Thiostannate

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Sulfidostannates, or thiostannates are chemical compounds containing anions composed of tin linked with sulfur. They can be considered as stannates with sulfur substituting for oxygen. Related compounds include the thiosilicates, and thiogermanates, and by varying the chalcogen: selenostannates, and tellurostannates. Oxothiostannates have oxygen in addition to sulfur. [1] Thiostannates can be classed as chalcogenidometalates, thiometallates, chalcogenidotetrelates, thiotetrelates, and chalcogenidostannates. Tin is almost always in the +4 oxidation state in thiostannates, although a couple of mixed sulfides in the +2 state are known,

Contents

Some thiostannate minerals are known. In nature the tin can be partly replaced by arsenic, germanium, antimony or indium. Many thiostannate minerals contain copper, silver or lead. In the field of mineralogy, these compound can be termed sulfostannates or sulphostannates.

Different cluster anions are known: [SnS4]4–, [SnS3]2–, [Sn2S5]2–, [Sn2S6]4–, [Sn2S7]6–, [Sn2S8]2–, [Sn3S7]2–, [Sn4S9]2–, [Sn5S12]4–, or [Sn4S10]4–. [2]

The number of sulfur atoms coordinated around the tin atom is most commonly four. However there are also complexes with five or six sulfur atoms surrounding the tin. The behaviour for selenium and tellurium differs as only five selenium or four tellurium atoms can bind to a tin atom. The smaller germanium atom can only accommodate four sulfur atoms. For lead it is hard for it to be in the +4 oxidation state. The SnSn polyhedrons can be standalone in strongly alkaline conditions, or at higher concentrations or less alkaline can condense together. Polyhedra shapes are tetrahedron for four, trigonal bipyramid for five, and octahedron for six sulfur atoms. The polyhedra can be connected at a vertex (corner), or at an edge. Where connected at an edge, four membered rings of -SnSSnS- with internal angles close to 90°. [3] [Sn2S7]6– is corner bridged. Tetrahedra linked by at the corner by a disulfur bridge are unknown. [3]

Sn10O4S208- is a supertetrahedron made from 1, 3 and 6 tin atoms connected by oxygen on the interior and sulfur on the surface. [3]

For anions with formula SnxSy the condensation ratio c is given by x⁄y. It can vary from 1⁄4 to just below 1/2. [3]

Synthesis

The first human production of a thiostannate heated tin oxide with sodium carbonate and sulfur: [4]

2SnO2 + 2Na2CO3 + 9S → 2Na2SnS3 + 2CO2 + 3SO2

Transition metal complexes may be prepared by crystallisation from the ligand solvent. [4]

Copper(II) is normally reduced by sulfide S2- in thiostannates to copper(I). [5]

Anions

formulanamecoordinationdimensionalitydescription
[SnS4]4−40tetrahedra
[Sn2S6]4−bis(μ-sulfido)-tetrathiolato-di-tin40edge shared
[Sn3S9]6−1,3,5,2,4,6-trithiatristanninane-2,2,4,4,6,6-hexakis(thiolate)406 membered ring
[Sn4S10]4-40tetrameric adamantane-like : tetrahedron of tetrahedra, 6 bridging sulfur, 4 terminal sulfur

Reactions

Some hydrates are unstable, where water reacts with the sulfide to make hydrogen sulfide gas.

