Deicing is the process of removing snow, ice or frost from a surface. Anti-icing is the application of chemicals that not only deice but also remain on a surface and continue to delay the reformation of ice for a certain period of time, or prevent adhesion of ice to make mechanical removal easier.
Deicing can be accomplished by mechanical methods (scraping, pushing); through the application of heat; by use of dry or liquid chemicals designed to lower the freezing point of water (various salts or brines, alcohols, glycols); or by a combination of these different techniques.
In 2013, an estimated 14 million tons of salt were used for deicing roads in North America. [1]
Deicing of roads has traditionally been done with salt, spread by snowplows or dump trucks designed to spread it, often mixed with sand and gravel, on slick roads. Sodium chloride (rock salt) is normally used, as it is inexpensive and readily available in large quantities. However, since salt water still freezes at −18 °C (0 °F), it is of no help when the temperature falls below this point. It also has a tendency to cause corrosion, rusting the steel used in most vehicles and the rebar in concrete bridges. Depending on the concentration, it can be toxic to some plants and animals, [2] and some urban areas have moved away from it as a result. More recent snowmelters use other salts, such as calcium chloride and magnesium chloride, which not only depress the freezing point of water to a much lower temperature, but also produce an exothermic reaction. They are somewhat safer for sidewalks, but excess should still be removed.
More recently, organic compounds have been developed that reduce the environmental issues connected with salts and have longer residual effects when spread on roadways, usually in conjunction with salt brines or solids. These compounds are often generated as byproducts of agricultural operations such as sugar beet refining or the distillation process that produces ethanol. [3] [4] Other organic compounds are wood ash and a deicing salt called calcium magnesium acetate made from roadside grass or even kitchen waste. [5] Additionally, mixing common rock salt with some of the organic compounds and magnesium chloride results in spreadable materials that are both effective to much colder temperatures (−34 °C (−29 °F)) as well as at lower overall rates of spreading per unit area. [6]
Solar road systems have been used to maintain the surface of roads above the freezing point of water. An array of pipes embedded in the road surface is used to collect solar energy in summer, transfer the heat to thermal banks and return the heat to the road in winter to maintain the surface above 0 °C (32 °F). [7] This automated form of renewable energy collection, storage and delivery avoids the environmental issues of using chemical contaminants.
It was suggested in 2012 that superhydrophobic surfaces capable of repelling water can also be used to prevent ice accumulation leading to icephobicity. However, not every superhydrophobic surface is icephobic [8] and the method is still under development. [9]
Trains and rail switches in Arctic regions can have significant problems with snow and ice build up. They need a constant heat source on cold days to ensure functionality. On trains it is primarily the brakes, suspension and couplers that require heaters for deicing. On rails it is primarily the switches that are sensitive to ice. High-powered electrical heaters prevent ice formation and rapidly melt any ice that forms.
The heaters are preferably made of PTC material, for example PTC rubber, to avoid overheating and potentially destroying the heaters. These heaters are self-limiting and require no regulating electronics; they cannot overheat and require no overheat protection. [10]
On the ground, when there are freezing conditions and precipitation, deicing an aircraft is commonly practiced. Frozen contaminants interfere with the aerodynamic properties of the vehicle. Furthermore, dislodged ice can damage the engines.
Ground deicing methods include:
Ice can build up on aircraft in flight due to atmospheric conditions, causing potential degradation of flight performance. Large commercial aircraft almost always have in-flight ice protections systems to shed ice buildup and prevent reformation. Ice protection systems are becoming increasingly common in smaller general aviation aircraft as well.
