Hydrogen deuteride

Last updated
Hydrogen deuteride
Hydrogen deuteride.svg
Hydrogen-deuteride-3D-vdW.png
Names
IUPAC name
Hydrogen deuteride
Systematic IUPAC name
(2H)Dihydrogen[ citation needed ]
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.325 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 237-773-0
PubChem CID
UN number 1049
  • InChI=1S/H2/h1H/i1+1 Yes check.svgY
    Key: UFHFLCQGNIYNRP-OUBTZVSYSA-N Yes check.svgY
  • InChI=1/H2/h1H/i1+1
    Key: UFHFLCQGNIYNRP-OUBTZVSYED
  • [2H][H]
Properties
HD
Molar mass 3.02204 g mol−1
Melting point −259 °C (−434.2 °F; 14.1 K)
Boiling point −253 °C (−423.4 °F; 20.1 K)
Hazards
GHS labelling:
GHS-pictogram-flamme.svg GHS-pictogram-bottle.svg
Danger
H220, H280
P210, P377, P381, P403, P410+P403
NFPA 704 (fire diamond)
NFPA 704.svgHealth 0: Exposure under fire conditions would offer no hazard beyond that of ordinary combustible material. E.g. sodium chlorideFlammability 4: Will rapidly or completely vaporize at normal atmospheric pressure and temperature, or is readily dispersed in air and will burn readily. Flash point below 23 °C (73 °F). E.g. propaneInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
0
4
0
571 °C (1,060 °F; 844 K)
Related compounds
Related hydrogens
Deuterium

Hydrogen
Tritium

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Yes check.svgY  verify  (what is  Yes check.svgYX mark.svgN ?)

Hydrogen deuteride is an isotopologue of dihydrogen composed of two isotopes of hydrogen: the majority isotope 1H (protium) and 2H (deuterium). Its proper molecular formula is 1H2H, but for simplification, it is usually written as HD.

Contents

Preparation and occurrence

In the laboratory it is produced by treating sodium hydride with deuterated water: [1]

NaH + D2O → HD + NaOD

Hydrogen deuteride is a minor component of naturally occurring molecular hydrogen. It is one of the minor but noticeable components of the atmospheres of all the giant planets, with abundances from about 30 ppm to about 200 ppm. HD has also been found in supernova remnants, [2] and other sources.[ citation needed ]

Occurrence of HD vs. H2 in giant planets' atmospheres
PlanetHDH2
Jupiter~0.003%89.8% ±2.0% [3]
Uranus~0.015%82.5% ±3.3% [4]
Neptune~0.019%80.0% ±3.2% [5]
H NMR spectrum of a solution of HD (labeled with red bars) and
H2 (blue bar). The 1:1:1 triplet arises from the coupling of the H nucleus (I = 1/2) to the H nucleus ( I = 1). H2&HDlowRes.tiff
H NMR spectrum of a solution of HD (labeled with red bars) and H2 (blue bar). The 1:1:1 triplet arises from the coupling of the H nucleus (I = 1/2) to the H nucleus ( I = 1).

Radio emission spectra

HD and H2 have very similar emission spectra, but the emission frequencies differ. [6]

The frequency of the astronomically important J = 1-0 rotational transition of HD at 2.7 THz has been measured with tunable FIR radiation with an accuracy of 150 kHz. [7]


Related Research Articles

<span class="mw-page-title-main">Astrochemistry</span> Study of molecules in the Universe and their reactions

Astrochemistry is the study of the abundance and reactions of molecules in the universe, and their interaction with radiation. The discipline is an overlap of astronomy and chemistry. The word "astrochemistry" may be applied to both the Solar System and the interstellar medium. The study of the abundance of elements and isotope ratios in Solar System objects, such as meteorites, is also called cosmochemistry, while the study of interstellar atoms and molecules and their interaction with radiation is sometimes called molecular astrophysics. The formation, atomic and chemical composition, evolution and fate of molecular gas clouds is of special interest, because it is from these clouds that solar systems form.

<span class="mw-page-title-main">Wolf–Rayet star</span> Heterogeneous class of stars with unusual spectra

Wolf–Rayet stars, often abbreviated as WR stars, are a rare heterogeneous set of stars with unusual spectra showing prominent broad emission lines of ionised helium and highly ionised nitrogen or carbon. The spectra indicate very high surface enhancement of heavy elements, depletion of hydrogen, and strong stellar winds. The surface temperatures of known Wolf–Rayet stars range from 20,000 K to around 210,000 K, hotter than almost all other kinds of stars. They were previously called W-type stars referring to their spectral classification.

