Deicing

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An Aeroflot Airbus A330 being de-iced at Sheremetyevo International Airport Aeroflot Airbus A330-200 de-icing Pereslavtsev.jpg
An Aeroflot Airbus A330 being de-iced at Sheremetyevo International Airport
Econ Salt Spreader Econ Salt Spreader.jpg
Econ Salt Spreader

De-icing is the process of removing snow, ice or frost from a surface. Anti-icing is the application of chemicals that not only de-ice but also remain on a surface and continue to delay the reformation of ice for a certain period of time, or prevent adhesion of ice to make mechanical removal easier.

Contents

De-icing can be accomplished by mechanical methods (scraping, pushing); through the application of heat; by use of dry or liquid chemicals designed to lower the freezing point of water (various salts or brines, alcohols, glycols); or by a combination of these different techniques.

Application areas

Roadways

In 2013, an estimated 14 million tons of salt were used for de-icing roads in North America. [1]

De-icing of roads has traditionally been done with salt, spread by snowplows or dump trucks designed to spread it, often mixed with sand and gravel, on slick roads. Sodium chloride (rock salt) is normally used, as it is inexpensive and readily available in large quantities. However, since salt water still freezes at −18 °C (0 °F), it is of no help when the temperature falls below this point. It also has a tendency to cause corrosion, rusting the steel used in most vehicles and the rebar in concrete bridges. Depending on the concentration, it can be toxic to some plants and animals, [2] and some urban areas have moved away from it as a result. More recent snowmelters use other salts, such as calcium chloride and magnesium chloride, which not only depress the freezing point of water to a much lower temperature, but also produce an exothermic reaction. They are somewhat safer for sidewalks, but excess should still be removed.

More recently, organic compounds have been developed that reduce the environmental issues connected with salts and have longer residual effects when spread on roadways, usually in conjunction with salt brines or solids. These compounds are often generated as byproducts of agricultural operations such as sugar beet refining or the distillation process that produces ethanol. [3] [4] Other organic compounds are wood ash and a de-icing salt called calcium magnesium acetate made from roadside grass or even kitchen waste. [5] Additionally, mixing common rock salt with some of the organic compounds and magnesium chloride results in spreadable materials that are both effective to much colder temperatures (−34 °C (−29 °F)) as well as at lower overall rates of spreading per unit area. [6]

Several of these new compounds release very small amounts of gases into the air, which are known to be able to cause irritation of the throat and the respiratory tract in humans and animals. The majority of the human population do not experience problems although long-term effects have not been studied. People with sensitive airways, especially infants, may experience serious respiratory problems. Broader scientific studies of the respiratory health problems specifically for people with sensitive airways are lacking (in general, scientific studies have focused on non-respiratory health issues and environmental issues).

Solar road systems have been used to maintain the surface of roads above the freezing point of water. An array of pipes embedded in the road surface is used to collect solar energy in summer, transfer the heat to thermal banks and return the heat to the road in winter to maintain the surface above 0 °C (32 °F). [7] This automated form of renewable energy collection, storage and delivery avoids the environmental issues of using chemical contaminants.

It was suggested in 2012 that superhydrophobic surfaces capable of repelling water can also be used to prevent ice accumulation leading to icephobicity. However, not every superhydrophobic surface is icephobic [8] and the method is still under development. [9]

Trains and rail switches

Ice build up in train brakes jeopardizes effective braking. Icy train brake.jpg
Ice build up in train brakes jeopardizes effective braking.

Trains and rail switches in Arctic regions can have significant problems with snow and ice build up. They need a constant heat source on cold days to ensure functionality. On trains it is primarily the brakes, suspension, and couplers that require heaters for de-icing. On the rails it is primarily track switches that are sensitive to ice. High-powered electrical heaters prevent ice formation and rapidly melt any ice that forms.