List

formulasystemspace groupunit cell Åvolumedensitycomment
Li4SnS4orthorhombicPnmaa=13.812 b=7.962 c=6.370 [6]
[Li8(H2O)29][Sn10O4S20]·2H2OtriclinicP1a = 11.232, b = 13.097, c = 23.735, α = 102.73°, β = 90.43°, γ = 93.44°, Z = 23399oxothiostannate [7]
(NH4)4Sn2S6·3H2OorthorhombicP41212a =8.56294 b =8.56294 c= 22.7703 [8]
(NH4)6Sn3S9·1.3H2OmonoclinicC2a 16.9872 b 10.54777 c 21.0871 β 108.0389°3592.62.154colourless [9]
[(CH3)3NH]2Sn3S7 [3]
[(CH3)4N]2Sn3S7·H2O [3]
[(CH3)4N]4Sn4S10 [8]
[(CH3CH2)4N]2Sn3S7 [3]
[(CH3CH2CH2)4N]2Sn4S9 [3]
[(CH3CH2CH2CH2)4N]2Sn4S9 [3]
[(CH3CH2CH2)4N][(CH3)3NH]Sn4S9 [3]
(C12H25NH3)4Sn2S6·2H2O [3]
[dabcoH]2Sn3S7 [3]
(Et4N)2Sn(S4)3 [3]
(Et4N)2Sn(S4)2(S6) [3]
((CH3C(NH2)2)8Sn2S6SnS4monoclinicC 1 2/m 1a=23.7739 b=16.0647 c=11.8936 β=99.029 Z=44486.11.702colourless [9]
((CH3)2NH2)(NH4)SnS3 dimethylammonium ammoniumorthorhombicP212121a=5.9393 b=12.1816 c=12.4709 Z=4902.262.054colourless [9]
(DBNH)2Sn3S6 DBN=1,5-diazabicyclo[4.3.0]non-7-eneSn(II) and Sn(IV) [10]
(1AEP)2Sn3S7 1AEP = 1-(2-aminoethyl) piperidineorthorhombicP212121a=13.2299 b= 22.2673 c=9.0772 Z=42674.1pale yellow [11]
SnS2·enmonoclinicC2/ca 15.317 b 10.443 c 12.754, β 93.62° [12]
[enH]4[Sn2S6]·entriclinicP1a 9.8770 b 9.9340 c 15.4230, α 72.630° β 86.220° γ 81.380° [12]
Na2SnS3R3ma=3.834 c=19.876 Z=22533.43 [4] [13]
Na4SnS4tetragonalP421ca=7.837 c=6.9504272.64 [13]
Na4Sn2S6 [3]
Na4Sn2S6·14H2OtriclinicP1a=10.114 b=7.027 c=9.801 α=108.30 β=92.18 γ=91.11 Z=16631.95 [2]
Na4SnS4·14H2OmonoclinicC2/ca=8.622 b=23.534 c=11.347 β=110.53 Z=421561.82 [13]
Na4Sn3S8 [3]
Na5[SnS4]Cl·13H2OmonoclinicP21/ma=8.4335 b=11.4958 c=11.5609 β=91.066 Z=21120.631.872 [2]
Na4Sn2S6·5H2O [3]
Na6Sn2S7C2/ca=9.395 b=10.719 c=15.671 β=109.97 Z=414832.69 [13]
Mg2SnS4orthorhombicPnmaa=12.93 b=7.52 c=6.16 Z=45993.28 [13]
Na2MgSnS4R3ma 3.7496 b 3.7496 c 19.9130 [14]
(Ph4P)2Sn(S4)3 [3]
K2SnS3·2H2O [3]
K2SnS3·2H2OorthorhombicPnmaa=6.429 b=15.621 c=10.569 Z=410612.06 [13]
K2Sn2S5 [3]
K2Sn3S7·H2O [3]
[K4(H2O)4][SnS4] [15]
Ca2SnS4orthorhombicPnmaa=13.74 b=8.23 c=6.44 Z=47282.99 [13]
[H2tepa][VIII(tepa)(μ-Sn2Q6)]2orthorhombicAbm2a =7.7486 b =40.410 c =16.745 [16]
Mn2SnS4tetragonalI41/aa=7.408 c=10.41 Z=85714.15 [13]
[Mn(en)3]2[Sn2S6]monoclinicC2/ca=15.138 b=10.6533 c=23.586 β=118.42 Z=43345.21.787colourless [5] [17]
[Mn(en)3]2Sn2S6·2H2OmonoclinicP21/ca=10.129, b=15.746, c=11.524, β=102.36° Z=21795.51.732 [18]
[Mn(en)2]2(μ-en)[Sn2S6]triclinica=9.0017 b=9.7735 c=10.8421 α=60.38° β=67.23° γ=70.25°752.38 [16]
[Mn(dien)2]2Sn2S6monoclinicP21/ca=12.48 12, b= 9.3760, c=17.7617, β=121.752°, Z=2,1767.51.789 [18]
[Mn(tren)]2Sn2S6triclinicP1a 7.653 b 8.088 c 12.200, α 97.27° β 104.06° γ 108.80° Z=1676.02.044yellow [5] [19]
[Mn(tren)(H2O)][Mn(baen)]3Mn4Sn6S20∙9H2OorthorhombicP213a =21.404 b =21.404 c= 21.404super tetrahedron [20]
{Mn(tepa)}2(μ-Sn2S6)tetragonalI41/aa=25.977 c=10.041 Z=867751.800yellow [19]
{[Mn(trien)]2[SnS4]} [5]
{[Mn(C6H18N4)]2SnS4}·4H2OmonoclinicP21/ca 10.8446 b 20.974 c 13.2746 β 113.487° [21]
{[Mn(phen)2]2(μ2-Sn2S6)}monoclinicP21/na =10.8230 b=9.8940 c=24.811 β=91.356° [22]
{[Mn(phen)2]2(μ2-Sn2S6)}·phentriclinicP1a=10.0642 b=10.6249 c=13.693, α=71.700° β=81.458° γ=84.346° [22]
{[Mn(phen)2]2[Sn2S6]}·phen·H2O phen = 1,10-phenanthrolinetriclinicP1a=11.3203 b=12.1436 c=12.7586, α=113.200° β=90.908° γ=110.974° [5] [22]
[Mn(phen)]2(SnS4)·H2OmonoclinicC2/ma=16.146 b=19.262 c=9.938 β=124.970 Z=42532.61.928red chain [23]
{[Mn(phen)2]2[μ-η2-η2-SnS4]2[Mn(phen)]2}·H2OtriclinicP1a=10.8703 b=12.5183 c=14.9644, α=103.381° β=108.390° γ=101.636° [22]
{[Mn(2,2′-bipy)2]2[Sn2S6]} [24]
(1,4-dabH)2MnSnS4 1,4-dab = 1,4-diaminobutaneorthorhombicFdd2a = 22.812, b = 24.789, c = 6.4153, Z = 83627.8 [25]
Li4MnSn2Se7monoclinicCca=18.126 b=7.2209 c=10.740 β=93.43 Z=41403.24.132orange [26]
Fe2SnS4tetragonalI41/aa=7.308 c=10.338 Z=45524.32 [13]
{[Fe(tepa)]2[Sn2S6]}tetragonalI41/a [5] [27]
{[Fe(1,2-dach)2][Sn2S6]}·2(1,2-dachH) [5]
{[Fe(phen)2]2[Sn2S6]}·phen·H2O [5]
[Co(en)3]2[Sn2S6]orthorhombicPbcaa=15.640 b=11.564 c=18.742 Z=42289.71.779yellow [5] [17]
[Co(dien)2]2[Sn2S6] [5]
[Co2(cyclam)2Sn2S6]·2H2O [28]
[Co(tren)]2Sn2S6monoclinicC2/ca=12.228 b=9.7528 c=23.285 β=102.902706.8 [5] [16]
{[Co(cyclam)]2[Sn2S6]}n·2nH2O cyclam = 1,4,8,11-tetraazacyclotetradecane [5]
{[Co(tepa)]2[Sn2S6]} tepa=tetraethylenepentaminetetragonalI41/aa=25.742 c=9.8986558 [5] [27] [16]
{[Co(phen)2]2[Sn2S6]}·phen·H2O [5]
[Co(2-(aminomethyl)pyridine)3]2Sn2S6·10H2O (2amp)monoclinicP21/ca=10.1443 b=14.6124 c=18.8842 β=90.601° Z=22799.11.633yellow [29]
[Co(trans-1,2-diaminocyclohexane)3]2Sn2S6·8H2O (dach)monoclinicP21/na=12.6521 b=11.7187 c=20.4386 β=91.262° Z=23029.61.509red [29]
Ni6SnS2 Butianite tetragonalI4/mmma = 3.650, c = 18.141 Z=2241.77.62opaque [30]
[Ni(en)3]2[Sn2S6] [5]
[Ni(dap)3]2[Sn2S6]·2H2O dap=1,2-diaminopropanetriclinicP1a=9.9046 b=10.527 c=11.319 α =72.13° β =85.19° γ =63.63°1004.5 [5] [16]
[Ni(1,2-dach)3]2[Sn2S6]·4H2O 1,2-dach = 1,2-diaminocyclohexane [5]
[Ni(dien)2]2[Sn2S6] [5]
{[Ni(cyclen)]6[Sn6S12O2(OH)6]}·2(ClO4)·19H2O