Ice protection systems typically use one or more of the following approaches:
Deicing operations for airport pavement (runways, taxiways, aprons, taxiway bridges) may involve several types of liquid and solid chemical products, including propylene glycol, ethylene glycol and other organic compounds. Chloride-based compounds (e.g. salt) are not used at airports, due to their corrosive effect on aircraft and other equipment. [11] : 34–35
Urea mixtures have also been used for pavement deicing, due to their low cost. However, urea is a significant pollutant in waterways and wildlife, as it degrades to ammonia after application, and it has largely been phased out at U.S. airports. In 2012 the U.S. Environmental Protection Agency (EPA) prohibited use of urea-based deicers at most commercial airports. [12]
Water agitators are electric motors put under water that propel up warmer water and agitate the surface with it to deice aquatic structures on rivers and lakes in freezing temperatures. There are also agitator bubblers that use compressed air, run through a hose, and released to agitate the water. [13]
All chemical deicers share a common working mechanism: they chemically prevent water molecules from binding above a certain temperature that depends on the concentration. This temperature is below 0 °C, the freezing point of pure water (freezing point depression). Sometimes, there is an exothermic dissolution reaction that allows for an even stronger melting power. The following lists contains the most-commonly used deicing chemicals and their typical chemical formula.
Deicing salts such as sodium chloride or calcium chloride leach into natural waters, strongly affecting their salinity. [1]
Ethylene glycol and propylene glycol are known to exert high levels of biochemical oxygen demand (BOD) during degradation in surface waters. This process can adversely affect aquatic life by consuming oxygen needed by aquatic organisms for survival. Large quantities of dissolved oxygen (DO) in the water column are consumed when microbial populations decompose propylene glycol. [14] : 2–23
Some airports recycle used deicing fluid, separating water and solid contaminants, enabling reuse of the fluid in other applications. Other airports have an on-site wastewater treatment facility, and/or send collected fluid to a municipal sewage treatment plant or a commercial wastewater treatment facility. [11] : 68–80 [15]
Sodium chloride, commonly known as edible salt, is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chlorine ions. It is transparent or translucent, brittle, hygroscopic, and occurs as the mineral halite. In its edible form, it is commonly used as a condiment and food preservative. Large quantities of sodium chloride are used in many industrial processes, and it is a major source of sodium and chlorine compounds used as feedstocks for further chemical syntheses. Another major application of sodium chloride is deicing of roadways in sub-freezing weather.
Propylene glycol (IUPAC name: propane-1,2-diol) is a viscous, colorless liquid. It is almost odorless and has a faintly sweet taste. Its chemical formula is CH3CH(OH)CH2OH. As it contains two alcohol groups, it is classed as a diol. An aliphatic diol may also be called a glycol. It is miscible with a broad range of solvents, including water, acetone, and chloroform. In general, glycols are non-irritating and have very low volatility.
Calcium chloride is an inorganic compound, a salt with the chemical formula CaCl2. It is a white crystalline solid at room temperature, and it is highly soluble in water. It can be created by neutralising hydrochloric acid with calcium hydroxide.
Black ice, sometimes called clear ice, is a coating of glaze ice on a surface, for example on streets or on lakes. The ice itself is not black, but visually transparent, allowing the often black road below to be seen through it and light to be transmitted. The typically low levels of noticeable ice pellets, snow, or sleet surrounding black ice means that areas of the ice are often next to invisible to drivers or people walking on it. Thus, there is a risk of slippage and subsequent accident due to the unexpected loss of traction.
An antifreeze is an additive which lowers the freezing point of a water-based liquid. An antifreeze mixture is used to achieve freezing-point depression for cold environments. Common antifreezes also increase the boiling point of the liquid, allowing higher coolant temperature. However, all common antifreeze additives also have lower heat capacities than water, and do reduce water's ability to act as a coolant when added to it.
Freezing-point depression is a drop in the maximum temperature at which a substance freezes, caused when a smaller amount of another, non-volatile substance is added. Examples include adding salt into water, alcohol in water, ethylene or propylene glycol in water, adding copper to molten silver, or the mixing of two solids such as impurities into a finely powdered drug.
Water softening is the removal of calcium, magnesium, and certain other metal cations in hard water. The resulting soft water requires less soap for the same cleaning effort, as soap is not wasted bonding with calcium ions. Soft water also extends the lifetime of plumbing by reducing or eliminating scale build-up in pipes and fittings. Water softening is usually achieved using lime softening or ion-exchange resins, but is increasingly being accomplished using nanofiltration or reverse osmosis membranes.
