Sodium bromate

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Sodium bromate
Bromicnan sodny.JPG
The sodium cation Sodium-3D.png
The sodium cation
The bromate anion (space-filling model) Bromate-3D-vdW.png
The bromate anion (space-filling model)
Names
IUPAC name
Sodium bromate
Other names
Sodium bromate(V)
Bromic acid, sodium salt
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.029.237 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 232-160-4
PubChem CID
RTECS number
  • EF8750000
UNII
UN number 1494
  • InChI=1S/BrHO3.Na/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1 Yes check.svgY
    Key: XUXNAKZDHHEHPC-UHFFFAOYSA-M Yes check.svgY
  • InChI=1/BrHO3.Na/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1
    Key: XUXNAKZDHHEHPC-REWHXWOFAY
  • [Na+].[O-]Br(=O)=O
Properties
NaBrO3
Molar mass 150.89g/mol
Appearancecolorless or white solid
Odor odorless
Density 3.339 g/cm3
Melting point 381 °C (718 °F; 654 K)
Boiling point 1,390 °C (2,530 °F; 1,660 K)
27.5 g/100 mL (0 °C)
36.4 g/100 mL (20 °C)
48.8 g/100 mL (40 °C)
90.8 g/100 mL (100 °C)
Solubility soluble in ammonia
insoluble in ethanol
44.2·10−6 cm3/mol
1.594
Structure
cubic
Thermochemistry
Std molar
entropy
(S298)
130.5 J/mol K
-342.5 kJ/mol
-252.6 kJ/mol
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Oxidizing agent
GHS labelling:
GHS-pictogram-rondflam.svg GHS-pictogram-exclam.svg GHS-pictogram-silhouette.svg
Danger
H271, H272, H302, H315, H319, H335, H341, H350
P201, P202, P210, P220, P221, P261, P264, P270, P271, P280, P281, P283, P301+P312, P302+P352, P304+P340, P305+P351+P338, P306+P360, P308+P313, P312, P321, P330, P332+P313, P337+P313, P362, P370+P378, P371+P380+P375, P403+P233, P405, P501
NFPA 704 (fire diamond)
NFPA 704.svgHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazard OX: Oxidizer. E.g. potassium perchlorate
1
0
0
OX
Flash point 381 °C (718 °F; 654 K)
Safety data sheet (SDS) ICSC 0196
Related compounds
Other anions
Sodium chlorate
Sodium iodate
Other cations
Potassium bromate
Calcium bromate
Related compounds
Sodium bromide
Sodium hypobromite
Sodium bromite
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
X mark.svgN  verify  (what is  Yes check.svgYX mark.svgN ?)

Sodium bromate, the inorganic compound with the chemical formula of NaBrO3, is the sodium salt of bromic acid. It is a strong oxidant.

Contents

Uses

Sodium bromate is mainly used in continuous or batch dyeing processes involving sulfur or vat dyes and as a hair-permagent, chemical agent, or gold solvent in gold mines when used with sodium bromide.

Production

Sodium bromate is produced by passing bromine into a solution of sodium carbonate. [1] It may also be produced by the electrolytic oxidation of sodium bromide. Alternatively, it can also be created by the oxidation of bromine with chlorine to sodium hydroxide at 80 °C.

3 Br2+3 Na2CO3 → 5 NaBr+NaBrO3+3 CO2

Human health issues

Bromate in drinking water is undesirable because it is a suspected human carcinogen. [2] [3] Its presence in Coca-Cola's Dasani bottled water forced a recall of that product in the UK. [4]

Related Research Articles

<span class="mw-page-title-main">Bromine</span> Chemical element, symbol Br and atomic number 35

Bromine is a chemical element; it has symbol Br and atomic number 35. It is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between those of chlorine and iodine. Isolated independently by two chemists, Carl Jacob Löwig and Antoine Jérôme Balard, its name was derived from the Ancient Greek βρῶμος (bromos) meaning "stench", referring to its sharp and pungent smell.

<span class="mw-page-title-main">Sodium carbonate</span> Chemical compound

Sodium carbonate is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water. Historically, it was extracted from the ashes of plants grown in sodium-rich soils, and because the ashes of these sodium-rich plants were noticeably different from ashes of wood, sodium carbonate became known as "soda ash". It is produced in large quantities from sodium chloride and limestone by the Solvay process, as well as by carbonating sodium hydroxide which is made using the Chlor-alkali process.

<span class="mw-page-title-main">Oxidizing agent</span> Chemical compound used to oxidize another substance in a chemical reaction

An oxidizing agent is a substance in a redox chemical reaction that gains or "accepts"/"receives" an electron from a reducing agent. In other words, an oxidizer is any substance that oxidizes another substance. The oxidation state, which describes the degree of loss of electrons, of the oxidizer decreases while that of the reductant increases; this is expressed by saying that oxidizers "undergo reduction" and "are reduced" while reducers "undergo oxidation" and "are oxidized". Common oxidizing agents are oxygen, hydrogen peroxide, and the halogens.

<span class="mw-page-title-main">Hydrogen bromide</span> Chemical compound

Hydrogen bromide is the inorganic compound with the formula HBr. It is a hydrogen halide consisting of hydrogen and bromine. A colorless gas, it dissolves in water, forming hydrobromic acid, which is saturated at 68.85% HBr by weight at room temperature. Aqueous solutions that are 47.6% HBr by mass form a constant-boiling azeotrope mixture that boils at 124.3 °C (255.7 °F). Boiling less concentrated solutions releases H2O until the constant-boiling mixture composition is reached.

