Hydrogen cyanide is a chemical compound with the formula HCN and structural formula H−C≡N. It is a highly toxic and flammable liquid that boils slightly above room temperature, at 25.6 °C (78.1 °F). HCN is produced on an industrial scale and is a highly valued precursor to many chemical compounds ranging from polymers to pharmaceuticals. Large-scale applications are for the production of potassium cyanide and adiponitrile, used in mining and plastics, respectively. It is more toxic than solid cyanide compounds due to its volatile nature. A solution of hydrogen cyanide in water, represented as HCN, is called hydrocyanic acid. The salts of the cyanide anion are known as cyanides.
Titan is the largest moon of Saturn and the second-largest in the Solar System. It is the only moon known to have an atmosphere denser than the Earth's and is the only known object in space—other than Earth—on which clear evidence of stable bodies of surface liquid has been found. Titan is one of seven gravitationally rounded moons of Saturn and the second-most distant among them. Frequently described as a planet-like moon, Titan is 50% larger in diameter than Earth's Moon and 80% more massive. It is the second-largest moon in the Solar System after Jupiter's Ganymede and is larger than Mercury, but only 40% as massive due to the latter being composed mainly of dense iron and rock, while a large portion of Titan is less-dense ice.
Astrochemistry is the study of the abundance and reactions of molecules in the universe, and their interaction with radiation. The discipline is an overlap of astronomy and chemistry. The word "astrochemistry" may be applied to both the Solar System and the interstellar medium. The study of the abundance of elements and isotope ratios in Solar System objects, such as meteorites, is also called cosmochemistry, while the study of interstellar atoms and molecules and their interaction with radiation is sometimes called molecular astrophysics. The formation, atomic and chemical composition, evolution and fate of molecular gas clouds is of special interest, because it is from these clouds that solar systems form.
Tholins are a wide variety of organic compounds formed by solar ultraviolet or cosmic ray irradiation of simple carbon-containing compounds such as carbon dioxide, methane or ethane, often in combination with nitrogen or water. Tholins are disordered polymer-like materials made of repeating chains of linked subunits and complex combinations of functional groups, typically nitriles and hydrocarbons, and their degraded forms such as amines and phenyls. Tholins do not form naturally on modern-day Earth, but they are found in great abundance on the surfaces of icy bodies in the outer Solar System, and as reddish aerosols in the atmospheres of outer Solar System planets and moons.
Sulfur monoxide is an inorganic compound with formula SO. It is only found as a dilute gas phase. When concentrated or condensed, it converts to S2O2 (disulfur dioxide). It has been detected in space but is rarely encountered intact otherwise.
The trihydrogen cation or protonated molecular hydrogen is a cation with formula H+3, consisting of three hydrogen nuclei (protons) sharing two electrons.
Atmospheric escape is the loss of planetary atmospheric gases to outer space. A number of different mechanisms can be responsible for atmospheric escape; these processes can be divided into thermal escape, non-thermal escape, and impact erosion. The relative importance of each loss process depends on the planet's escape velocity, its atmosphere composition, and its distance from its star. Escape occurs when molecular kinetic energy overcomes gravitational energy; in other words, a molecule can escape when it is moving faster than the escape velocity of its planet. Categorizing the rate of atmospheric escape in exoplanets is necessary to determining whether an atmosphere persists, and so the exoplanet's habitability and likelihood of life.
The PAH world hypothesis is a speculative hypothesis that proposes that polycyclic aromatic hydrocarbons (PAHs), known to be abundant in the universe, including in comets, and assumed to be abundant in the primordial soup of the early Earth, played a major role in the origin of life by mediating the synthesis of RNA molecules, leading into the RNA world. However, as yet, the hypothesis is untested.
Dicyanoacetylene, also called carbon subnitride or but-2-ynedinitrile (IUPAC), is a compound of carbon and nitrogen with chemical formula C4N2. It has a linear molecular structure, N≡C−C≡C−C≡N, with alternating triple and single covalent bonds. It can be viewed as acetylene with the two hydrogen atoms replaced by cyanide groups.