cyclen = 1,4,7,10-tetraazacyclododecane

 [31]
[Ni(cyclen)(H2O)2]4[Sn10S20O4]·~13H2O [31]
{[Ni(cyclen)]6[Sn6S12O2(OH)6]}·2(ClO4)·19H2OmonoclinicC2/ca=25.7223 b=15.6522 c=29.070 β=105.879 Z=4112571.863oxothiostannate [32]
[Ni(2amp)3]2[Sn2S6]·9.5H2O 2amp = 2-(aminomethyl)pyridinemonoclinicP21/na=18.7021 b=14.6141 c=20.2591 β=97.696 Z=45487.21.655purple [4]
[Ni(aepa)2]2[Sn2S6] aepa=N-2-aminoethyl-1,3-propandiamine [5]
[Ni(tren)]2Sn2S6monoclinicC2/ca=23.371 b=8.231 c=14.274 β =107.230 Z=42622.62.127 [5] [33]
[Ni(tren)2]2[Sn2S6]·8H2OorthorhombicP42/na=26.1885 b=26.1885 c=11.1122 [5] [34]
[Ni(tren)(2amp)]2[Sn2S6]triclinicP1a =10.2878 b =11.1100 c =11.4206, α =84.740° β =84.395° γ =79.093° [5] [34]
[Ni(tren)(2amp)]2[Sn2S6]·10H2OmonoclinicP21/na =12.1933 b =13.4025 c =14.8920 β= 103.090° [35]
[Ni(tren)(en)]2[Sn2S6]·2H2OmonoclinicP21/na 12.7041 b 9.8000 c 15.3989, β 108.843° [35]
[Ni(tren)(en)]2[Sn2S6]·6H2OmonoclinicP21/na 12.5580 b 9.7089 c 16.0359, β 91.827° [35]
[Ni(tren)(1,2-dach)]2[Sn2S6]·3H2OtriclinicP1a 9.8121 b 10.0080 c 12.422, α 86.38° β 79.65° γ 65.72° [35]
[Ni(tren)(1,2-dach)]2[Sn2S6]·4H2OmonoclinicP21/na 10.7119 b 19.0797 c 11.1005, β 104.803° [35]
{[Ni(cyclam)]2[Sn2S6]}·2H2O [5]
{[Ni(tepa)]2[Sn2S6]}monoclinicP21/n [5] [27]
{[Ni(phen)2]2[Sn2S6]}·2,2′-bipymonoclinicP21/na=10.5715 b=9.9086 c=24.9960 β=92.800 Z=22615.171.809deep red [5] [36]
{[Ni(phen)2]2Sn2S6}·4,4′-bipy·½H2O 4,4′-bipy = 4,4′-bipyridinemonoclinicC2/ca=18.3431 b=19.4475 c=15.0835 β=95.556 Z=45355.41.789dark red-brown [36]
{[Ni(phen)2]2[Sn2S6]}·phen·H2O [24]
[Ni(L1)][Ni(L1)Sn2S6]n·2H2O L1 = 1,8-dimethyl-1,3,6,8,10,13-hexaazacyclotetradecanemonoclinicP21/c [37]
[Ni(L2)]2[Sn2S6]·4H2O L2 = 1,8-diethyl-1,3,6,8,10,13-hexaazacyclotetradecanetriclinicP1 [37]
[Ni(tren)(ma)(H2O)]2[Sn2S6]·4H2O ma = methylaminemonoclinicP21/na=11.1715 b=10.5384 c=15.8594 Z=21827.451.835 [33]
[Ni(tren)(1,2-dap)]2[Sn2S6]·2H2OmonoclinicP21/na=12.9264 b=10.1627 c=15.6585 Z=21889.81.799 [33]
[Ni(tren)(1,2-dap)]2[Sn2S6]·4H2OmonoclinicC2/ca =14.3925 b=15.1550 c=18.9307, β=99.108° [35]
[Ni(2amp)3]2[Sn2S6]·9.5H2O 2amp = 2-(aminomethyl)pyridinemonoclinicP21/na=18.7021 b=14.6141 c=20.2591 Z=45487.231.655purple [4]
Cu2SnS3 Mohite monoclinica=23.10 b=6.25 c=6.25 β=101.0°4.69greenish grey [13] [38]
Cu3SnS4 Kuramite tetragonalI42ma = 5.445, c = 10.75, Z = 2318.724.56 [39]
Cu4SnS4orthorhombicPnmaa=13.70 b=7.750 c=6.454 Z=46854.96 [13]
Cu4SnS6 Erazoite rhombohedralR3ma = 3.739, c = 32.941, Z = 24.53black [40]
Cu4Sn7S16monoclinica=12.75 b=7.34 c=12.71 β=109.5 Z=211214.74 [13]
(DBUH)CuSnS3 DBU = 1,8-diazabicyclo[5.4.0]undec-7-enemonoclinicP21/na=9.254 b=8.6190 c=18.135, β=92.80° [41]
