Atomic and molecular astrophysics

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Within a few million years the light from bright stars will have boiled away this molecular cloud of gas and dust. The cloud has broken off from the Carina Nebula. Newly formed stars are visible nearby, their images reddened by blue light being preferentially scattered by the pervasive dust. This image spans about two light years and was taken by the orbiting Hubble Space Telescope in 1999. Molecular.cloud.arp.750pix.jpg
Within a few million years the light from bright stars will have boiled away this molecular cloud of gas and dust. The cloud has broken off from the Carina Nebula. Newly formed stars are visible nearby, their images reddened by blue light being preferentially scattered by the pervasive dust. This image spans about two light years and was taken by the orbiting Hubble Space Telescope in 1999.

Atomic astrophysics is concerned with performing atomic physics calculations that will be useful to astronomers and using atomic data to interpret astronomical observations. Atomic physics plays a key role in astrophysics as astronomers' only information about a particular object comes through the light that it emits, and this light arises through atomic transitions.

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Molecular astrophysics, developed into a rigorous field of investigation by theoretical astrochemist Alexander Dalgarno beginning in 1967, concerns the study of emission from molecules in space. There are 110 currently known interstellar molecules. These molecules have large numbers of observable transitions. Lines may also be observed in absorption—for example the highly redshifted lines seen against the gravitationally lensed quasar PKS1830-211. High energy radiation, such as ultraviolet light, can break the molecular bonds which hold atoms in molecules. In general then, molecules are found in cool astrophysical environments. The most massive objects in our galaxy are giant clouds of molecules and dust known as giant molecular clouds. In these clouds, and smaller versions of them, stars and planets are formed. One of the primary fields of study of molecular astrophysics is star and planet formation. Molecules may be found in many environments, however, from stellar atmospheres to those of planetary satellites. Most of these locations are relatively cool, and molecular emission is most easily studied via photons emitted when the molecules make transitions between low rotational energy states. One molecule, composed of the abundant carbon and oxygen atoms, and very stable against dissociation into atoms, is carbon monoxide (CO). The wavelength of the photon emitted when the CO molecule falls from its lowest excited state to its zero energy, or ground, state is 2.6mm, or 115 gigahertz. This frequency is a thousand times higher than typical FM radio frequencies. At these high frequencies, molecules in the Earth's atmosphere can block transmissions from space, and telescopes must be located in dry (water is an important atmospheric blocker), high sites. Radio telescopes must have very accurate surfaces to produce high fidelity images.

On February 21, 2014, NASA announced a greatly upgraded database for tracking polycyclic aromatic hydrocarbons (PAHs) in the universe. According to scientists, more than 20% of the carbon in the universe may be associated with PAHs, possible starting materials for the formation of life. PAHs seem to have been formed shortly after the Big Bang, are widespread throughout the universe, and are associated with new stars and exoplanets. [1]

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<span class="mw-page-title-main">Atom</span> Smallest unit of a chemical element

Atoms are the basic particles of the chemical elements. An atom consists of a nucleus of protons and generally neutrons, surrounded by an electromagnetically bound swarm of electrons. The chemical elements are distinguished from each other by the number of protons that are in their atoms. For example, any atom that contains 11 protons is sodium, and any atom that contains 29 protons is copper. Atoms with the same number of protons but a different number of neutrons are called isotopes of the same element.

<span class="mw-page-title-main">Diatomic molecule</span> Molecule composed of any two atoms

Diatomic molecules are molecules composed of only two atoms, of the same or different chemical elements. If a diatomic molecule consists of two atoms of the same element, such as hydrogen or oxygen, then it is said to be homonuclear. Otherwise, if a diatomic molecule consists of two different atoms, such as carbon monoxide or nitric oxide, the molecule is said to be heteronuclear. The bond in a homonuclear diatomic molecule is non-polar.

<span class="mw-page-title-main">Electromagnetic spectrum</span> Range of frequencies or wavelengths of electromagnetic radiation

The electromagnetic spectrum is the full range of electromagnetic radiation, organized by frequency or wavelength. The spectrum is divided into separate bands, with different names for the electromagnetic waves within each band. From low to high frequency these are: radio waves, microwaves, infrared, visible light, ultraviolet, X-rays, and gamma rays. The electromagnetic waves in each of these bands have different characteristics, such as how they are produced, how they interact with matter, and their practical applications.

<span class="mw-page-title-main">Molecular cloud</span> Type of interstellar cloud

A molecular cloud, sometimes called a stellar nursery (if star formation is occurring within), is a type of interstellar cloud, the density and size of which permit absorption nebulae, the formation of molecules (most commonly molecular hydrogen, H2), and the formation of H II regions. This is in contrast to other areas of the interstellar medium that contain predominantly ionized gas.

