Names | |||
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Preferred IUPAC name Ethanimine | |||
Other names As imine: ethylimine, ethylideneimine, ethylidenimine, acetaldehyde imine, acetaldehyde-ammonia Schiff base, acetaldimine, iminoethane As amine: ethenamine, ethyleneamine, ethylideneamine, aminoethylene, vinylamine, vinyl amine | |||
Identifiers | |||
3D model (JSmol) | |||
ChemSpider | |||
PubChem CID | |||
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Properties | |||
C2H5N | |||
Molar mass | 43.069 g·mol−1 | ||
Related compounds | |||
Related compounds | N-Methylmethanimine Methanimine | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Ethanimine is an organonitrogen compound classified as an imine. It is formed by reacting acetaldehyde and ammonia, but rapidly polymerizes to acetaldehyde ammonia trimer.
It has two tautomers: ethanimine, an imine, and ethenamine or aminoethylene, an amine. Ethanimine has two hydrogens on the carbon, while ethenamine has two on the nitrogen atom.
It is not well known terrestrially, but has been detected in abundance toward Sagittarius B2 (Sgr B2), a dense interstellar cloud between stars toward the Galactic Center of the Milky Way. The distance between the Sgr B2 cloud and center of galaxy is 100 pc (1 pc = 3.26 ly). Ethanimine is mainly found in hot cores of ISM clouds; in case of Sgr B2, the region would be the Sgr B2 N and Sgr B2 M. [1] Radio telescopes such as the Green Bank Observatory's Green Bank Telescope and those operated by the National Radio Astronomy Observatory (measuring radio frequency light lambda ranging from 1–300 GHz) are able to detect organic molecules such as ethanimines because its internal energy transition, more specifically the rotational transition is within the radio frequency of 14085 MHz = 140.8 GHz. [2]
A molecular cloud, sometimes called a stellar nursery (if star formation is occurring within), is a type of interstellar cloud, the density and size of which permit absorption nebulae, the formation of molecules (most commonly molecular hydrogen, H2), and the formation of H II regions. This is in contrast to other areas of the interstellar medium that contain predominantly ionized gas.
In chemistry, hydronium (hydroxonium in traditional British English) is the common name for the cation [H3O]+, also written as H3O+, the type of oxonium ion produced by protonation of water. It is often viewed as the positive ion present when an Arrhenius acid is dissolved in water, as Arrhenius acid molecules in solution give up a proton (a positive hydrogen ion, H+) to the surrounding water molecules (H2O). In fact, acids must be surrounded by more than a single water molecule in order to ionize, yielding aqueous H+ and conjugate base. Three main structures for the aqueous proton have garnered experimental support: the Eigen cation, which is a tetrahydrate, H3O+(H2O)3, the Zundel cation, which is a symmetric dihydrate, H+(H2O)2, and the Stoyanov cation, an expanded Zundel cation, which is a hexahydrate: H+(H2O)2(H2O)4. Spectroscopic evidence from well-defined IR spectra overwhelmingly supports the Stoyanov cation as the predominant form. For this reason, it has been suggested that wherever possible, the symbol H+(aq) should be used instead of the hydronium ion.
The Robert C. Byrd Green Bank Telescope (GBT) in Green Bank, West Virginia, US is the world's largest fully steerable radio telescope, surpassing the Effelsberg 100-m Radio Telescope in Germany. The Green Bank site was part of the National Radio Astronomy Observatory (NRAO) until September 30, 2016. Since October 1, 2016, the telescope has been operated by the independent Green Bank Observatory. The telescope's name honors the late Senator Robert C. Byrd who represented West Virginia and who pushed the funding of the telescope through Congress.
Sagittarius A*, abbreviated Sgr A*, is the supermassive black hole at the Galactic Center of the Milky Way. Viewed from Earth, it is located near the border of the constellations Sagittarius and Scorpius, about 5.6° south of the ecliptic, visually close to the Butterfly Cluster (M6) and Lambda Scorpii.
Onsala Space Observatory (OSO), the Swedish National Facility for Radio Astronomy, provides scientists with equipment to study the Earth and the rest of the Universe. The observatory operates two radio telescopes in Onsala, 45 km south of Gothenburg, and takes part in several international projects. Examples of activities:
The Wow! signal was a strong narrowband radio signal detected on August 15, 1977, by Ohio State University's Big Ear radio telescope in the United States, then used to support the search for extraterrestrial intelligence. The signal appeared to come from the direction of the constellation Sagittarius and bore the expected hallmarks of extraterrestrial origin.
