Names | |||
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IUPAC name Sodium bromate | |||
Other names Sodium bromate(V) Bromic acid, sodium salt | |||
Identifiers | |||
3D model (JSmol) | |||
ChEBI | |||
ChemSpider | |||
ECHA InfoCard | 100.029.237 | ||
EC Number |
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PubChem CID | |||
RTECS number |
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UNII | |||
UN number | 1494 | ||
CompTox Dashboard (EPA) | |||
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Properties | |||
NaBrO3 | |||
Molar mass | 150.89g/mol | ||
Appearance | colorless or white solid | ||
Odor | odorless | ||
Density | 3.339 g/cm3 | ||
Melting point | 381 °C (718 °F; 654 K) | ||
Boiling point | 1,390 °C (2,530 °F; 1,660 K) | ||
27.5 g/100 mL (0 °C) 36.4 g/100 mL (20 °C) 48.8 g/100 mL (40 °C) 90.8 g/100 mL (100 °C) | |||
Solubility | soluble in ammonia insoluble in ethanol | ||
−44.2·10−6 cm3/mol | |||
Refractive index (nD) | 1.594 | ||
Structure | |||
cubic | |||
Thermochemistry | |||
Std molar entropy (S⦵298) | 130.5 J/mol K | ||
Std enthalpy of formation (ΔfH⦵298) | -342.5 kJ/mol | ||
Gibbs free energy (ΔfG⦵) | -252.6 kJ/mol | ||
Hazards | |||
Occupational safety and health (OHS/OSH): | |||
Main hazards | Oxidizing agent | ||
GHS labelling: | |||
Danger | |||
H271, H272, H302, H315, H319, H335, H341, H350 | |||
P201, P202, P210, P220, P221, P261, P264, P270, P271, P280, P281, P283, P301+P312, P302+P352, P304+P340, P305+P351+P338, P306+P360, P308+P313, P312, P321, P330, P332+P313, P337+P313, P362, P370+P378, P371+P380+P375, P403+P233, P405, P501 | |||
NFPA 704 (fire diamond) | |||
Flash point | 381 °C (718 °F; 654 K) | ||
Safety data sheet (SDS) | ICSC 0196 | ||
Related compounds | |||
Other anions | Sodium chlorate Sodium iodate | ||
Other cations | Potassium bromate Calcium bromate | ||
Related compounds | Sodium bromide Sodium hypobromite Sodium bromite | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
This article needs additional citations for verification .(June 2019) |
Sodium bromate, the inorganic compound with the chemical formula of NaBrO3, is the sodium salt of bromic acid. It is a strong oxidant.
Sodium bromate is mainly used in continuous or batch dyeing processes involving sulfur or vat dyes and as a hair-permagent, chemical agent, or gold solvent in gold mines when used with sodium bromide.
Sodium bromate is produced by passing bromine into a solution of sodium carbonate. [1] It may also be produced by the electrolytic oxidation of sodium bromide. Alternatively, it can also be created by the oxidation of bromine with chlorine to sodium hydroxide at 80 °C.
3 Br2+3 Na2CO3 → 5 NaBr+NaBrO3+3 CO2
Bromate in drinking water is undesirable because it is a suspected human carcinogen. [2] [3] Its presence in Coca-Cola's Dasani bottled water forced a recall of that product in the UK. [4]
Bromine is a chemical element; it has symbol Br and atomic number 35. It is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between those of chlorine and iodine. Isolated independently by two chemists, Carl Jacob Löwig and Antoine Jérôme Balard, its name was derived from the Ancient Greek βρῶμος (bromos) meaning "stench", referring to its sharp and pungent smell.
Sodium carbonate is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water. Historically, it was extracted from the ashes of plants grown in sodium-rich soils, and because the ashes of these sodium-rich plants were noticeably different from ashes of wood, sodium carbonate became known as "soda ash". It is produced in large quantities from sodium chloride and limestone by the Solvay process, as well as by carbonating sodium hydroxide which is made using the Chlor-alkali process.
An oxidizing agent is a substance in a redox chemical reaction that gains or "accepts"/"receives" an electron from a reducing agent. In other words, an oxidizer is any substance that oxidizes another substance. The oxidation state, which describes the degree of loss of electrons, of the oxidizer decreases while that of the reductant increases; this is expressed by saying that oxidizers "undergo reduction" and "are reduced" while reducers "undergo oxidation" and "are oxidized". Common oxidizing agents are oxygen, hydrogen peroxide, and the halogens.
