Octatetraynyl radical

Last updated
Octatetraynyl radical
Skeletal formula of the octatetraynyl radical with the explicit hydrogen added Octatetraynyl radical.png
Skeletal formula of the octatetraynyl radical with the explicit hydrogen added
Names
Preferred IUPAC name
Octa-1,3,5,7-tetrayn-1-yl
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/C8H/c1-3-5-7-8-6-4-2/h1H Yes check.svgY
    Key: GTEOCQSGHJLKQX-UHFFFAOYSA-N Yes check.svgY
  • anion:InChI=1S/C8H/c1-3-5-7-8-6-4-2/h1H/q-1
    Key: JPYHXIJMECKQLV-UHFFFAOYSA-N
  • [C]#CC#CC#CC#C
  • anion:[C-]#CC#CC#CC#C
Properties
C8H
Molar mass 97.096 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Yes check.svgY  verify  (what is  Yes check.svgYX mark.svgN ?)

Octatetraynyl radical (C8H) is an organic free radical with eight carbon atoms linked in a linear chain with alternating single bonds and triple bonds (H−C≡C−C≡C−C≡C−C≡C•).

In 2007 negatively charged octatetraynyl was detected in Galactic molecular source TMC-1, making it the second type of anion to be found in the interstellar medium (after hexatriynyl radical) and the largest such molecule detected to date. [1] [2]

References

  1. Remijan, Anthony J.; J. M. Hollis; F. J. Lovas; M. A. Cordiner; T. J. Millar; A. J. Markwick-Kemper; P. R. Jewell (July 20, 2007). "Detection of C8H and Comparison with C8H toward IRC +10 216". The Astrophysical Journal. 664 (1): L47 –L50. Bibcode:2007ApJ...664L..47R. doi: 10.1086/520704 .
  2. Brünken, S.; H. Gupta; C. A. Gottlieb; M. C. McCarthy; P. Thaddeus (July 20, 2007). "Detection of the Carbon Chain Negative Ion C8H in TMC-1". The Astrophysical Journal. 664 (1): L43 –L46. Bibcode:2007ApJ...664L..43B. doi:10.1086/520703. S2CID   120912943.