An astrophysical maser is a naturally occurring source of stimulated spectral line emission, typically in the microwave portion of the electromagnetic spectrum. This emission may arise in molecular clouds, comets, planetary atmospheres, stellar atmospheres, or various other conditions in interstellar space.
Hydrogen isocyanide is a chemical with the molecular formula HNC. It is a minor tautomer of hydrogen cyanide (HCN). Its importance in the field of astrochemistry is linked to its ubiquity in the interstellar medium.
Sagittarius B2 is a giant molecular cloud of gas and dust that is located about 120 parsecs (390 ly) from the center of the Milky Way. This complex is the largest molecular cloud in the vicinity of the core and one of the largest in the galaxy, spanning a region about 45 parsecs (150 ly) across. The total mass of Sgr B2 is about 3 million times the mass of the Sun. The mean hydrogen density within the cloud is 3000 atoms per cm3, which is about 20–40 times denser than a typical molecular cloud.
Propynylidyne is a chemical compound that has been identified in interstellar space.
Diazenylium is the chemical N2H+, an inorganic cation that was one of the first ions to be observed in interstellar clouds. Since then, it has been observed for in several different types of interstellar environments, observations that have several different scientific uses. It gives astronomers information about the fractional ionization of gas clouds, the chemistry that happens within those clouds, and it is often used as a tracer for molecules that are not as easily detected (such as N2). Its 1–0 rotational transition occurs at 93.174 GHz, a region of the spectrum where Earth's atmosphere is transparent and it has a significant optical depth in both cold and warm clouds so it is relatively easy to observe with ground-based observatories. The results of N2H+ observations can be used not only for determining the chemistry of interstellar clouds, but also for mapping the density and velocity profiles of these clouds.
HCNH+, also known as protonated hydrogen cyanide, is a molecular ion of astrophysical interest. It also exists in the condensed state when formed by superacids.
The cyano radical (or cyanido radical) is a radical with molecular formula CN, sometimes written •CN. The cyano radical was one of the first detected molecules in the interstellar medium, in 1938. Its detection and analysis was influential in astrochemistry. The discovery was confirmed with a coudé spectrograph, which was made famous and credible due to this detection. ·CN has been observed in both diffuse clouds and dense clouds. Usually, CN is detected in regions with hydrogen cyanide, hydrogen isocyanide, and HCNH+, since it is involved in the creation and destruction of these species (see also Cyanogen).
Sagittarius A is a complex radio source at the center of the Milky Way, which contains a supermassive black hole. It is located in the constellation Sagittarius, and is hidden from view at optical wavelengths by large clouds of cosmic dust in the spiral arms of the Milky Way. The dust lane that obscures the Galactic Center from a vantage point around the Sun causes the Great Rift through the bright bulge of the galaxy.
Sulfur mononitride is an inorganic compound with the molecular formula SN. It is the sulfur analogue of and isoelectronic to the radical nitric oxide, NO. It was initially detected in 1975, in outer space in giant molecular clouds and later the coma of comets. This spurred further laboratory studies of the compound. Synthetically, it is produced by electric discharge in mixtures of nitrogen and sulfur compounds, or combustion in the gas phase and by photolysis in solution.
Imidogen is an inorganic compound with the chemical formula NH. Like other simple radicals, it is highly reactive and consequently short-lived except as a dilute gas. Its behavior depends on its spin multiplicity.
Breakthrough Listen is a project to search for intelligent extraterrestrial communications in the Universe. With $100 million in funding and thousands of hours of dedicated telescope time on state-of-the-art facilities, it is the most comprehensive search for alien communications to date. The project began in January 2016, and is expected to continue for 10 years. It is a component of Yuri Milner's Breakthrough Initiatives program. The science program for Breakthrough Listen is based at Berkeley SETI Research Center, located in the Astronomy Department at the University of California, Berkeley.
Isobutyronitrile is a complex organic molecule that has recently been found in several meteorites arrived from space. The singularity of this chemical is due to the fact that it is the only one among the molecules arriving from the universe that has a branched, rather than straight, carbon backbone. The backbone is also larger than usual, in comparison with others.
Phosphorus monoxide is an unstable radical inorganic compound with molecular formula PO.