weight. At 100 °C (212 °F), the amount of salt that can be dissolved in one liter of water increases to about 391 grams, a concentration of 28.1% w/w.
Sodium formate, HCOONa, is the sodium salt of formic acid, HCOOH. It usually appears as a white deliquescent powder.
The Castner–Kellner process is a method of electrolysis on an aqueous alkali chloride solution to produce the corresponding alkali hydroxide, invented by American Hamilton Castner and Austrian Carl Kellner in the 1890s. Due to lower energy cost and fewer environmental concerns, the Castner–Kellner process is being replaced gradually with membrane electrolysis.
Chlorine gas can be produced by extracting from natural materials, including the electrolysis of a sodium chloride solution (brine) and other ways.
Soil stabilization is a general term for any physical, chemical, mechanical, biological, or combined method of changing a natural soil to meet an engineering purpose. Improvements include increasing the weight-bearing capabilities, tensile strength, and overall performance of unstable subsoils, sands, and waste materials in order to strengthen road pavements.
Neutralization of a strong acid and a strong base gives a neutral salt.