Stannite

Last updated
Stannite
Stannite-Chalcopyrite-Quartz-168837.jpg
General
Category Sulfide mineral
Formula
(repeating unit)
Cu2FeSnS4
IMA symbol Stn [1]
Strunz classification 2.CB.15a
Crystal system Tetragonal
Crystal class Scalenohedral (42m)
H-M symbol: (4 2m)
Space group I42m
Unit cell a = 5.4432, c = 10.7299 [Å]; Z = 2
Identification
ColorSteel-gray to iron-black, may tarnish blue
Crystal habit Rarely as pseudo-octahedral crystals also massive, granular, and disseminated
Twinning Penetration twins on {102}
Cleavage Indistinct on {110} and {001}
Fracture Uneven
Mohs scale hardness4
Luster Metallic
Streak Black
Diaphaneity Opaque
Specific gravity 4.3 – 4.5
References [2] [3] [4]

Stannite is a mineral, a sulfide of copper, iron, and tin, in the category of thiostannates.

Contents

Background

The chemical formula is Cu 2 Fe Sn S 4. Zinc commonly occurs with the iron and trace germanium may be present. [4] Stannite is used as an ore of tin, consisting of approximately 28% tin, 13% iron, 30% copper, 30% sulfur by mass. It is found in tin-bearing, hydrothermal vein deposits occurring with chalcopyrite, sphalerite, tetrahedrite, arsenopyrite, pyrite, cassiterite, and wolframite. [2]

It is also known as bell metal ore as tin is an important constituent of bell-metal. It is thought the exploitation of tin deposits in Cornwall led to an expansion in bell founding.

The name comes from the Latin for tin: stannum. It was first described in 1797 for an occurrence in Wheal Rock, St. Agnes, Cornwall, England. [4]

See also

Related Research Articles

<span class="mw-page-title-main">Ore</span> Rock with valuable metals, minerals and elements

Ore is natural rock or sediment that contains one or more valuable minerals, typically including metals, concentrated above background levels, and that is economically viable to mine and process. The grade of ore refers to the concentration of the desired material it contains. The value of the metals or minerals a rock contains must be weighed against the cost of extraction to determine whether it is of sufficiently high grade to be worth mining and is therefore considered an ore. A complex ore is one containing more than one valuable mineral.

<span class="mw-page-title-main">Chalcopyrite</span> Copper iron sulfide mineral

Chalcopyrite ( KAL-kə-PY-ryte, -⁠koh-) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green-tinged black.

<span class="mw-page-title-main">Bornite</span> Sulfide mineral

Bornite, also known as peacock ore, is a sulfide mineral with chemical composition Cu5FeS4 that crystallizes in the orthorhombic system (pseudo-cubic). It is an important copper ore.

<span class="mw-page-title-main">Galena</span> Natural mineral form of lead sulfide

Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver.

<span class="mw-page-title-main">Skarn</span> Hard, coarse-grained, hydrothermally altered metamorphic rocks

Skarns or tactites are coarse-grained metamorphic rocks that form by replacement of carbonate-bearing rocks during regional or contact metamorphism and metasomatism. Skarns may form by metamorphic recrystallization of impure carbonate protoliths, bimetasomatic reaction of different lithologies, and infiltration metasomatism by magmatic-hydrothermal fluids. Skarns tend to be rich in calcium-magnesium-iron-manganese-aluminium silicate minerals, which are also referred to as calc-silicate minerals. These minerals form as a result of alteration which occurs when hydrothermal fluids interact with a protolith of either igneous or sedimentary origin. In many cases, skarns are associated with the intrusion of a granitic pluton found in and around faults or shear zones that commonly intrude into a carbonate layer composed of either dolomite or limestone. Skarns can form by regional or contact metamorphism and therefore form in relatively high temperature environments. The hydrothermal fluids associated with the metasomatic processes can originate from a variety of sources; magmatic, metamorphic, meteoric, marine, or even a mix of these. The resulting skarn may consist of a variety of different minerals which are highly dependent on both the original composition of the hydrothermal fluid and the original composition of the protolith.

<span class="mw-page-title-main">Nickeline</span> Nickel arsenide mineral

Nickeline or niccolite is the mineral form of nickel arsenide. The naturally-occurring mineral contains roughly 43.9% nickel and 56.1% arsenic by mass, but composition of the mineral may vary slightly.

<span class="mw-page-title-main">Cuprite</span> Oxide mineral

Cuprite is an oxide mineral composed of copper(I) oxide Cu2O, and is a minor ore of copper.

<span class="mw-page-title-main">Tennantite</span> Copper arsenic sulfosalt mineral

Tennantite is a copper arsenic sulfosalt mineral with an ideal formula Cu12As4S13. Due to variable substitution of the copper by iron and zinc the formula is Cu6[Cu4(Fe,Zn)2]As4S13. It is gray-black, steel-gray, iron-gray or black in color. A closely related mineral, tetrahedrite (Cu12Sb4S13) has antimony substituting for arsenic and the two form a solid solution series. The two have very similar properties and is often difficult to distinguish between tennantite and tetrahedrite. Iron, zinc, and silver substitute up to about 15% for the copper site.