<span class="mw-page-title-main">Sodium bromide</span> Inorganic salt: NaBr

Sodium bromide is an inorganic compound with the formula NaBr. It is a high-melting white, crystalline solid that resembles sodium chloride. It is a widely used source of the bromide ion and has many applications.

A bromide ion is the negatively charged form (Br) of the element bromine, a member of the halogens group on the periodic table. Most bromides are colorless. Bromides have many practical roles, being found in anticonvulsants, flame-retardant materials, and cell stains. Although uncommon, chronic toxicity from bromide can result in bromism, a syndrome with multiple neurological symptoms. Bromide toxicity can also cause a type of skin eruption, see potassium bromide. The bromide ion has an ionic radius of 196 pm.

Sodium oxide is a chemical compound with the formula Na2O. It is used in ceramics and glasses. It is a white solid but the compound is rarely encountered. Instead "sodium oxide" is used to describe components of various materials such as glasses and fertilizers which contain oxides that include sodium and other elements.

<span class="mw-page-title-main">Bromate</span> Ion, and compounds containing the ion

The bromate anion, BrO
3
, is a bromine-based oxoanion. A bromate is a chemical compound that contains this ion. Examples of bromates include sodium bromate,, and potassium bromate,.

<span class="mw-page-title-main">Bromine pentafluoride</span> Chemical compound

Bromine pentafluoride, BrF5, is an interhalogen compound and a fluoride of bromine. It is a strong fluorinating agent.

<span class="mw-page-title-main">Potassium bromate</span> Chemical compound

Potassium bromate is a bromate of potassium and takes the form of white crystals or powder. It is a strong oxidizing agent.

<span class="mw-page-title-main">Hypobromous acid</span> Chemical compound

Hypobromous acid is a weak, unstable acid with chemical formula of HOBr. It is mainly produced and handled in an aqueous solution. It is generated both biologically and commercially as a disinfectant. Salts of hypobromite are rarely isolated as solids.

<span class="mw-page-title-main">Arsenic tribromide</span> Chemical compound

Arsenic tribromide is an inorganic compound with the formula AsBr3, it is a bromide of arsenic. Arsenic is a chemical element that has the symbol As and atomic number 33. This pyramidal molecule is the only known binary arsenic bromide. AsBr3 is noteworthy for its very high refractive index of approximately 2.3. It also has a very high diamagnetic susceptibility. It is a poisonous metalloid that has many allotropic forms: yellow and several black and gray forms (metalloids), orthorhombic prisms, colorless rhombic crystals are a few that are seen. Bromine is a halogen element with the symbol Br and atomic number 35. Diatomic bromine does not occur naturally, but bromine salts can be found in crustal rock.

<span class="mw-page-title-main">Hypobromite</span> Ion, and compounds containing the ion

The hypobromite ion, also called alkaline bromine water, is BrO. Bromine is in the +1 oxidation state. The Br–O bond length is 1.82 Å. Hypobromite is the bromine compound analogous to hypochlorites found in common bleaches, and in immune cells. In many ways, hypobromite functions in the same manner as hypochlorite, and is also used as a germicide and antiparasitic in both industrial applications, and in the immune system.

Bromine compounds are compounds containing the element bromine (Br). These compounds usually form the -1, +1, +3 and +5 oxidation states. Bromine is intermediate in reactivity between chlorine and iodine, and is one of the most reactive elements. Bond energies to bromine tend to be lower than those to chlorine but higher than those to iodine, and bromine is a weaker oxidising agent than chlorine but a stronger one than iodine. This can be seen from the standard electrode potentials of the X2/X couples (F, +2.866 V; Cl, +1.395 V; Br, +1.087 V; I, +0.615 V; At, approximately +0.3 V). Bromination often leads to higher oxidation states than iodination but lower or equal oxidation states to chlorination. Bromine tends to react with compounds including M–M, M–H, or M–C bonds to form M–Br bonds.

<span class="mw-page-title-main">Dibromomethane</span> Chemical compound

Dibromomethane or methylene bromide, or methylene dibromide is a halomethane with the formula CH2Br2. It is slightly soluble in water but very soluble in organic solvents. It is a colorless liquid.

<span class="mw-page-title-main">Bromous acid</span> Chemical compound

Bromous acid is the inorganic compound with the formula of HBrO2. It is an unstable compound, although salts of its conjugate base – bromites – have been isolated. In acidic solution, bromites decompose to bromine.

<span class="mw-page-title-main">Sodium chromate</span> Chemical compound

Sodium chromate is the inorganic compound with the formula Na2CrO4. It exists as a yellow hygroscopic solid, which can form tetra-, hexa-, and decahydrates. It is an intermediate in the extraction of chromium from its ores.

Organobromine chemistry is the study of the synthesis and properties of organobromine compounds, also called organobromides, which are organic compounds that contain carbon bonded to bromine. The most pervasive is the naturally produced bromomethane.

Nitrosyl bromide is the chemical compound with the chemical formula NOBr. It is a red gas with a condensing point just below room temperature. It reacts with water.

References

  1. "Br2 + Na2CO3 = NaBr + NaBrO3 + CO2 | Chemical reaction and equation".
  2. "Potassium Bromate (Group 2B)". International Agency for Research on Cancer: Summaries and Evaluations. Canadian Centre for Occupational Health and Safety . Retrieved 2008-03-09.
  3. Kurokawa, Yuji; Maekawa, A; Takahashi, M; Hayashi, Y (July 1990). "Toxicity and carcinogenicity of potassium bromate—a new renal carcinogen". Environmental Health Perspectives . 87: 309–35. doi:10.1289/EHP.9087309. JSTOR   3431039. PMC   1567851 . PMID   2269236.
  4. "Coke recalls controversial water". BBC News . 2004-03-19. Retrieved 2008-03-09.