(1,4-dabH2)Cu2SnS4 1,4-dab = 1,4-diaminobutanetetragonalP42/na=14.539 c=11.478 [42]
(enH)6Cu40Sn15S60 en=ethylenediaminecubicPn3na=25.260 Z=4161192.727black [43]
(enH)3Cu7Sn4S12trigonalR3ca=13.532 c=28.933 Z=645883.23red [43]
[H2en]2[Cu8Sn3S12] [5]
(trenH3)Cu7Sn4S12tren = tris(2-aminoethyl)amine)trigonalR3ca=13.1059 c=29.347 Z=64365.43.317 [43]
[dienH2][Cu2Sn2S6] [5]
[DBUH][CuSnS3] DBU = 1,8-diazabicyclo[5.4.0]undec-7-ene [5]
[1,4-dabH2][Cu2SnS4] [5]
{[Cu(cyclam)]2[Sn2S6]}·2H2O cyclam=1,4,8,11-tetraazacyclotetradecanetriclinicP1a=9.0580 b=9.9419 c=10.2352, α=97.068° β=94.314° γ=101.514° [5]
(DBNH)2Cu6Sn2S8 DBN=1,5-diazabicyclo[4.3.0]non-7-ene [10]
[Co(2-(aminomethyl)pyridine)3]2 Sn2S6·10H2OmonoclinicP21/ca=10.1443 b=14.6124 c=18.8842 β=90.601° Z=22799.11.633yellow; unstable [44]
[Co(trans-1,2-diaminocyclohexane)3]2Sn2S6·8H2OmonoclinicP21/na=12.6521 b=11.7187 c=20.4386 β=91.262° Z=23029.61.509red [44]
Na4Cu32Sn12S48·4H2OcubicFm3ca = 17.921 z = 13black; absorption edge 2.0 eV [45]
CuAlSnS4cubica=10.28 Z=810744.17 [13]
K11Cu32Sn12S48·4H2OcubicFm3ca = 18.0559 z = 14.75black; absorption edge 1.9 eV [45]
Cu2MnSnS4tetragonala=5.49 c=10.72 Z=23234.41 [13]
Cu2FeSnS4 Stannite Ferrokësterite tetragonalI42ma = 5.4432, c = 10.7299 Z=2317.91grey [46]
Cu2FeSn3S8tetragonalI41/aa=7.29 c=10.31 Z=25484.82 [13]
Cu6Fe2SnS8 Mawsonite TetragonalP4m2a = 7.603, c = 5.358 Z=13094.65brownish orange [47]
Cu6FeSn2S8 Chatkalite TetragonalP4m2a = 7.61, c = 5.373 Z=1311.15.00 [48]
Cu2CoSnS4TetragonalI42ma=5.402 c=10.805 Z=23154.56 [13]
Cu2NiSnS4a=5.425 Z=11604.49 [13]
Cu13VSn3S16 Nekrasovite isometrica=10.731,235brown [49]
[Zn(en)3]2[Sn2S6]orthorhombicPbcaa=15.452 b=11.524 c=18.614 Z=43315.31.845colourless [5] [17]
{Zn(tren)}2(μ-Sn2S6)monoclinicC2/ca 12.214 b 9.726 c 23.209 β 102.732°2689.32.107light yellow [19] [50]
Cu2ZnSnS4 Kësterite tetragonalI4a = 5.427, c = 10.871 Z=2320.184.55greenish black [51]
Cu6+Cu22+(Fe2+,Zn)3Sn2S12 Stannoidite orthorhombica = 10.76, b = 5.4, c = 16.09934.94.68brass [52]
Cu3(V,Ge,Sn)S4 Ge-Sn-Sulvanite361 [53]
SnGeS3 Stangersite monoclinicP21/ba = 7.270, b = 10.197, c = 6.846 β = 105.34° Z=44893.98orange
Rb4SnS4 [3]
Rb4Sn2S6 [3]
Rb2Sn3S7·2H2O [3]
Rb2Cu2SnS4orthorhombicIbama=5.528 b=11.418 c=13.700 Z=48654.185band gap 2.08 eV [54]
Rb2Cu2Sn2S6monoclinicC2/ca=11.026 b=11.019 c=20.299 β=97.79 Z=824443.956band gap 1.44 eV [54]
Rb2ZnSn3S8 [55]
[Rb4(H2O)4][SnS4] [15]
Sr3MnSn2S8cubicI43da = 14.2287 Z = 82880.73.743dark green [56]
Cu2SrSnS4trigonalP31a = 6.29, c = 15.57 Z=35344.31 [57] [13]
Sr6Cu4Sn4S16cubicI43da=13.98227344.295yellow [58]
Sr6Cu2FeSn4S16cubicI43da=14.1349band gap 1.53 eV [59]
SrSnS3orthorhombicPnmaa=8.264 b=3.867 c=14.116 Z=44514.45 [13]