<span class="mw-page-title-main">Maser</span> Device for producing coherent EM waves in the sub-visible spectrum

A maser is a device that produces coherent electromagnetic waves (microwaves), through amplification by stimulated emission. The term is an acronym for microwave amplification by stimulated emission of radiation. First suggested by Joseph Weber, the first maser was built by Charles H. Townes, James P. Gordon, and Herbert J. Zeiger at Columbia University in 1953. Townes, Nikolay Basov and Alexander Prokhorov were awarded the 1964 Nobel Prize in Physics for theoretical work leading to the maser. Masers are used as the timekeeping device in atomic clocks, and as extremely low-noise microwave amplifiers in radio telescopes and deep-space spacecraft communication ground stations.

Atomic, molecular, and optical physics (AMO) is the study of matter–matter and light–matter interactions, at the scale of one or a few atoms and energy scales around several electron volts. The three areas are closely interrelated. AMO theory includes classical, semi-classical and quantum treatments. Typically, the theory and applications of emission, absorption, scattering of electromagnetic radiation (light) from excited atoms and molecules, analysis of spectroscopy, generation of lasers and masers, and the optical properties of matter in general, fall into these categories.

<span class="mw-page-title-main">Astronomy</span> Scientific study of celestial objects

Astronomy is a natural science that studies celestial objects and the phenomena that occur in the cosmos. It uses mathematics, physics, and chemistry in order to explain their origin and their overall evolution. Objects of interest include planets, moons, stars, nebulae, galaxies, meteoroids, asteroids, and comets. Relevant phenomena include supernova explosions, gamma ray bursts, quasars, blazars, pulsars, and cosmic microwave background radiation. More generally, astronomy studies everything that originates beyond Earth's atmosphere. Cosmology is a branch of astronomy that studies the universe as a whole.

<span class="mw-page-title-main">Interstellar medium</span> Matter and radiation in the space between the star systems in a galaxy

The interstellar medium (ISM) is the matter and radiation that exists in the space between the star systems in a galaxy. This matter includes gas in ionic, atomic, and molecular form, as well as dust and cosmic rays. It fills interstellar space and blends smoothly into the surrounding intergalactic space. The energy that occupies the same volume, in the form of electromagnetic radiation, is the interstellar radiation field. Although the density of atoms in the ISM is usually far below that in the best laboratory vacuums, the mean free path between collisions is short compared to typical interstellar lengths, so on these scales the ISM behaves as a gas, responding to pressure forces, and not as a collection of non-interacting particles.

<span class="mw-page-title-main">Astrochemistry</span> Study of molecules in the Universe and their reactions

Astrochemistry is the study of the abundance and reactions of molecules in the universe, and their interaction with radiation. The discipline is an overlap of astronomy and chemistry. The word "astrochemistry" may be applied to both the Solar System and the interstellar medium. The study of the abundance of elements and isotope ratios in Solar System objects, such as meteorites, is also called cosmochemistry, while the study of interstellar atoms and molecules and their interaction with radiation is sometimes called molecular astrophysics. The formation, atomic and chemical composition, evolution and fate of molecular gas clouds is of special interest, because it is from these clouds that solar systems form.

<span class="mw-page-title-main">Astronomical spectroscopy</span> Study of astronomy using spectroscopy to measure the spectrum of electromagnetic radiation

Astronomical spectroscopy is the study of astronomy using the techniques of spectroscopy to measure the spectrum of electromagnetic radiation, including visible light, ultraviolet, X-ray, infrared and radio waves that radiate from stars and other celestial objects. A stellar spectrum can reveal many properties of stars, such as their chemical composition, temperature, density, mass, distance and luminosity. Spectroscopy can show the velocity of motion towards or away from the observer by measuring the Doppler shift. Spectroscopy is also used to study the physical properties of many other types of celestial objects such as planets, nebulae, galaxies, and active galactic nuclei.

<span class="mw-page-title-main">Emission spectrum</span> Frequencies of light emitted by atoms or chemical compounds

The emission spectrum of a chemical element or chemical compound is the spectrum of frequencies of electromagnetic radiation emitted due to electrons making a transition from a high energy state to a lower energy state. The photon energy of the emitted photons is equal to the energy difference between the two states. There are many possible electron transitions for each atom, and each transition has a specific energy difference. This collection of different transitions, leading to different radiated wavelengths, make up an emission spectrum. Each element's emission spectrum is unique. Therefore, spectroscopy can be used to identify elements in matter of unknown composition. Similarly, the emission spectra of molecules can be used in chemical analysis of substances.

<span class="mw-page-title-main">Cosmochemistry</span> Study of the chemical composition of matter in the universe

Cosmochemistry or chemical cosmology is the study of the chemical composition of matter in the universe and the processes that led to those compositions. This is done primarily through the study of the chemical composition of meteorites and other physical samples. Given that the asteroid parent bodies of meteorites were some of the first solid material to condense from the early solar nebula, cosmochemists are generally, but not exclusively, concerned with the objects contained within the Solar System.