<span class="mw-page-title-main">HD 209458 b</span> Gas giant exoplanet orbiting HD 209458

HD 209458 b is an exoplanet that orbits the solar analog HD 209458 in the constellation Pegasus, some 157 light-years from the Solar System. The radius of the planet's orbit is 0.047 AU, or one-eighth the radius of Mercury's orbit. This small radius results in a year that is 3.5 Earth-days long and an estimated surface temperature of about 1,000 °C. Its mass is 220 times that of Earth and its volume is some 2.5 times greater than that of Jupiter. The high mass and volume of HD 209458 b indicate that it is a gas giant.

<span class="mw-page-title-main">Centaurus A</span> Radio galaxy in the constellation Centaurus

Centaurus A is a galaxy in the constellation of Centaurus. It was discovered in 1826 by Scottish astronomer James Dunlop from his home in Parramatta, in New South Wales, Australia. There is considerable debate in the literature regarding the galaxy's fundamental properties such as its Hubble type and distance. NGC 5128 is one of the closest radio galaxies to Earth, so its active galactic nucleus has been extensively studied by professional astronomers. The galaxy is also the fifth-brightest in the sky, making it an ideal amateur astronomy target. It is only visible from the southern hemisphere and low northern latitudes.

<span class="mw-page-title-main">Messier 108</span> Galaxy in the constellation Ursa Major

Messier 108 is a barred spiral galaxy about 28 million light-years away from Earth in the northern constellation Ursa Major. It was discovered by Pierre Méchain in 1781 or 1782. From the Earth, this galaxy is seen almost edge-on.

<span class="mw-page-title-main">Cassiopeia A</span> Supernova remnant in the constellation Cassiopeia

Cassiopeia A (Cas A) is a supernova remnant (SNR) in the constellation Cassiopeia and the brightest extrasolar radio source in the sky at frequencies above 1 GHz. The supernova occurred approximately 11,000 light-years (3.4 kpc) away within the Milky Way; given the width of the Orion Arm, it lies in the next-nearest arm outwards, the Perseus Arm, about 30 degrees from the Galactic anticenter. The expanding cloud of material left over from the supernova now appears approximately 10 light-years (3 pc) across from Earth's perspective. It has been seen in wavelengths of visible light with amateur telescopes down to 234 mm (9.25 in) with filters.

<span class="mw-page-title-main">Lithium hydride</span> Chemical compound

Lithium hydride is an inorganic compound with the formula LiH. This alkali metal hydride is a colorless solid, although commercial samples are grey. Characteristic of a salt-like (ionic) hydride, it has a high melting point, and it is not soluble but reactive with all protic organic solvents. It is soluble and nonreactive with certain molten salts such as lithium fluoride, lithium borohydride, and sodium hydride. With a molar mass of 7.95 g/mol, it is the lightest ionic compound.

Borderline hydrides typically refer to hydrides formed of hydrogen and elements of the periodic table in group 11 and group 12 and indium (In) and thallium (Tl). These compounds have properties intermediate between covalent hydrides and saline hydrides. Hydrides are chemical compounds that contain a metal and hydrogen acting as a negative ion.

<span class="mw-page-title-main">Upsilon Sagittarii</span> Binary star system in the constellation Sagittarius

Upsilon Sagittarii is a spectroscopic binary star system in the constellation Sagittarius. Upsilon Sagittarii is the prototypical hydrogen-deficient binary (HdB), and one of only four such systems known. The unusual spectrum of hydrogen-deficient binaries has made stellar classification of Upsilon Sagittarii difficult.

<span class="mw-page-title-main">Trihydrogen cation</span> Polyatomic ion (H₃, charge +1)

The trihydrogen cation or protonated molecular hydrogen is a cation with formula H+
3
, consisting of three hydrogen nuclei (protons) sharing two electrons.

<span class="mw-page-title-main">Dihydrogen complex</span> Containing intact H2 as a ligand

Dihydrogen complexes are coordination complexes containing intact H2 as a ligand. They are a subset of sigma complexes. The prototypical complex is W(CO)3(PCy3)2(H2). This class of compounds represent intermediates in metal-catalyzed reactions involving hydrogen. Hundreds of dihydrogen complexes have been reported. Most examples are cationic transition metals complexes with octahedral geometry.

<span class="mw-page-title-main">Helium hydride ion</span> Chemical compound

The helium hydride ion, hydridohelium(1+) ion, or helonium is a cation (positively charged ion) with chemical formula HeH+. It consists of a helium atom bonded to a hydrogen atom, with one electron removed. It can also be viewed as protonated helium. It is the lightest heteronuclear ion, and is believed to be the first compound formed in the Universe after the Big Bang.

