Ytterbium(III) bromate

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Ytterbium(III) bromate
Identifiers
Properties
Br3O9Yb
Molar mass 556.748 g·mol−1
Appearancecolourless needle crystals (nonahydrate) [1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Ytterbium(III) bromate is an inorganic compound with the chemical formula Yb(BrO3)3. It can be produced by the reaction of ytterbium(III) sulfate and barium bromate. After filtering out the barium sulfate, the solution is concentrated to crystallize ytterbium(III) bromate nonahydrate. [1] [2] The nonahydrate is thermally decomposed into anhydride to obtain ytterbium oxybromide. [2]

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<span class="mw-page-title-main">Ytterbium</span> Chemical element, symbol Yb and atomic number 70

Ytterbium is a chemical element; it has symbol Yb and atomic number 70. It is a metal, the fourteenth and penultimate element in the lanthanide series, which is the basis of the relative stability of its +2 oxidation state. Like the other lanthanides, its most common oxidation state is +3, as in its oxide, halides, and other compounds. In aqueous solution, like compounds of other late lanthanides, soluble ytterbium compounds form complexes with nine water molecules. Because of its closed-shell electron configuration, its density, melting point and boiling point are much lower than those of most other lanthanides.

<span class="mw-page-title-main">Ytterbium(III) oxide</span> Chemical compound

Ytterbium(III) oxide is the chemical compound with the formula Yb2O3. It is one of the more commonly encountered compounds of ytterbium. It occurs naturally in trace amounts in the mineral gadolinite. It was first isolated from this in 1878 by Jean Charles Galissard de Marignac.

<span class="mw-page-title-main">Perbromate</span> Ion

In chemistry, the perbromate ion is the anion having the chemical formula BrO
4
. It is an oxyanion of bromine, the conjugate base of perbromic acid, in which bromine has the oxidation state +7. Unlike its chlorine and iodine analogs, it is difficult to synthesize. It has tetrahedral molecular geometry.

Selenic acid is the inorganic compound with the formula H2SeO4. It is an oxoacid of selenium, and its structure is more accurately described as O2Se(OH)2. It is a colorless compound. Although it has few uses, one of its salts, sodium selenate is used in the production of glass and animal feeds.

Calcium bromate, Ca(BrO3)2, is a calcium salt of bromic acid. It is most commonly encountered as the monohydrate, Ca(BrO3)2•H2O.

Langbeinites are a family of crystalline substances based on the structure of langbeinite with general formula M2M'2(SO4)3, where M is a large univalent cation, and M' is a small divalent cation. The sulfate group, SO2−4, can be substituted by other tetrahedral anions with a double negative charge such as tetrafluoroberyllate, selenate, chromate, molybdate, or tungstates. Although monofluorophosphates are predicted, they have not been described. By redistributing charges other anions with the same shape such as phosphate also form langbeinite structures. In these the M' atom must have a greater charge to balance the extra three negative charges.

Yttrium(III) sulfate is an inorganic compound with the formula Y2(SO4)3. The most common form is the anhydrate and octahydrate.

A sulfite sulfate is a chemical compound that contains both sulfite and sulfate anions [SO3]2− [SO4]2−. These compounds were discovered in the 1980s as calcium and rare earth element salts. Minerals in this class were later discovered. Minerals may have sulfite as an essential component, or have it substituted for another anion as in alloriite. The related ions [O3SOSO2]2− and [(O2SO)2SO2]2− may be produced in a reaction between sulfur dioxide and sulfate and exist in the solid form as tetramethyl ammonium salts. They have a significant partial pressure of sulfur dioxide.

<span class="mw-page-title-main">Iron(II) nitrate</span> Chemical compound

Iron(II) nitrate is the nitrate salt of iron(II). It is commonly encountered as the green hexahydrate, Fe(NO3)2·6H2O, which is a metal aquo complex, however it is not commercially available unlike iron(III) nitrate due to its instability to air. The salt is soluble in water serves as a ready source of ferrous ions.