Hydrogen bromide is the inorganic compound with the formula HBr. It is a hydrogen halide consisting of hydrogen and bromine. A colorless gas, it dissolves in water, forming hydrobromic acid, which is saturated at 68.85% HBr by weight at room temperature. Aqueous solutions that are 47.6% HBr by mass form a constant-boiling azeotrope mixture that boils at 124.3 °C (255.7 °F). Boiling less concentrated solutions releases H2O until the constant-boiling mixture composition is reached.
Sodium bromide is an inorganic compound with the formula NaBr. It is a high-melting white, crystalline solid that resembles sodium chloride. It is a widely used source of the bromide ion and has many applications.
A bromide ion is the negatively charged form (Br−) of the element bromine, a member of the halogens group on the periodic table. Most bromides are colorless. Bromides have many practical roles, being found in anticonvulsants, flame-retardant materials, and cell stains. Although uncommon, chronic toxicity from bromide can result in bromism, a syndrome with multiple neurological symptoms. Bromide toxicity can also cause a type of skin eruption, see potassium bromide. The bromide ion has an ionic radius of 196 pm.
Sodium oxide is a chemical compound with the formula Na2O. It is used in ceramics and glasses. It is a white solid but the compound is rarely encountered. Instead "sodium oxide" is used to describe components of various materials such as glasses and fertilizers which contain oxides that include sodium and other elements.
The bromate anion, BrO−
3, is a bromine-based oxoanion. A bromate is a chemical compound that contains this ion. Examples of bromates include sodium bromate,, and potassium bromate,.
Bromine pentafluoride, BrF5, is an interhalogen compound and a fluoride of bromine. It is a strong fluorinating agent.
Potassium bromate is a bromate of potassium and takes the form of white crystals or powder. It is a strong oxidizing agent.
Hypobromous acid is a weak, unstable acid with chemical formula of HOBr. It is mainly produced and handled in an aqueous solution. It is generated both biologically and commercially as a disinfectant. Salts of hypobromite are rarely isolated as solids.
Arsenic tribromide is an inorganic compound with the formula AsBr3, it is a bromide of arsenic. Arsenic is a chemical element that has the symbol As and atomic number 33. This pyramidal molecule is the only known binary arsenic bromide. AsBr3 is noteworthy for its very high refractive index of approximately 2.3. It also has a very high diamagnetic susceptibility. It is a poisonous metalloid that has many allotropic forms: yellow and several black and gray forms (metalloids), orthorhombic prisms, colorless rhombic crystals are a few that are seen. Bromine is a halogen element with the symbol Br and atomic number 35. Diatomic bromine does not occur naturally, but bromine salts can be found in crustal rock.
The hypobromite ion, also called alkaline bromine water, is BrO−. Bromine is in the +1 oxidation state. The Br–O bond length is 1.82 Å. Hypobromite is the bromine compound analogous to hypochlorites found in common bleaches, and in immune cells. In many ways, hypobromite functions in the same manner as hypochlorite, and is also used as a germicide and antiparasitic in both industrial applications, and in the immune system.
Bromine compounds are compounds containing the element bromine (Br). These compounds usually form the -1, +1, +3 and +5 oxidation states. Bromine is intermediate in reactivity between chlorine and iodine, and is one of the most reactive elements. Bond energies to bromine tend to be lower than those to chlorine but higher than those to iodine, and bromine is a weaker oxidising agent than chlorine but a stronger one than iodine. This can be seen from the standard electrode potentials of the X2/X− couples (F, +2.866 V; Cl, +1.395 V; Br, +1.087 V; I, +0.615 V; At, approximately +0.3 V). Bromination often leads to higher oxidation states than iodination but lower or equal oxidation states to chlorination. Bromine tends to react with compounds including M–M, M–H, or M–C bonds to form M–Br bonds.
Dibromomethane or methylene bromide, or methylene dibromide is a halomethane with the formula CH2Br2. It is slightly soluble in water but very soluble in organic solvents. It is a colorless liquid.
Bromous acid is the inorganic compound with the formula of HBrO2. It is an unstable compound, although salts of its conjugate base – bromites – have been isolated. In acidic solution, bromites decompose to bromine.
Sodium chromate is the inorganic compound with the formula Na2CrO4. It exists as a yellow hygroscopic solid, which can form tetra-, hexa-, and decahydrates. It is an intermediate in the extraction of chromium from its ores.
Organobromine chemistry is the study of the synthesis and properties of organobromine compounds, also called organobromides, which are organic compounds that contain carbon bonded to bromine. The most pervasive is the naturally produced bromomethane.
Nitrosyl bromide is the chemical compound with the chemical formula NOBr. It is a red gas with a condensing point just below room temperature. It reacts with water.