Snow removal or snow clearing is the job of removing snow after a snowfall to make travel easier and safer. This is done both by individual households and by governments, institutions, and commercial businesses.
In aeronautics, ice protection systems keep atmospheric moisture from accumulating on aircraft surfaces, such as wings, propellers, rotor blades, engine intakes, and environmental control intakes. Ice buildup can change the shape of airfoils and flight control surfaces, degrading control and handling characteristics as well as performance. An anti-icing, de-icing, or ice protection system either prevents formation of ice, or enables the aircraft to shed the ice before it becomes dangerous.
In ground deicing of aircraft, aircraft deicing fluid (ADF), aircraft deicer and anti-icer fluid (ADAF) or aircraft anti-icing fluid (AAF) are commonly used for both commercial and general aviation. Environmental concerns include increased salinity of groundwater where de-icing fluids are discharged into soil, and toxicity to humans and other mammals.
Sodium formate, HCOONa, is the sodium salt of formic acid, HCOOH. It usually appears as a white deliquescent powder.
Calcium magnesium acetate (CMA) is a deicer and can be used as an alternative to road salt. It is approximately as corrosive as normal tap water, and in varying concentrations can be effective in stopping road ice from forming down to around −27.5 °C (−17.5 °F) (its eutectic temperature). CMA can also be used as an H2S capture agent.
A winter service vehicle (WSV), or snow removal vehicle, is a vehicle specially designed or adapted to clear thoroughfares of ice and snow. Winter service vehicles are usually based on a dump truck chassis, with adaptations allowing them to carry specially designed snow removal equipment. Many authorities also use smaller vehicles on sidewalks, footpaths, and cycleways. Road maintenance agencies and contractors in temperate or polar areas often own several winter service vehicles, using them to keep the roads clear of snow and ice and safe for driving during winter. Airports use winter service vehicles to keep both aircraft surfaces, and runways and taxiways free of snow and ice, which, besides endangering aircraft takeoff and landing, can interfere with the aerodynamics of the craft.
A cooling bath or ice bath, in laboratory chemistry practice, is a liquid mixture which is used to maintain low temperatures, typically between 13 °C and −196 °C. These low temperatures are used to collect liquids after distillation, to remove solvents using a rotary evaporator, or to perform a chemical reaction below room temperature.
Isopropyl alcohol is a colorless, flammable organic compound with a pungent alcoholic odor.
Calcium nitrite is an inorganic compound with the chemical formula Ca(NO
2)
2. In this compound, as in all nitrites, nitrogen is in a +3 oxidation state. It has many applications such as antifreeze, rust inhibitor of steel and wash heavy oil.
Icephobicity is the ability of a solid surface to repel ice or prevent ice formation due to a certain topographical structure of the surface. The word "icephobic" was used for the first time at least in 1950; however, the progress in micropatterned surfaces resulted in growing interest towards icephobicity since the 2000s.
Soil stabilization is a general term for any physical, chemical, mechanical, biological, or combined method of changing a natural soil to meet an engineering purpose. Improvements include increasing the weight-bearing capabilities, tensile strength, and overall performance of unstable subsoils, sands, and waste materials in order to strengthen road pavements.
In aviation, ground deicing of aircraft is the process of removing surface frost, ice or frozen contaminants on aircraft surfaces before an aircraft takes off. This prevents even a small amount of surface frost or ice on aircraft surfaces from severely impacting flight performance. Frozen contaminants on surfaces can also break off in flight, damaging engines or control surfaces.
Road salt is a salt used mainly as an anti-slip agent in winter road conditions, but also to prevent dust and snow build-up on roads. Various kinds of salts are used as road salt, but calcium chloride or sodium chloride are among the most common. The more expensive salt magnesium chloride is generally considered safer, but isn't as widely used due to its price and effect on structural integrity. When used in its solid form, road salt is often pre-wet as this speeds up the melting process significantly.
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