Silicon monosulfide

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Silicon monosulfide
Silicon monosulfide-3D-vdW.png
Names
IUPAC name
Silicon monosulfide
Identifiers
3D model (JSmol)
PubChem CID
  • InChI=1S/SSi/c1-2
    Key: DWFFKGPZNGKUPH-UHFFFAOYSA-N
  • [Si]=S
Properties
SiS
Molar mass 60.150 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Silicon monosulfide is a chemical compound of silicon and sulfur. The chemical formula is SiS. Molecular SiS has been detected at high temperature in the gas phase. [1] The gas phase molecule has an Si-S bondlength of 192.93 pm, this compares to the normal single bond length of 216 pm, [1] [2] and is shorter than the Si=S bond length of around 201 pm reported in an organosilanethione. [1] Historically a pale yellow-red amorphous solid compound has been reported. [3] The behavior of silicon can be contrasted with germanium which forms a stable solid monosulfide.

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Germanium compounds are chemical compounds formed by the element germanium (Ge). Germanium is insoluble in dilute acids and alkalis but dissolves slowly in hot concentrated sulfuric and nitric acids and reacts violently with molten alkalis to produce germanates ([GeO
3
]2−
). Germanium occurs mostly in the oxidation state +4 although many +2 compounds are known. Other oxidation states are rare: +3 is found in compounds such as Ge2Cl6, and +3 and +1 are found on the surface of oxides, or negative oxidation states in germanides, such as −4 in Mg
2
Ge
. Germanium cluster anions (Zintl ions) such as Ge42−, Ge94−, Ge92−, [(Ge9)2]6− have been prepared by the extraction from alloys containing alkali metals and germanium in liquid ammonia in the presence of ethylenediamine or a cryptand. The oxidation states of the element in these ions are not integers—similar to the ozonides O3.

References

  1. 1 2 3 Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN   978-0-08-037941-8.
  2. Lide, David R., ed. (2006). CRC Handbook of Chemistry and Physics (87th ed.). Boca Raton, FL: CRC Press. ISBN   0-8493-0487-3.
  3. E. G. Rochow, E. W. Abel ,1973, The Chemistry of Germanium Tin and Lead, Pergamon Press, ISBN   0-08-018854-0