[Y2(dien)4(μ-OH)2]Sn2S6monoclinicP21/na=11.854 b=11.449 c=13.803 β=97.978 Z=218551.888light yellow [60]
α-Ag8SnS6cubica=21.439842 [13]
β-Ag8SnS6cubica=10.851277 [13]
Ag8SnS6 Canfieldite orthorhombica = 15.298, b = 7.548, c = 10.699 Z=41,235.46.311metallic [61]
Na3AgSnS4monoclinicP21/ca 8.109 b 6.483 c 15.941, α 90° β 103.713double chain [62]
AgCrSnS4cubica=10.74 Z=812394.92 [13]
Ag2MnSnS4 – Agmantinite orthorhombica = 6.632, b = 6.922, c = 8.156 Z=24.574orange [63]
Ag2ZnSnS4 Pirquitasite tetragonalI4a = 5.78, c = 10.82361black [64]
Ag2(Fe2+,Zn)SnS4 Hocartite tetragonalI42ma = 5.74, c = 10.96 Z=23614.77brownish grey [65]
Ag1+(Fe2+0.5Sn4+1.5)S4 Toyohaite tetragonalgrey [66]
[enH][Cu2AgSnS4]orthorhombicPnmaa=19.7256 b=7.8544 c= 6.5083 Z=41008.33.577red [67]
Ag2SrSnS4orthorhombica=7.127 b=8.117 c=6.854 Z=23975.02 [13]
Sr6Ag4Sn4S16cubicI43da=14.2219 Z=42876.64.491yellow [58]
Sr6Ag2FeSn4S16cubicI43da=14.2766band gap 1.87 eV [59]
[1,4-dabH2][Ag2SnS4] 1,4-dab = 1,4-diaminobutanetetragonalP42/na = 14.7847, c = 11.9087, Z = 82603.1 [5] [68]
[H2en][Ag2SnS4] [5]
[CH3NH3]2Ag4SnIV2SnIIS8orthorhombicPnmaa =19.378 b =7.390 c =13.683 Z=419593.756Orange Sn(II) [69]
[CH3NH3]6Ag12Sn6S21monoclinicP21/ca =18.8646 b =19.9115 c =14.3125 β 100.117° [70]
[(Me)2NH2]3[Ag5Sn4Se12]tetragonalP421ma=13.998 c=8.685 Z=21701.94.403dark red [71]
[enH][Cu2AgSnS4] [5]
Cu2CdSnS4I42ma=5.402 c=10.86 Z=23384.77 [13]
Ag2CdSnS4Cmc21a=4.111 b=7.038 c=6.685 Z=11934.95 [13]
Cu2(Cd,Zn,Fe)SnS4 Černýite tetragonalI42ma = 5.48, c = 10.828 Z=43264.76metallic [72]
CuInSnS4a=10.50 Z=811584.91 [13]
AgInSnS4a=10.16 Z=810484.59 [13]
(Cu,Fe,Zn,Ag)3(Sn,In)S4 Petrukite orthorhombica = 7.66, b = 6.43, c = 6.26308brown [73]
(Cu,Zn,Fe)3(In,Sn)S4 Sakuraiite isometrica = 5.46 Z=1162greenish grey [74]
Sn2S3orthorhombicPnmaa=8.864 b=3.7471 c=14.020 Z=44664.76 [13]
Cs4SnS40d [3]
Cs2Sn3S7·0.5S82d [3]
Cs4Sn5S12·2H2O2d [3]
[Cs4(H2O)3][SnS4] [15]
Cs2Sn(S4)2(S6) [3]
Cs8Sn10O4S20·13H2O [3]
[Cs10(H2O)18][Mn4(μ4-S)(SnS4)4] [15]
Cs2ZnSn3S8monoclinicP21/na 7.5366 b 17.6947 c 12.4976, β=94.830° Z=41660.73.775layered, band gap 3. eV [55]
[Ba2(H2O)11][SnS4] [15]
Li2Ba6MnSn4S16cubicI43da=14.6080 Z=43117.34.007light yellow [42]
Ag2Ba6MnSn4S16cubicI43da=14.7064 Z=43180.74.349yellow [42]
Ag2BaSnS4orthorhombicI222a =7.127 b =8.117 c =6.854 Z=2black [75]
Ba3Ag2Sn2S8 [76]
BaSnS2Sn(II) [77]
BaSn2S3Sn(II) [77]
BaSnS3orthorhombicPnmaa=8.527 b=3.933 c=14.515 Z=44874.8 [13]
BaSnS3monoclinicC2/cCca=24.49 b=6.354 c=23.09 β=90.15 Z=2835934.55 [13]
α-Ba2SnS4monoclinicP21/ca=8.481 b=8.526 c=12.280 β=112.97 Z=48184.24 [13]
β-Ba2SnS4orthorhombicPnmaa=17.823 b=7.359 c=12.61316544.18 [13]
Ba3Sn2S7monoclinicP21/ca=11.073 b=6.771 c=18.703 β=100.77 Z=413784.21 [13]