The heaters are preferably made of PTC material, for example PTC rubber, to avoid overheating and potentially destroying the heaters. These heaters are self-limiting and require no regulating electronics; they cannot overheat and require no overheat protection. [10]

Aviation

A U.S. C-37B VIP jet gets de-iced before departing Alaska in January 2012 A U.S. Army C-37B aircraft transporting Army Chief of Staff Gen. Raymond T. Odierno, gets de-iced before it departs Joint Base Elmendorf-Richardson, Alaska.jpg
A U.S. C-37B VIP jet gets de-iced before departing Alaska in January 2012

Ground de-icing of aircraft

On the ground, when there are freezing conditions and precipitation, de-icing an aircraft is commonly practiced. Frozen contaminants interfere with the aerodynamic properties of the vehicle. Furthermore, dislodged ice can damage the engines.

Ground de-icing methods include:

  • Spraying on various aircraft deicing fluids to melt ice and prevent reformation
  • Using unheated forced air to blow off loose snow and ice
  • Using infrared heating to melt snow, ice, and frost without using chemicals
  • Mechanical deicing using tools such as brooms, scrapers, and ropes
  • Placing an aircraft in a warm hangar

In-flight de-icing

Ice can build up on aircraft in flight due to atmospheric conditions, causing potential degradation of flight performance. Large commercial aircraft almost always have in-flight ice protections systems to shed ice buildup and prevent reformation. Ice protection systems are becoming increasingly common in smaller general aviation aircraft as well.

Ice protection systems typically use one or more of the following approaches:

  • pneumatic rubber "boots" on leading edges of wings and control surfaces, which expand to break off accumulated ice
  • electrically heated strips on critical surfaces to prevent ice formation and melt accumulated ice
  • bleed air systems which take heated air from the engines and duct them to locations where ice can accumulate
  • fluid systems which "weep" de-icing fluid over wings and control surfaces via tiny holes

Airport pavement

De-icing operations for airport pavement (runways, taxiways, aprons, taxiway bridges) may involve several types of liquid and solid chemical products, including propylene glycol, ethylene glycol and other organic compounds. Chloride-based compounds (e.g. salt) are not used at airports, due to their corrosive effect on aircraft and other equipment. [11] :34–35

Urea mixtures have also been used for pavement de-icing, due to their low cost. However, urea is a significant pollutant in waterways and wildlife, as it degrades to ammonia after application, and it has largely been phased out at U.S. airports. In 2012 the U.S. Environmental Protection Agency (EPA) prohibited use of urea-based de-icers at most commercial airports. [12]

Water agitator de-icer

Water agitators are electric motors put under water that propel up warmer water and agitate the surface with it to de-ice aquatic structures on rivers and lakes in freezing temperatures. There are also agitator bubblers that use compressed air, run through a hose, and released to agitate the water. [13]

De-icing chemicals

All chemical de-icers share a common working mechanism: they chemically prevent water molecules from binding above a certain temperature that depends on the concentration. This temperature is below 0 °C, the freezing point of pure water (freezing point depression). Sometimes, there is an exothermic dissolution reaction that allows for an even stronger melting power. The following lists contains the most-commonly used de-icing chemicals and their typical chemical formula.

Salts

Organics

Environmental impact and mitigation

De-icing salts such as sodium chloride or calcium chloride leach into natural waters, strongly affecting their salinity. [1]

Ethylene glycol and propylene glycol are known to exert high levels of biochemical oxygen demand (BOD) during degradation in surface waters. This process can adversely affect aquatic life by consuming oxygen needed by aquatic organisms for survival. Large quantities of dissolved oxygen (DO) in the water column are consumed when microbial populations decompose propylene glycol. [14] :2–23

Some airports recycle used de-icing fluid, separating water and solid contaminants, enabling reuse of the fluid in other applications. Other airports have an on-site wastewater treatment facility, and/or send collected fluid to a municipal sewage treatment plant or a commercial wastewater treatment facility. [11] :68–80 [15]

See also

Related Research Articles

<span class="mw-page-title-main">Brine</span> Concentrated solution of salt in water

Brine is a high-concentration solution of salt in water. In diverse contexts, brine may refer to the salt solutions ranging from about 3.5% up to about 26%. Brine forms naturally due to evaporation of ground saline water but it is also generated in the mining of sodium chloride. Brine is used for food processing and cooking, for de-icing of roads and other structures, and in a number of technological processes. It is also a by-product of many industrial processes, such as desalination, so it requires wastewater treatment for proper disposal or further utilization.

