Carbon monosulfide

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Carbon monosulfide
Carbon monosulfide.svg
Carbon monosulfide molecule spacefill.png
Names
IUPAC name
carbon monosulfide
Other names
carbon(II) sulfide, thiocarbonyl, sulfidocarbon, methanidylidynesulfanium
Identifiers
3D model (JSmol)
1697516, 1918616
ChEBI
ChemSpider
648
PubChem CID
  • InChI=1S/CS/c1-2 X mark.svgN
    Key: DXHPZXWIPWDXHJ-UHFFFAOYSA-N X mark.svgN
  • InChI=1/CS/c1-2
    Key: DXHPZXWIPWDXHJ-UHFFFAOYAW
  • [S+]#[C-]
Properties
CS
Molar mass 44.07 g·mol−1
Appearancereddish crystalline powder
insoluble
Related compounds
Other anions
Carbon monoxide
Other cations
Silicon monosulfide
Germanium monosulfide
Tin(II) sulfide
Lead(II) sulfide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Carbon monosulfide is a chemical compound with the formula CS. This diatomic molecule is the sulfur analogue of carbon monoxide, and is unstable as a solid or a liquid, but it has been observed as a gas both in the laboratory and in the interstellar medium. [1] The molecule resembles carbon monoxide with a triple bond between carbon and sulfur. The molecule is not intrinsically unstable, but it tends to polymerize in sunlight to a brown mass, as first discovered in 1868 and 1872. [2] The polymer is quite stable, decomposing a little at 360 °C to carbon disulfide. This tendency towards polymerization reflects the greater stability of C–S single bonds.

Polymers with the formula (CS)n have been reported, [3] and the formal dimer is ethenedithione. Also, CS has been observed as a ligand in some transition metal complexes.[ citation needed ]

The simplest carbon monosulfide synthesis decomposes carbon disulfide in a high-voltage AC arc. [4]

Related Research Articles

<span class="mw-page-title-main">Carbon disulfide</span> Neurotoxic compound with formula S=C=S

Carbon disulfide is an inorganic compound with the chemical formula CS2 and structure S=C=S. It is also considered as the anhydride of thiocarbonic acid. It is a colorless, flammable, neurotoxic liquid that is used as a building block in organic synthesis. Pure carbon disulfide has a pleasant, ether- or chloroform-like odor, but commercial samples are usually yellowish and are typically contaminated with foul-smelling impurities.

<span class="mw-page-title-main">Sulfur monoxide</span> Chemical compound

Sulfur monoxide is an inorganic compound with formula SO. It is only found as a dilute gas phase. When concentrated or condensed, it converts to S2O2 (disulfur dioxide). It has been detected in space but is rarely encountered intact otherwise.

Organosulfur chemistry is the study of the properties and synthesis of organosulfur compounds, which are organic compounds that contain sulfur. They are often associated with foul odors, but many of the sweetest compounds known are organosulfur derivatives, e.g., saccharin. Nature is abound with organosulfur compounds—sulfur is vital for life. Of the 20 common amino acids, two are organosulfur compounds, and the antibiotics penicillin and sulfa drugs both contain sulfur. While sulfur-containing antibiotics save many lives, sulfur mustard is a deadly chemical warfare agent. Fossil fuels, coal, petroleum, and natural gas, which are derived from ancient organisms, necessarily contain organosulfur compounds, the removal of which is a major focus of oil refineries.

<span class="mw-page-title-main">Carbonyl sulfide</span> Chemical compound

Carbonyl sulfide is the chemical compound with the linear formula O=C=S. It is a colorless flammable gas with an unpleasant odor. It is a linear molecule consisting of a carbonyl double bonded to a sulfur atom. Carbonyl sulfide can be considered to be intermediate between carbon dioxide and carbon disulfide, both of which are valence isoelectronic with it.

<span class="mw-page-title-main">Heptazine</span> Chemical compound

Heptazine, or tri-s-triazine or cyamelurine, is a chemical compound with formula C
6
N
7
H
3
, that consist of a planar triangular core group or three fused triazine rings, with three hydrogen atoms at the corners. It is a yellow, weakly fluorescent solid with melting point over 300 °C. It is soluble in organic solvents such as acetonitrile, but is decomposed by water and light.

<span class="mw-page-title-main">Carbon suboxide</span> Organic compound with structure O=C=C=C=O

Carbon suboxide, or tricarbon dioxide, is an organic, oxygen-containing chemical compound with formula C3O2 and structure O=C=C=C=O. Its four cumulative double bonds make it a cumulene. It is one of the stable members of the series of linear oxocarbons O=Cn=O, which also includes carbon dioxide and pentacarbon dioxide. Although if carefully purified it can exist at room temperature in the dark without decomposing, it will polymerize under certain conditions.

Sulfur compounds are chemical compounds formed the element sulfur (S). Common oxidation states of sulfur range from −2 to +6. Sulfur forms stable compounds with all elements except the noble gases.

<span class="mw-page-title-main">Allotropes of sulfur</span> Class of substances

The element sulfur exists as many allotropes. In number of allotropes, sulfur is second only to carbon. In addition to the allotropes, each allotrope often exists in polymorphs delineated by Greek prefixes.