K2BaSnS4R3ca 25.419 c 7.497band gap 3.09 eV; SHG 0.5×AgGaS2 [78]
Ba6Cu2FeSn4S16cubicI43da=14.5260band gap 1.2 eV [59]
Ba6Cu2NiSn4S16cubicI43da=14.511band gap 0.82 eV [59]
Ba6Li2ZnSn4S16cubicI43da=14.5924 [79]
Ba6Ag2ZnSn4S16cubicI43da=14.6839 [79]
BaCdSnS4orthorhombicFdd2a=21.57 b=21.76 c=13.110 Z=3261524.290yellow [80]
Ba3CdSn2S8cubicI43da=14.723 [81]
Ba6CdAg2Sn4S16cubicI43da=14.725 [81]
La2SnS5orthorhombicPbama=11.22 b=7.915 c=3.97 Z=23525.26 [13]
[La(dien)3]2[Sn2S6]Cl2band gap 3.25 eV [82]
La(peha)(μ–SnS4H) peha=pentaethylenehexaminetriclinicP1a 8.609 b 9.327 c 14.649, α 79.2° β 85.5° γ 63.74° [83]
BaCeSn2S6orthorhombicPmc21a 4.0665 b 19.859 c 11.873 [84]
BaPrSn2S6orthorhombicPmc21a 4.0478 b 19.8914 c 11.9303 [84]
BaNdSn2S6orthorhombicPmc21a 4.0098 b 19.761 c 11.841 [84]
[Nd2(en)6(μ2-OH)2]Sn2S6monoclinicP21/na =10.176, b =11.387, c=15.018, β =97.869° [85]
Nd(peha)(μ–SnS4H)triclinicP1a 8.621 b 9.372 c 14.656, α 78.28° β 84.33° γ 63.32° [83]
{Nd(tepa)(μ–OH)}2(μ–Sn2S6)]·H2O tepa=tetraethylenepentaminemonoclinicC2/ca=21.537 b=12.863 c=17.697 β=124.308° [83]
[Nd(dien)3]2[(Sn2S6)Cl2] dien = diethylenetriaminemonoclinicP21/na = 11.672, b = 15.119, c = 14.157, β = 96.213°, Z = 42483.6 [86]
[Nd(dien)3]2[(Sn2S6)(SH)2]monoclinicP21/na = 11.719, b = 15.217, c = 14.221, β = 95.775°, Z = 42523.1 [86]
(tetaH)2[Eu2(teta)2(tren)2(μ-Sn2S6)]Sn2S6triclinicP1a=9.886 b=10.371 c=17.442 α=89.78 β=88.00 γ=85.14 Z=11780.81.898light yellow [60]
[Eu2(tepa)2(μ-OH)2(μ-Sn2S6)](tepa)0.5·H2O tepa = tetraethylene-pentaminemonoclinicC2/ca=19.803 b=14.998 c=17.800 β=126.57 Z=442461.970colourless [60]
[{Eu(en)3}2(μ-OH)2]Sn2S6monoclinicP21/na = 10.116, b = 11.379, c = 14.949, β = 98.209°, Z=21703.1 [87]
[{Eu(en)3}2(μ-OH)2]Sn2Se6monoclinicP21/na = 10.136, b = 11.771, c = 15.423, β = 99.322°, Z = 21815.8 [87]
[Eu(dien)3]2[(Sn2S6)(SH)2]monoclinicP21/na = 11.656, b = 15.168, c = 14.173, β = 95.682°, Z = 22493.4 [87]
(tetaH)2[Sm2(teta)2(tren)2(μ-Sn2S6)]Sn2S6triclinicP1a=9.920 b=10.382 c=17.520 α=89.91 β=88.07 γ=85.23 Z=11797.11.877light yellow [60]
{Sm(tepa)(μ–OH)}2(μ–Sn2S6)]·H2OmonoclinicC2/ca 21.487 b 12.8199 c 17.716 β 124.675° [83]
[Sm2(en)6(μ2-OH)2]Sn2S6monoclinicP21/na 10.129 b 11.377 c 14.962, β 98.128° [88]
[Sm(dien)3]2[(Sn2S6)Cl2]monoclinicP21/na 11.631 b 15.091 c 14.1420 β 96.202° [88]
[Sm(dien)3]2[(Sn2S6)(SH)2]monoclinicP21/na 11.698 b 15.212 c 14.219, β 95.654° [88]
[Sm(trien)(tren)(Cl)]2Sn2S6 · entriclinicP1a 10.320 b 10.491 c 13.791, α 100.524° β 91.930° γ 119.083° [88]
{Gd(tepa)(μ–OH)}2(μ–Sn2S6)]·H2OmonoclinicC2/ca 21.455 b 12.804 c 17.735 β 124.81° [83]
[Gd2(en)6(μ2-OH)2]Sn2S6monoclinicP21/na =10.1053 b =11.357 c =14.924, β = 98.346° [85]
