Names | |
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Preferred IUPAC name 3-Sulfanylidenepropa-1,2-dien-1-ylidene | |
Other names Tricarbon sulfur | |
Identifiers | |
3D model (JSmol) | |
ChemSpider | |
PubChem CID | |
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Properties | |
C3S | |
Molar mass | 68.09 g·mol−1 |
Related compounds | |
dicarbon monosulfide carbon monosulfide carbon disulfide | |
Related compounds | tricarbon monoxide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Tricarbon monosulfide (C3S) or tricarbon sulfur [1] is a reactive molecular substance that has been detected in outer space. Tricarbon monosulfide is a heterocumulene or thiocumulene, consisting of a straight chain of three carbon atoms and a terminal sulfur atom. [2]
The dipole moment of tricarbon monosulfide is 3.704 debye. The bond lengths are 1.275 Å, for terminal C=C bond, 1.292 Å for internal bond, and 1.535 Å for the C=S bond. The similar bond lengths between the carbon atoms indicate they each have a double bond nature. [2] The rotational constants for 12C12C12C32S are B0 = 2890.38000 MHz and D0 = 0.00022416. [3]
There is a characteristic infrared absorption band at 2047.5 cm−1 due to stretching of a C=C bond. [1]
Along with the related dicarbon monosulfide (CCS), tricarbon monosulfide was made by a glow discharge though carbon disulfide vapour in helium. Microwave emission lines from rotational transitions matched up with previously unknown molecular lines from the Taurus molecular cloud 1. [4] [3] Maximal concentrations occurred with a carbon disulfide pressure of 0.02 torr.
In molecular clouds, the formation mechanism is speculated to be CCS + CH → CCCS + H. [5]
On dust grains, in space the formation mechanism is theorised to be: CCC + H2S → C3•HSH → CCCS + H2 when irradiated with visible or UV light. THis reaction has been reproduced in a solid argon matrix. [1]
Tricarbon monosulfide has been detected in molecular clouds in space, such as the Taurus molecular cloud [2] and the Kleinmann–Low Nebula. [6] The ratio of tricarbon monoxide to tricarbon monosulfide reflects the ratio of sulfur to oxygen in the cloud. The ratio of concentration of sulfur to oxygen analogues follows the same pattern. [2] The clouds can be cold and dark, or warm. [6] CCCS has also been found in the stellar envelope of carbon-rich AGB stars, including in IRC+10216. [7]
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The cyano radical (or cyanido radical) is a radical with molecular formula CN, sometimes written •CN. The cyano radical was one of the first detected molecules in the interstellar medium, in 1938. Its detection and analysis was influential in astrochemistry. The discovery was confirmed with a coudé spectrograph, which was made famous and credible due to this detection. ·CN has been observed in both diffuse clouds and dense clouds. Usually, CN is detected in regions with hydrogen cyanide, hydrogen isocyanide, and HCNH+, since it is involved in the creation and destruction of these species (see also Cyanogen).
Imidogen is an inorganic compound with the chemical formula NH. Like other simple radicals, it is highly reactive and consequently short-lived except as a dilute gas. Its behavior depends on its spin multiplicity.
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A heterocumulene is a molecule or ion containing a chain of at least three double bonds between consecutive atoms, in which one or more atoms in the doubly bonded chain is a heteroatom. Such species are analogous to a cumulene in which the chain of doubly bonded atoms contains only carbon, except that at least one carbon is replaced by a heteroatom. Some authors relax the definition to include species with chains of only two double bonds between consecutive atoms, also known as heteroallenes.
Thioxoethenylidene, is a reactive heteroallene molecule with formula CCS.
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