<span class="mw-page-title-main">Absorption spectroscopy</span> Spectroscopic techniques that measure the absorption of radiation

Absorption spectroscopy is spectroscopy that involves techniques that measure the absorption of electromagnetic radiation, as a function of frequency or wavelength, due to its interaction with a sample. The sample absorbs energy, i.e., photons, from the radiating field. The intensity of the absorption varies as a function of frequency, and this variation is the absorption spectrum. Absorption spectroscopy is performed across the electromagnetic spectrum.

<span class="mw-page-title-main">Coma (comet)</span> Cloud of gas or a trail around a comet or asteroid

The coma is the nebulous envelope around the nucleus of a comet, formed when the comet passes near the Sun in its highly elliptical orbit. As the comet warms, parts of it sublimate; this gives a comet a diffuse appearance when viewed through telescopes and distinguishes it from stars. The word coma comes from the Greek κόμη (kómē), which means "hair" and is the origin of the word comet itself.

<span class="mw-page-title-main">Hydrogen line</span> Spectral line of hydrogen state transition in UHF radio frequencies

The hydrogen line, 21 centimeter line, or H I line is a spectral line that is created by a change in the energy state of solitary, electrically neutral hydrogen atoms. It is produced by a spin-flip transition, which means the direction of the electron's spin is reversed relative to the spin of the proton. This is a quantum state change between the two hyperfine levels of the hydrogen 1 s ground state. The electromagnetic radiation producing this line has a frequency of 1420.405751768(2) MHz (1.42 GHz), which is equivalent to a wavelength of 21.106114054160(30) cm in a vacuum. According to the Planck–Einstein relation E = , the photon emitted by this transition has an energy of 5.8743261841116(81) μeV [9.411708152678(13)×10−25 J]. The constant of proportionality, h, is known as the Planck constant.

<span class="mw-page-title-main">Theoretical astronomy</span> Applied and interdisciplinary physics

Theoretical astronomy is the use of analytical and computational models based on principles from physics and chemistry to describe and explain astronomical objects and astronomical phenomena. Theorists in astronomy endeavor to create theoretical models and from the results predict observational consequences of those models. The observation of a phenomenon predicted by a model allows astronomers to select between several alternate or conflicting models as the one best able to describe the phenomena.

<span class="mw-page-title-main">Cosmic dust</span> Dust floating in space

Cosmic dust – also called extraterrestrial dust, space dust, or star dust – is dust that occurs in outer space or has fallen onto Earth. Most cosmic dust particles measure between a few molecules and 0.1 mm (100 μm), such as micrometeoroids and meteoroids. Cosmic dust can be further distinguished by its astronomical location: intergalactic dust, interstellar dust, interplanetary dust, and circumplanetary dust. There are several methods to obtain space dust measurement.

<span class="mw-page-title-main">PAH world hypothesis</span> Hypothesis about the origin of life

The PAH world hypothesis is a speculative hypothesis that proposes that polycyclic aromatic hydrocarbons (PAHs), known to be abundant in the universe, including in comets, and assumed to be abundant in the primordial soup of the early Earth, played a major role in the origin of life by mediating the synthesis of RNA molecules, leading into the RNA world. However, as yet, the hypothesis is untested.

<span class="mw-page-title-main">Ethynyl radical</span> Hydrocarbon compound (•CCH)

The ethynyl radical (systematically named λ3-ethyne and hydridodicarbon(CC)) is an organic compound with the chemical formula C≡CH (also written [CCH] or C
2
H
). It is a simple molecule that does not occur naturally on Earth but is abundant in the interstellar medium. It was first observed by electron spin resonance isolated in a solid argon matrix at liquid helium temperatures in 1963 by Cochran and coworkers at the Johns Hopkins Applied Physics Laboratory. It was first observed in the gas phase by Tucker and coworkers in November 1973 toward the Orion Nebula, using the NRAO 11-meter radio telescope. It has since been detected in a large variety of interstellar environments, including dense molecular clouds, bok globules, star forming regions, the shells around carbon-rich evolved stars, and even in other galaxies.

In organic chemistry, cyanopolyynes are a family of organic compounds with the chemical formula HCnN (n = 3,5,7,…) and the structural formula H−[C≡C−]nC≡N (n = 1,2,3,…). Structurally, they are polyynes with a cyano group (−C≡N) covalently bonded to one of the terminal acetylene units (H−C≡C).

References

  1. Hoover, Rachel (February 21, 2014). "Need to Track Organic Nano-Particles Across the Universe? NASA's Got an App for That". NASA . Retrieved February 22, 2014.