The borate bromides are mixed anion compounds that contain borate and bromide anions. They are in the borate halide family of compounds which also includes borate fluorides, borate chlorides, and borate iodides.

<span class="mw-page-title-main">Ytterbium(III) nitrate</span> Chemical compound

Ytterbium(III) nitrate is an inorganic compound, a salt of ytterbium and nitric acid with the chemical formula Yb(NO3)3. The compound forms colorless crystals, dissolves in water, and also forms crystalline hydrates.

Neodymium(III) iodide is an inorganic salt of iodine and neodymium with the formula NdI3. Neodymium uses the +3 oxidation state in the compound. The anhydrous compound is a green powdery solid at room temperature.

<span class="mw-page-title-main">Neodymium compounds</span> Chemical compounds with at least one neodymium atom

Neodymium compounds are compounds formed by the lanthanide metal neodymium (Nd). In these compounds, neodymium generally exhibits the +3 oxidation state, such as NdCl3, Nd2(SO4)3 and Nd(CH3COO)3. Compounds with neodymium in the +2 oxidation state are also known, such as NdCl2 and NdI2. Some neodymium compounds have colors that vary based upon the type of lighting.

<span class="mw-page-title-main">Ytterbium(III) acetate</span> Chemical compound

Ytterbium(III) acetate is an inorganic salt of ytterbium and acetic acid, with a chemical formula of Yb(CH3COO)3. It has colorless crystals that are soluble in water and can form hydrates.

Ytterbium compounds are chemical compounds that contain the element ytterbium (Yb). The chemical behavior of ytterbium is similar to that of the rest of the lanthanides. Most ytterbium compounds are found in the +3 oxidation state, and its salts in this oxidation state are nearly colorless. Like europium, samarium, and thulium, the trihalides of ytterbium can be reduced to the dihalides by hydrogen, zinc dust, or by the addition of metallic ytterbium. The +2 oxidation state occurs only in solid compounds and reacts in some ways similarly to the alkaline earth metal compounds; for example, ytterbium(II) oxide (YbO) shows the same structure as calcium oxide (CaO).

Praseodymium bromide is an inorganic compound with the chemical formula Pr(BrO3)3. It is soluble in water and can form the dihydrate, tetrahydrate and nonahydrate. The nonahydrate melts in its own crystal water at 56.5 °C and completely loses its crystal water at 130 °C. It can be produced by the reaction of barium bromate and praseodymium sulfate.

<span class="mw-page-title-main">Ytterbium(III) acetylacetonate</span> Chemical compound

Ytterbium(III) acetylacetonate is a coordination compound with the chemical formula Yb(C5H7O2)3(H2O)2. Its structure is different from the acetylacetone complexes of neodymium, europium and holmium. The adjacent Yb-Yb The distance is 8.3 Å. Yb(acac)3(bpy) can be obtained by reacting its trihydrate with 2,2'-bipyridine in ethanol.

Barium selenate is an inorganic compound with the chemical formula BaSeO4. It is isomorphous with barium sulfate, but its solubility is 18 times that of barium sulfate, and its thermal stability is worse than that of barium sulfate.

Ytterbium(III) iodate is an inorganic compound with the chemical formula Yb(IO3)3. Its dihydrate can be prepared by reacting ytterbium sulfate and iodic acid in water at 200 °C. It crystallizes in the P21/c space group, with unit cell parameters a=8.685, b=6.066, c=16.687 Å, β=115.01°.

References

  1. 1 2 Neogy, D.; Chakrabarti, P. K.; Chattopadhyay, K. N.; Chatterji, A. (Apr 1996). "Magnetic measurements and crystal field investigations on Yb(BrO 3 ) 3 · 9 H 2 O". physica status solidi (b). 194 (2): 717–721. doi:10.1002/pssb.2221940227. ISSN   0370-1972.
  2. 1 2 Mayer, I.; Glasner, Y. (Jul 1967). "Rare earth bromate hydrates". Journal of Inorganic and Nuclear Chemistry. 29 (7): 1605–1609. doi:10.1016/0022-1902(67)80203-3.

External reading