<span class="mw-page-title-main">Sodium chloride</span> Chemical compound with formula NaCl

Sodium chloride, commonly known as edible salt, is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chlorine ions. It is transparent or translucent, brittle, hygroscopic, and occurs as the mineral halite. In its edible form, it is commonly used as a condiment and food preservative. Large quantities of sodium chloride are used in many industrial processes, and it is a major source of sodium and chlorine compounds used as feedstocks for further chemical syntheses. Another major application of sodium chloride is deicing of roadways in sub-freezing weather.

<span class="mw-page-title-main">Ethylene glycol</span> Organic compound ethane-1,2-diol

Ethylene glycol is an organic compound with the formula (CH2OH)2. It is mainly used for two purposes: as a raw material in the manufacture of polyester fibers and for antifreeze formulations. It is an odorless, colorless, flammable, viscous liquid. It has a sweet taste, but is toxic in high concentrations. This molecule has been observed in outer space.

<span class="mw-page-title-main">Propylene glycol</span> Chemical compound

Propylene glycol (IUPAC name: propane-1,2-diol) is a viscous, colorless liquid. It is almost odorless and has a faintly sweet taste. Its chemical formula is CH3CH(OH)CH2OH. As it contains two alcohol groups, it is classified as a diol. An aliphatic diol may also be called a glycol. It is miscible with a broad range of solvents, including water, acetone, and chloroform. In general, glycols are non-irritating and have very low volatility.

<span class="mw-page-title-main">Black ice</span> Thin coating of glazed ice on a surface

Black ice, sometimes called clear ice, is a coating of glaze ice on a surface, for example on streets or on lakes. The ice itself is not black, but visually transparent, allowing the often black road below to be seen through it and light to be transmitted. The typically low levels of noticeable ice pellets, snow, or sleet surrounding black ice means that areas of the ice are often next to invisible to drivers or people walking on it. Thus, there is a risk of slippage and subsequent accident due to the unexpected loss of traction.

<span class="mw-page-title-main">Magnesium chloride</span> Inorganic salt: MgCl2 and its hydrates

Magnesium chloride is an inorganic compound with the formula MgCl2. It forms hydrates MgCl2·nH2O, where n can range from 1 to 12. These salts are colorless or white solids that are highly soluble in water. These compounds and their solutions, both of which occur in nature, have a variety of practical uses. Anhydrous magnesium chloride is the principal precursor to magnesium metal, which is produced on a large scale. Hydrated magnesium chloride is the form most readily available.

An antifreeze is an additive which lowers the freezing point of a water-based liquid. An antifreeze mixture is used to achieve freezing-point depression for cold environments. Common antifreezes also increase the boiling point of the liquid, allowing higher coolant temperature. However, all common antifreeze additives also have lower heat capacities than water, and do reduce water's ability to act as a coolant when added to it.

<span class="mw-page-title-main">Freezing-point depression</span> Drop in freezing temperature of a solvent due to the addition of solute

Freezing-point depression is a drop in the maximum temperature at which a substance freezes, caused when a smaller amount of another, non-volatile substance is added. Examples include adding salt into water, alcohol in water, ethylene or propylene glycol in water, adding copper to molten silver, or the mixing of two solids such as impurities into a finely powdered drug.

<span class="mw-page-title-main">Snow removal</span> Job of removing snow

Snow removal or snow clearing is the job of removing snow after a snowfall to make travel easier and safer. This is done both by individual households and by governments institutions, and commercial businesses.