<span class="mw-page-title-main">Cobaltite</span> Sulfide mineral composed of cobalt, arsenic, and sulfur

Cobaltite is an arsenide and sulfide mineral with the mineral formula CoAsS. It is the naming mineral of the cobaltite group of minerals, whose members structurally resemble pyrite (FeS2).

<span class="mw-page-title-main">Bismuthinite</span> Bismuth (III) sulfide mineral

Bismuthinite is a mineral consisting of bismuth sulfide (Bi2S3). It is an important ore for bismuth. The crystals are steel-grey to off-white with a metallic luster. It is soft enough to be scratched with a fingernail and rather dense.

<span class="mw-page-title-main">Liroconite</span> Copper aluminium arsenate mineral

Liroconite is a complex mineral: Hydrated copper aluminium arsenate hydroxide, with the formula Cu2Al[(OH)4|AsO4]·4(H2O). It is a vitreous monoclinic mineral, colored bright blue to green, often associated with malachite, azurite, olivenite, and clinoclase. It is quite soft, with a Mohs hardness of 2–2.5, and has a specific gravity of 2.9–3.0.

<span class="mw-page-title-main">Sperrylite</span> Platinum arsenide mineral

Sperrylite is a platinum arsenide mineral with the chemical formula PtAs2 and is an opaque metallic tin white mineral which crystallizes in the isometric system with the pyrite group structure. It forms cubic, octahedral or pyritohedral crystals in addition to massive and reniform habits. It has a Mohs hardness of 6–7 and a very high specific gravity of 10.6.

<span class="mw-page-title-main">Greisen</span> Highly altered granitic rock or pegmatite

Greisen is a highly altered granitic rock or pegmatite, usually composed predominantly of quartz and micas. Greisen is formed by self-generated alteration of a granite and is a class of moderate- to high-temperature magmatic-hydrothermal alteration related to the late-stage release of volatiles dissolved in a magma during the solidification of that magma.

<span class="mw-page-title-main">Native metal</span> Form of metal

A native metal is any metal that is found pure in its metallic form in nature. Metals that can be found as native deposits singly or in alloys include antimony, arsenic, bismuth, cadmium, chromium, cobalt, indium, iron, manganese, molybdenum, nickel, niobium, rhenium, tantalum, tellurium, tin, titanium, tungsten, vanadium, and zinc, as well as the gold group and the platinum group. Among the alloys found in native state have been brass, bronze, pewter, German silver, osmiridium, electrum, white gold, silver-mercury amalgam, and gold-mercury amalgam.

<span class="mw-page-title-main">Augelite</span> Aluminium phosphate mineral

Augelite is an aluminium phosphate mineral with formula: Al2(PO4)(OH)3. The shade varies from colorless to white, yellow or rose. Its crystal system is monoclinic.

<span class="mw-page-title-main">Arthurite</span> Arsenate mineral

Arthurite is a mineral composed of divalent copper and iron ions in combination with trivalent arsenate, phosphate and sulfate ions with hydrogen and oxygen. Initially discovered by Sir Arthur Russell in 1954 at Hingston Down Consols mine in Calstock, Cornwall, England, arthurite is formed as a resultant mineral in the oxidation region of some copper deposits by the variation of enargite or arsenopyrite. The chemical formula of Arthurite is CuFe23+(AsO4,PO4,SO4)2(O,OH)2·4H2O.

<span class="mw-page-title-main">Cubanite</span> Copper iron sulfide mineral

Cubanite is a copper iron sulfide mineral that commonly occurs as a minor alteration mineral in magmatic sulfide deposits. It has the chemical formula CuFe2S3 and when found, it has a bronze to brass-yellow appearance. On the Mohs hardness scale, cubanite falls between 3.5 and 4 and has a orthorhombic crystal system. Cubanite is chemically similar to chalcopyrite; however, it is the less common copper iron sulfide mineral due to crystallization requirements.

<span class="mw-page-title-main">Stannoidite</span>

Stannoidite is a sulfide mineral composed of five chemical elements: copper, iron, zinc, tin and sulfur. Its name originates from Latin stannum (tin) and Greek eides. The mineral is found in hydrothermal Cu-Sn deposits.

<span class="mw-page-title-main">Kesterite</span> Sulfide mineral

Kësterite is a sulfide mineral with a chemical formula of Cu2(Zn,Fe)SnS4. In its lattice structure, zinc and iron atoms share the same lattice sites. Kesterite is the Zn-rich variety whereas the Zn-poor form is called ferrokesterite or stannite. Owing to their similarity, kesterite is sometimes called isostannite. The synthetic form of kesterite is abbreviated as CZTS. The name kesterite is sometimes extended to include this synthetic material and also CZTSe, which contains selenium instead of sulfur.

Mawsonite is a brownish orange sulfosalt mineral, containing copper, iron, tin, and sulfur: Cu6Fe2SnS8.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 "Stannite" (PDF). Handbook of Mineralogy.
  3. "Stannite". Webmineral data.
  4. 1 2 3 "Stannite". Mindat.org.