The ethynyl radical (systematically named λ3-ethyne and hydridodicarbon(C—C)) is an organic compound with the chemical formula C≡CH (also written [CCH] or C
2H). It is a simple molecule that does not occur naturally on Earth but is abundant in the interstellar medium. It was first observed by electron spin resonance isolated in a solid argon matrix at liquid helium temperatures in 1963 by Cochran and coworkers at the Johns Hopkins Applied Physics Laboratory. It was first observed in the gas phase by Tucker and coworkers in November 1973 toward the Orion Nebula, using the NRAO 11-meter radio telescope. It has since been detected in a large variety of interstellar environments, including dense molecular clouds, bok globules, star forming regions, the shells around carbon-rich evolved stars, and even in other galaxies.
The study of extraterrestrial atmospheres is an active field of research, both as an aspect of astronomy and to gain insight into Earth's atmosphere. In addition to Earth, many of the other astronomical objects in the Solar System have atmospheres. These include all the giant planets, as well as Mars, Venus and Titan. Several moons and other bodies also have atmospheres, as do comets and the Sun. There is evidence that extrasolar planets can have an atmosphere. Comparisons of these atmospheres to one another and to Earth's atmosphere broaden our basic understanding of atmospheric processes such as the greenhouse effect, aerosol and cloud physics, and atmospheric chemistry and dynamics.
The atmosphere of Titan is the dense layer of gases surrounding Titan, the largest moon of Saturn. Titan is the only natural satellite in the Solar System with an atmosphere that is denser than the atmosphere of Earth and is one of two moons with an atmosphere significant enough to drive weather. Titan's lower atmosphere is primarily composed of nitrogen (94.2%), methane (5.65%), and hydrogen (0.099%). There are trace amounts of other hydrocarbons, such as ethane, diacetylene, methylacetylene, acetylene, propane, PAHs and of other gases, such as cyanoacetylene, hydrogen cyanide, carbon dioxide, carbon monoxide, cyanogen, acetonitrile, argon and helium. The isotopic study of nitrogen isotopes ratio also suggests acetonitrile may be present in quantities exceeding hydrogen cyanide and cyanoacetylene. The surface pressure is about 50% higher than on Earth at 1.5 bars which is near the triple point of methane and allows there to be gaseous methane in the atmosphere and liquid methane on the surface. The orange color as seen from space is produced by other more complex chemicals in small quantities, possibly tholins, tar-like organic precipitates.
The climate of Titan, the largest moon of Saturn, is similar in many respects to that of Earth, despite having a far lower surface temperature. Its thick atmosphere, methane rain, and possible cryovolcanism create an analogue, though with different materials, to the climatic changes undergone by Earth during the far shorter year of Earth.
Propynylidyne is a chemical compound that has been identified in interstellar space.
HCNH+, also known as protonated hydrogen cyanide, is a molecular ion of astrophysical interest. It also exists in the condensed state when formed by superacids.
Cyclopropenylidene, or c-C3H2, is a partially aromatic molecule belonging to a highly reactive class of organic molecules known as carbenes. On Earth, cyclopropenylidene is only seen in the laboratory due to its reactivity. However, cyclopropenylidene is found in significant concentrations in the interstellar medium (ISM) and on Saturn's moon Titan. Its C2v symmetric isomer, propadienylidene (CCCH2) is also found in the ISM, but with abundances about an order of magnitude lower. A third C2 symmetric isomer, propargylene (HCCCH), has not yet been detected in the ISM, most likely due to its low dipole moment.
In organic chemistry, cyanopolyynes are a family of organic compounds with the chemical formula HCnN (n = 3,5,7,…) and the structural formula H−[C≡C−]nC≡N (n = 1,2,3,…). Structurally, they are polyynes with a cyano group (−C≡N) covalently bonded to one of the terminal acetylene units (H−C≡C).
Imidogen is an inorganic compound with the chemical formula NH. Like other simple radicals, it is highly reactive and consequently short-lived except as a dilute gas. Its behavior depends on its spin multiplicity.
Phosphorus mononitride is an inorganic compound with the chemical formula PN. Containing only phosphorus and nitrogen, this material is classified as a binary nitride. From the Lewis structure perspective, it can be represented with a P-N triple bond with a lone pair on each atom. It is isoelectronic with N2, CO, P2, CS and SiO.