[Gd(dien)3]2[(Sn2S6)Cl2] dien = diethylenetriaminemonoclinicP21/na =11.662, b =15.168. c 14.185, β =95.696° [85]
{Dy(tepa)(μ–OH)}2(μ–Sn2S6)]·H2OmonoclinicC2/ca 21.363 b 12.717 c 17.654 β 124.915° [83]
[Hen]2[La(en)4(CuSn3S9)]⋅0.5 en [89]
[Hen]2[Ce(en)4(CuSn3S9)]⋅0.5 en [89]
[Hen]4[Nd(en)4]2[Cu6Sn6S20]⋅3 en [89]
[enH]4[Sm(en)4]2[Cu6Sn6S20]·3enmonoclinicC2/ma 14.257 b 24.242 c 13.119 β 92.223° [90]
[Hen]4[Gd(en)4]2[Cu6Sn6S20]⋅3 en [89]
[enH]4[Ho(en)4]2[Cu6Sn6S20]·3enmonoclinicC2/ma 14.3859 b 24.361 c 13.175, β 93.526° [90]
EuCu2SnS4orthorhombicAma2a=10.4793, b=10.3610, c=6.4015, Z=4 [91] [92]
[Hen]4[Er(en)4]2[Cu6Sn6S20]⋅3 en [89]
[Hen]4[Er(en)4]2[Ag6Sn6S20]·3enmonoclinicC2/ma 14.557 b 24.397 c 13.412 β 94.42° [93]
[Hen]4[Tm(en)4]2[Ag6Sn6S20]·3enmonoclinicC2/ma 14.517 b 24.380 c 13.422 β 94.46° [93]
[Hen]4[Yb(en)4]2[Ag6Sn6S20]·3enmonoclinicC2/ma 14.536 b 24.397 c 13.397, β 94.63° [93]
Cu6SnWS8 Kiddcreekite isometricF43ma = 10.8178 Z=41265.94.934grey [94]
PtSnS Bowlesite orthorhombicPca21a = 6.12 Å, b = 6.12 Å, c = 6.10 Å Z=4228.4710.06metallic [95]
(Pd,Pt)5(Cu,Fe)4SnTe2S2 Oulankaite tetragonala = 9.044, c = 4.937 Z=2403.810.27metallic
K2Au2SnS4triclinicP1a=8.212 b=11.019 c=7.314 α=97.82° β=111.72° γ=72.00° Z=2483.24.941band gap 2.75 eV [96] [54]
K2Au2Sn2S6tetragonalP4/mmca=7.968 c=19.200 Z=412194.914band gap 2.30 eV [96] [54]
Cs2Au2SnS4orthorhombicFddda = 6.143 b = 14.296 c = 24.578 Z = 42158.4 [96]
Ba[Au2SnS4]orthorhombicC2221a=6.6387 b=11.0605 c=10.9676 Z=1805.326.418red; blue-green luminescent [96]
K2Hg3Sn2S8 [97]
Cu2HgSnS4 Velikite tetrahedralI42ma = 5.55, c = 10.913365.450dark grey [98]
SrHgSnSe4 [99]
BaHgSnSe4orthorhombicFdd2a 22.441 b 22.760 c 13.579 [99]
EuHgSnS4Ama2a=10.3730 b=10.4380 c=6.5680SHG 1.77×AgGaS2 [100]
Tl4SnS40d
Tl2SnS31d
Tl2Sn2S53d
Tl4Sn5S123d
PbSnS2 Teallite orthorhombicPnmaa = 4.26, b = 11.41, c = 4.09198.86.36metallic
PbSnS3 Suredaite orthorhombicPnmaa=8.738 b=3.792 c=14.052 Z=44666.01metallic [13]
(Pb,Sn)12.5Sn5FeAs3S28 Coiraitemonoclinica = 5.84, b = 5.86, c = 17.32 β = 94.14° Z=45915.92dark grey [101]
Fe2+(Pb,Sn2+)6Sn4+2Sb2S14 Franckeite triclinicP1a = 46.9, b = 5.82, c = 17.3 α = 90°, β = 94.66°, γ = 90° Z=847015.90black [102]
Pb25.7Sn8.3Mn3.4Sb6.4S56.2 Ramosite monoclinica = 5.82, b = 5.92, c = 17.65 β = 99.1°600 [103]
Pb3Sn4FeSb2S14 Cylindrite triclinicP15.46black [104]
Pb6Sn3FeSb3S16 Potosíite triclinicgrey
(Pb,Ag)4Sn4FeSb2S15 Incaite monoclinic [105]
Pb2Fe2Sn2Sb2S11 Plumbostannite dark grey [106]
Ba5Pb2Sn3S13orthorhombicPnma [107]
Pb2SnInBiS7 Abramovite triclinicP1a = 23.4, b = 5.77, c = 5.83 α = 89.1°, β = 89.9°, γ = 91.5°786.79metallic [108]
Pb8Sn7Cu3(Bi,Sb)3S28 Lévyclaudite triclinicP15.71grey [109]