<span class="mw-page-title-main">Ice protection system</span> System to limit ice on aircraft surfaces

In aeronautics, ice protection systems keep atmospheric moisture from accumulating on aircraft surfaces, such as wings, propellers, rotor blades, engine intakes, and environmental control intakes. Ice buildup can change the shape of airfoils and flight control surfaces, degrading control and handling characteristics as well as performance. An anti-icing, de-icing, or ice protection system either prevents formation of ice, or enables the aircraft to shed the ice before it becomes dangerous.

In ground deicing of aircraft, aircraft de-icing fluid (ADF), aircraft de-icer and anti-icer fluid (ADAF) or aircraft anti-icing fluid (AAF) are commonly used for both commercial and general aviation. Environmental concerns include increased salinity of groundwater where de-icing fluids are discharged into soil, and toxicity to humans and other mammals.

<span class="mw-page-title-main">Sodium formate</span> Chemical compound

Sodium formate, HCOONa, is the sodium salt of formic acid, HCOOH. It usually appears as a white deliquescent powder.

Calcium magnesium acetate (CMA, with chemical formula C12H18CaMg2O12) is a deicer and can be used as an alternative to road salt. It is approximately as corrosive as normal tap water, and in varying concentrations can be effective in stopping road ice from forming down to around −27.5 °C (−17.5 °F) (its eutectic temperature). CMA can also be used as an H2S capture agent.

<span class="mw-page-title-main">Winter service vehicle</span> Vehicle used to clear snow and ice

A winter service vehicle (WSV), or snow removal vehicle, is a vehicle specially designed or adapted to clear thoroughfares of ice and snow. Winter service vehicles are usually based on a dump truck chassis, with adaptations allowing them to carry specially designed snow removal equipment. Many authorities also use smaller vehicles on sidewalks, footpaths, and cycleways. Road maintenance agencies and contractors in temperate or polar areas often own several winter service vehicles, using them to keep the roads clear of snow and ice and safe for driving during winter. Airports use winter service vehicles to keep aircraft surfaces, runways, and taxiways free of snow and ice, which, besides endangering aircraft takeoff and landing, can interfere with the aerodynamics of the craft.

<span class="mw-page-title-main">Cooling bath</span> Liquid mixture used to maintain low temperatures

A cooling bath or ice bath, in laboratory chemistry practice, is a liquid mixture which is used to maintain low temperatures, typically between 13 °C and −196 °C. These low temperatures are used to collect liquids after distillation, to remove solvents using a rotary evaporator, or to perform a chemical reaction below room temperature.

The ThermaWing ice protection system uses a flexible, electrically conductive, graphite foil attached to a wing's leading edge. Once activated the foil heats quickly, melting and then shedding any ice.

Calcium nitrite is an inorganic compound with the chemical formula Ca(NO
2
)
2
. In this compound, as in all nitrites, nitrogen is in a +3 oxidation state. It has many applications such as antifreeze, rust inhibitor of steel and wash heavy oil.

Soil stabilization is a general term for any physical, chemical, mechanical, biological, or combined method of changing a natural soil to meet an engineering purpose. Improvements include increasing the weight-bearing capabilities, tensile strength, and overall performance of unstable subsoils, sands, and waste materials in order to strengthen road pavements.

<span class="mw-page-title-main">Ground deicing of aircraft</span> Removal of frost, ice, or frozen contaminants

In aviation, ground deicing of aircraft is the process of removing surface frost, ice or frozen contaminants on aircraft surfaces before an aircraft takes off. This prevents even a small amount of surface frost or ice on aircraft surfaces from severely impacting flight performance. Frozen contaminants on surfaces can also break off in flight, damaging engines or control surfaces.

<span class="mw-page-title-main">Road salt</span> Salts used for de-icing road surfaces

Road salt is a salt used mainly as an anti-slip agent in winter road conditions, but also to prevent dust and snow build-up on roads. Various kinds of salts are used as road salt, but calcium chloride and sodium chloride are among the most common. The more expensive magnesium chloride is generally considered safer, but is not as widely used because of its cost and effect on structural integrity. When used in its solid form, road salt is often pre-wet to accelerate the ice-melting process.

References

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  12. "Airport Deicing Effluent Guidelines". EPA. 2021-02-10.
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