Trithionic acid

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Trithionic acid
Trithionic acid.svg
Names
IUPAC names
  • Thiodisulfuric acid
  • 1,5-Dihydrido-2,2,4,4-tetraoxido-1,5-dioxy-2,3,4-trisulfy-[5]catena [1]
  • Trithionic acid
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
PubChem CID
  • InChI=1S/H2O6S3/c1-8(2,3)7-9(4,5)6/h(H,1,2,3)(H,4,5,6)
    Key: KRURGYOKPVLRHQ-UHFFFAOYSA-N
  • OS(=O)(=O)SS(=O)(=O)O
Properties
H 2 O 6 S 3 [1] [2] [3]
Molar mass 194.19 g·mol−1 [3]
Density 2.4±0.1 g/cm3
Melting point 324.41 °C (615.94 °F; 597.56 K)
Boiling point 739.35 °C (1,362.83 °F; 1,012.50 K)
1e+006 mg/L
log P -1.1 [2]
Vapor pressure 1.07E-016 Pa (8.05E-019 mm Hg)
Acidity (pKa)-6.94 [2]
Conjugate base Hydrogen trithionate
1.700
Pharmacology
Pharmacokinetics:
0.570 hours
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Trithionic acid is a polythionic acid with three sulfur atoms. It can be viewed as two bisulfite radicals bridged by a sulfur atom.

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An acid is a molecule or ion capable of either donating a proton (i.e. hydrogen ion, H+), known as a Brønsted–Lowry acid, or forming a covalent bond with an electron pair, known as a Lewis acid.

<span class="mw-page-title-main">Chalcogen</span> Group of chemical elements

The chalcogens are the chemical elements in group 16 of the periodic table. This group is also known as the oxygen family. Group 16 consists of the elements oxygen (O), sulfur (S), selenium (Se), tellurium (Te), and the radioactive elements polonium (Po) and livermorium (Lv). Often, oxygen is treated separately from the other chalcogens, sometimes even excluded from the scope of the term "chalcogen" altogether, due to its very different chemical behavior from sulfur, selenium, tellurium, and polonium. The word "chalcogen" is derived from a combination of the Greek word khalkos (χαλκός) principally meaning copper, and the Latinized Greek word genēs, meaning born or produced.

<span class="mw-page-title-main">Heterocyclic compound</span> Molecule with one or more rings composed of different elements

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<span class="mw-page-title-main">Sulfur</span> Chemical element with atomic number 16 (S)

Sulfur (also spelled sulphur in British English) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with the chemical formula S8. Elemental sulfur is a bright yellow, crystalline solid at room temperature.

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<span class="mw-page-title-main">Thiol</span> Any organic compound having a sulfanyl group (–SH)

In organic chemistry, a thiol, or thiol derivative, is any organosulfur compound of the form R−SH, where R represents an alkyl or other organic substituent. The −SH functional group itself is referred to as either a thiol group or a sulfhydryl group, or a sulfanyl group. Thiols are the sulfur analogue of alcohols, and the word is a blend of "thio-" with "alcohol".

<span class="mw-page-title-main">Sulfate</span> Oxyanion with a central atom of sulfur surrounded by 4 oxygen atoms

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In organic chemistry, nitration is a general class of chemical processes for the introduction of a nitro group into an organic compound. The term also is applied incorrectly to the different process of forming nitrate esters between alcohols and nitric acid. The difference between the resulting molecular structures of nitro compounds and nitrates is that the nitrogen atom in nitro compounds is directly bonded to a non-oxygen atom, whereas in nitrate esters, the nitrogen is bonded to an oxygen atom that in turn usually is bonded to a carbon atom.

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<span class="mw-page-title-main">Disulfuric acid</span> Chemical compound

Disulfuric acid (alternative spelling disulphuric acid) or pyrosulfuric acid (alternative spelling pyrosulphuric acid), also named oleum, is a sulfur oxoacid. It is a major constituent of fuming sulfuric acid, oleum, and this is how most chemists encounter it. As confirmed by X-ray crystallography, the molecule consists of a pair of SO2(OH) groups joined by an oxide.

An oxyacid, oxoacid, or ternary acid is an acid that contains oxygen. Specifically, it is a compound that contains hydrogen, oxygen, and at least one other element, with at least one hydrogen atom bonded to oxygen that can dissociate to produce the H+ cation and the anion of the acid.

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<span class="mw-page-title-main">Dithionate</span> Ion

The dithionate (or metabisulfate) anion, S
2
O2−
6
, is a sulfur oxoanion derived from dithionic acid, H2S2O6. Its chemical formula is sometimes written in a semistructural format, as [O3SSO3]2−. It is the first member of the polythionates.

Hydrogen chalcogenides are binary compounds of hydrogen with chalcogen atoms. Water, the first chemical compound in this series, contains one oxygen atom and two hydrogen atoms, and is the most common compound on the Earth's surface.

In chemistry, a fluoroanion or fluorometallate anion is a polyatomic anion that contains one or more fluorine atoms. The ions and salts form from them are also known as complex fluorides. They can occur in salts, or in solution, but seldom as pure acids. Fluoroanions often contain elements in higher oxidation states. They mostly can be considered as fluorometallates, which are a subclass of halometallates.

References

  1. 1 2 EBI Web Team. "trithionic acid (CHEBI:29210)". ChEBI. Retrieved 23 September 2018.
  2. 1 2 3 "Compound Report Card". EBI. Retrieved 23 September 2018.
  3. 1 2 "Trithionic acid". PubChem. Retrieved 23 September 2018.