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The inorganic imides are compounds containing an ion composed of nitrogen bonded to hydrogen with formula HN2−. Organic imides have the NH group, and two single or one double covalent bond to other atoms. The imides are related to the inorganic amides (H2N−), the nitrides (N3−) and the nitridohydrides (N3−•H−).

The sulfate fluorides are double salts that contain both sulfate and fluoride anions. They are in the class of mixed anion compounds. Some of these minerals are deposited in fumaroles.

The telluride iodides are chemical compounds that contain both telluride ions (Te2−) and iodide ions (I−). They are in the class of mixed anion compounds or chalcogenide halides.

Nitride fluorides containing nitride and fluoride ions with the formula NF4-. They can be electronically equivalent to a pair of oxide ions O24-. Nitride fluorides were discovered in 1996 by Lavalle et al. They heated diammonium technetium hexafluoride to 300 °C to yield TcNF. Another preparation is to heat a fluoride compound with a nitride compound in a solid state reaction. The fluorimido ion is F-N2- and is found in a rhenium compound.

The borosulfates are heteropoly anion compounds which have sulfate groups attached to boron atoms. Other possible terms are sulfatoborates or boron-sulfur oxides. The ratio of sulfate to borate reflects the degree of condensation. With [B(SO4)4]5- there is no condensation, each ion stands alone. In [B(SO4)3]3- the anions are linked into a chain, a chain of loops, or as [B2(SO4)6]6− in a cycle. Finally in [B(SO4)2]− the sulfate and borate tetrahedra are all linked into a two or three-dimensional network. These arrangements of oxygen around boron and sulfur can have forms resembling silicates. The first borosulfate to be discovered was K5[B(SO4)4] in 2012. Over 75 unique compounds are known.

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<span class="mw-page-title-main">Transition metal ether complex</span>

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  107. ↑ Abudurusuli, Ailijiang; Ding, Hanqin; Wu, Kui (November 2017). "Synthesis and characterization of two lead-containing metal chalcogenides: Ba5Pb2Sn3S13 and Ba6PbSn3Se13". Journal of Solid State Chemistry. 255: 133–138. Bibcode:2017JSSCh.255..133A. doi:10.1016/j.jssc.2017.08.019.
  108. ↑ "Abramovite". www.mindat.org. Retrieved 2021-07-15.
  109. ↑ "Lévyclaudite". www.mindat.org. Retrieved 2021-07-15.
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