<span class="mw-page-title-main">Oxocarbon</span> Chemical compounds made of only carbon and oxygen

In chemistry, an oxocarbon or oxide of carbon is a chemical compound consisting only of carbon and oxygen. The simplest and most common oxocarbons are carbon monoxide (CO) and carbon dioxide. Many other stable or metastable oxides of carbon are known, but they are rarely encountered, such as carbon suboxide and mellitic anhydride.

<span class="mw-page-title-main">Cyclohexanehexone</span> Chemical compound

Cyclohexanehexone, also known as hexaketocyclohexane and triquinoyl, is an organic compound with formula C6O6, the sixfold ketone of cyclohexane. It is an oxide of carbon, a hexamer of carbon monoxide.

Sulfur mononitride is an inorganic compound with the molecular formula SN. It is the sulfur analogue of and isoelectronic to the radical nitric oxide, NO. It was initially detected in 1975, in outer space in giant molecular clouds and later the coma of comets. This spurred further laboratory studies of the compound. Synthetically, it is produced by electric discharge in mixtures of nitrogen and sulfur compounds, or combustion in the gas phase and by photolysis in solution.

<span class="mw-page-title-main">Disulfur monoxide</span> Chemical compound with sulfur and oxygen

Disulfur monoxide or sulfur suboxide is an inorganic compound with the formula S2O, one of the lower sulfur oxides. It is a colourless gas and condenses to give a roughly dark red coloured solid that is unstable at room temperature.

<span class="mw-page-title-main">Disulfur dioxide</span> Chemical compound

Disulfur dioxide, dimeric sulfur monoxide or SO dimer is an oxide of sulfur with the formula S2O2. The solid is unstable with a lifetime of a few seconds at room temperature.

<span class="mw-page-title-main">Phosphorus mononitride</span> Chemical compound

Phosphorus mononitride is an inorganic compound with the chemical formula PN. Containing only phosphorus and nitrogen, this material is classified as a binary nitride. From the Lewis structure perspective, it can be represented with a P-N triple bond with a lone pair on each atom. It is isoelectronic with N2, CO, P2, CS and SiO.

<span class="mw-page-title-main">Tricarbon monoxide</span> Chemical compound

Tricarbon monoxide C3O is a reactive radical oxocarbon molecule found in space, and which can be made as a transient substance in the laboratory. It can be trapped in an inert gas matrix or made as a short lived gas. C3O can be classified as a ketene or an oxocumulene a kind of heterocumulene.

A heterocumulene is a molecule or ion containing a chain of at least three double bonds between consecutive atoms, in which one or more atoms in the doubly bonded chain is a heteroatom. Such species are analogous to a cumulene in which the chain of doubly bonded atoms contains only carbon, except that at least one carbon is replaced by a heteroatom. Some authors relax the definition to include species with chains of only two double bonds between consecutive atoms, also known as heteroallenes.

<span class="mw-page-title-main">Sulfoxylic acid</span> Chemical compound

Sulfoxylic acid (H2SO2) (also known as hyposulfurous acid or sulfur dihydroxide) is an unstable oxoacid of sulfur in an intermediate oxidation state between hydrogen sulfide and dithionous acid. It consists of two hydroxy groups attached to a sulfur atom. Sulfoxylic acid contains sulfur in an oxidation state of +2. Sulfur monoxide (SO) can be considered as a theoretical anhydride for sulfoxylic acid, but it is not actually known to react with water.

Tricarbon monosulfide (C3S) or tricarbon sulfur is a reactive molecular substance that has been detected in outer space. Tricarbon monosulfide is a heterocumulene or thiocumulene, consisting of a straight chain of three carbon atoms and a terminal sulfur atom.

<span class="mw-page-title-main">Phosphorus monoxide</span> Chemical compound

Phosphorus monoxide is an unstable radical inorganic compound with molecular formula PO.

Ethenedithione or ethylenedithone is an unstable chemical substance with formula S=C=C=S made from carbon and sulfur.

References

  1. Wilson, R. W.; Penzias, A. A.; Wannier, P. G.; Linke, R. A. (1976). "Isotopic abundances in interstellar carbon monosulfide". Astrophysical Journal. 204 (pt 2): L135 –L137. Bibcode:1976ApJ...204L.135W. doi: 10.1086/182072 .
    • Discovery in 1868: Loew, Oscar (1868). "Notiz über die Wirkung des Sonnenlichts auf Kohlenbisulfid", from Zeitschrift für Chemie , vol. 11 issue 4, p.  622   via the Munich Digitization Center.
    • History and subsequent elucidation of the polymer: Dewar, James; Owen Jones, Humphrey (1910). "Note on carbon monosulphide", from Proceedings of the Royal Society of London, Series A, volume 83 issue 564, pp. 408–413. doi:10.1098/rspa.1910.0029
  2. Chou, J.-H.; Rauchfuss, T. B. (1997). "Solvatothermal Routes to Poly(Carbon Monosulfide)s Using Kinetically Stabilized Precursors" (PDF). Journal of the American Chemical Society. 119 (19): 4537–4538. doi:10.1021/ja970042w.
  3. Moltzen, Ejner K.; Klabunde, Kenneth J.; and Senning, Alexander (1988). "Carbon monosulfide", from Chemical Reviews , vol. 88 issue 2, pp. 391-406. doi : 10.1021/cr00084a003.