HD 98800, also catalogued as TV Crateris, is a quadruple star system in the constellation of Crater. Parallax measurements made by the Hipparcos spacecraft put it at a distance of about 150 light-years away. The system is located within the TW Hydrae association (TWA), and has received the designation TWA 4.

<span class="mw-page-title-main">HD 37974</span> Star in the constellation Dorado

HD 37974 a variable B[e] hypergiant in the Large Magellanic Cloud. It is surrounded by an unexpected dust disk.

<span class="mw-page-title-main">Dihydrogen cation</span> Molecular ion

The dihydrogen cation or hydrogen molecular ion is a cation with formula H+
2
. It consists of two hydrogen nuclei (protons) sharing a single electron. It is the simplest molecular ion.

Binary compounds of hydrogen are binary chemical compounds containing just hydrogen and one other chemical element. By convention all binary hydrogen compounds are called hydrides even when the hydrogen atom in it is not an anion. These hydrogen compounds can be grouped into several types.

<span class="mw-page-title-main">Iron hydride</span> Index of articles associated with the same name

An iron hydride is a chemical system which contains iron and hydrogen in some associated form.

<span class="mw-page-title-main">Chromium(I) hydride</span> Chemical compound

Chromium(I) hydride, systematically named chromium hydride, is an inorganic compound with the chemical formula (CrH)
n
. It occurs naturally in some kinds of stars where it has been detected by its spectrum. However, molecular chromium(I) hydride with the formula CrH has been isolated in solid gas matrices. The molecular hydride is very reactive. As such the compound is not well characterised, although many of its properties have been calculated via computational chemistry.

<span class="mw-page-title-main">Iron(I) hydride</span> Chemical compound

Iron(I) hydride, systematically named iron hydride and poly(hydridoiron) is a solid inorganic compound with the chemical formula (FeH)
n
(also written ([FeH])
n
or FeH). It is both thermodynamically and kinetically unstable toward decomposition at ambient temperature, and as such, little is known about its bulk properties.

<span class="mw-page-title-main">Magnesium monohydride</span> Chemical compound

Magnesium monohydride is a molecular gas with formula MgH that exists at high temperatures, such as the atmospheres of the Sun and stars. It was originally known as magnesium hydride, although that name is now more commonly used when referring to the similar chemical magnesium dihydride.

References

  1. Bautista, Maria T.; Cappellani, E. Paul; Drouin, Samantha D.; Morris, Robert H.; Schweitzer, Caroline T.; Sella, Andrea; Zubkowski, Jeffery (1991). "Preparation and Spectroscopic Properties of the η2-Dihydrogen Complexes [MH(η2-H2)PR2CH2CH2PR2)2]+ (M = Iron, Ruthenium; R = Ph, Et) and Trends in Properties Down the Iron Group Triad". Journal of the American Chemical Society. 113 (13): 4876–87. doi:10.1021/ja00013a025.
  2. Neufeld, David A.; Hollenbach, David J.; Kaufman, Michael J.; Snell, Ronald L.; Melnick, Gary J.; Bergin, Edwin A.; Sonnentrucker, Paule (2007). "SpitzerSpectral Line Mapping of Supernova Remnants. I. Basic Data and Principal Component Analysis". The Astrophysical Journal. 664 (2): 890–908. arXiv: 0704.2179 . Bibcode:2007ApJ...664..890N. doi:10.1086/518857. S2CID   15286019.
  3. Williams, David R. (May 22, 2023). "Jupiter Fact Sheet". NASA Space Science Data Coordinated Archive. Retrieved July 31, 2023.
  4. Williams, David R. (May 22, 2023). "Uranus Fact Sheet". NASA Space Science Data Coordinated Archive. Retrieved July 31, 2023.
  5. Williams, David R. (May 22, 2023). "Neptune Fact Sheet". NASA Space Science Data Coordinated Archive. Retrieved July 31, 2023.
  6. Quinn, W.; Baker, J.; Latourrette, J.; Ramsey, N. (1958). "Radio-Frequency Spectra of Hydrogen Deuteride in Strong Magnetic Fields". Phys. Rev. 112 (6): 1929. Bibcode:1958PhRv..112.1929Q. doi:10.1103/PhysRev.112.1929.
  7. Evenson, K. M.; Jennings, D. A.; Brown, J. M.; Zink, L. R.; Leopold, K. R. (1988). "Frequency measurement of the J = 1-0 rotational transition of HD". Astrophysical Journal. 330: L135. Bibcode:1988ApJ...330L.135E. doi:10.1086/185221.

Further reading