Stannoidite

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Stannoidite
Stannoidite.jpg
Silvery stannoidite crystals from the Akenobe Mine, Yabu City, Honshu Island, Japan, associated with chalcopyrite
General
Category Sulfide mineral
Formula
(repeating unit)
Cu6+Cu22+(Fe2+,Zn)3Sn2S12
IMA symbol Sta [1]
Strunz classification 2.CB.15c
Crystal system Orthorhombic
Crystal class Disphenoidal (222)
H-M symbol: (2 2 2)
Space group I222 (No. 23)
Unit cell a = 10.76  Å, b = 5.4 Å
c = 16.09 Å, Z = 2
Identification
ColorBrass brown
Crystal habit Uniformly indistinguishable crystals forming large masses
Cleavage None
Fracture Conchoidal – uneven
Mohs scale hardness4
Luster Metallic
Streak Brown gray
Diaphaneity Opaque
Specific gravity 4.29
References [2] [3] [4]

Stannoidite is a sulfide mineral composed of five chemical elements: copper, iron, zinc, tin and sulfur. Its name originates from Latin stannum (tin) and Greek eides (or Latin oïda meaning "like"). The mineral is found in hydrothermal Cu-Sn deposits. [2] [3]

Stannoidite was first described in 1969 for an occurrence in the Konjo mine, Okayama prefecture, Honshu Island, Japan. [3]

See also

Related Research Articles

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Kësterite is a sulfide mineral with a chemical formula of Cu2(Zn,Fe)SnS4. In its lattice structure, zinc and iron atoms share the same lattice sites. Kesterite is the Zn-rich variety whereas the Zn-poor form is called ferrokesterite or stannite. Owing to their similarity, kesterite is sometimes called isostannite. The synthetic form of kesterite is abbreviated as CZTS. The name kesterite is sometimes extended to include this synthetic material and also CZTSe, which contains selenium instead of sulfur.

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Hemusite is a very rare isometric gray mineral containing copper, molybdenum, sulfur, and tin with chemical formula Cu6SnMoS8. It was discovered by Bulgarian mineralogist Georgi Terziev in 1963. He also described it and named it after Haemus, the ancient name of Stara planina (Balkan) mountains in Europe. The type locality is Chelopech copper ore deposit, Bulgaria. Later tiny deposits of hemusite were found in Ozernovskoe deposit, Kamchatka, Russia; Kawazu mine, Rendaiji, Shimoda city, Chūbu region, Honshu Island, Japan; Iriki mine, Iriki, Satsuma-gun, Kagoshima Prefecture, Kyushu Region, Japan; Kochbulak deposit, Tashkent, Uzbekistan. Hemusite occurs as rounded isometric grains and aggregates usually about 0.05 mm in diameter and in association with enargite, luzonite, colusite, stannoidite, renierite, tennantite, chalcopyrite, pyrite, and other minerals.

Mawsonite is a brownish orange sulfosalt mineral, containing copper, iron, tin, and sulfur: Cu6Fe2SnS8.

Chatkalite is a copper, iron, tin sulfide mineral with formula Cu6Fe2+Sn6S8. It crystallizes in the tetragonal crystal system and forms as rounded dissemations within tetrahedrite in quartz veins.

Ximengite is a phosphate mineral discovered in and named for the Ximeng tin-mining district in China.

Genplesite is a very rare tin mineral coming from the Oktyabr'skoe deposit in the Noril'sk area, Russia, which is known for nickel and platinum group elements minerals. Its chemical formula is Ca3Sn(SO4)2(OH)6•3H2O. Genplesite is a member of the fleischerite group, and it is a calcium and tin-analogue of fleischerite. It is hexagonal, with space group P63/mmc.

Aspidolite is a mica group phyllosilicate mineral which is the sodium analogue of the magnesium-rich mineral phlogopite. The ideal chemical formula for aspidolite is NaMg3AlSi3O10(OH)2.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 Stannoidite. Webmineral
  3. 1 2 3 Stannoidite. Mindat.org
  4. Kudoh Y., Takeuchi Y. (1976). "The superstructure of stannoidite". Zeitschrift für Kristallographie – Crystalline Materials. 144 (1–6): 145–160. Bibcode:1976ZK....144..145K. doi:10.1524/zkri.1976.144.16.145. S2CID   201808201.