Strontium bromate

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Strontium bromate
Names
IUPAC name
Strontium dibromate
Identifiers
3D model (JSmol)
ECHA InfoCard 100.035.013 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 238-531-7
PubChem CID
UNII
  • InChI=1S/2BrHO3.Sr/c2*2-1(3)4;/h2*(H,2,3,4);/q;;+2/p-2
  • [O-]Br(=O)=O.[O-]Br(=O)=O.[Sr+2]
Properties
SrBr2O6
Molar mass 343.424 g/mol
Melting point 240 °C (464 °F; 513 K) (decomposes)
27.2 g/100 mL
−93.5·10−6 cm3/mol
Related compounds
Other cations
calcium bromate
barium bromate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Strontium bromate is a rarely considered chemical in the laboratory or in industries. It is, however, mentioned in the book Uncle Tungsten: Memories of a Chemical Boyhood by Oliver Sacks. There it is said that this salt glows when crystallized from a saturated aqueous solution. [1] Chemically this salt is soluble in water, and is a moderately strong oxidizing agent. [2]

Strontium bromate is toxic if ingested and irritates the skin and respiratory tract if come into contact with or inhaled, respectively. Its chemical formula is Sr(BrO3)2.

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<i>Uncle Tungsten</i> Book by Oliver Sacks

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<span class="mw-page-title-main">Trivial name</span> Nonsystematic name for a chemical substance

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<span class="mw-page-title-main">Strontium chloride</span> Chemical compound

Strontium chloride (SrCl2) is a salt of strontium and chloride. It is a 'typical' salt, forming neutral aqueous solutions. As with all compounds of strontium, this salt emits a bright red colour in flame, and is commonly used in fireworks to that effect. Its properties are intermediate between those for barium chloride, which is more toxic, and calcium chloride.

<span class="mw-page-title-main">Perbromate</span> Ion

In chemistry, the perbromate ion is the anion having the chemical formula BrO
4
. It is an oxyanion of bromine, the conjugate base of perbromic acid, in which bromine has the oxidation state +7. Unlike its chlorine and iodine analogs, it is difficult to synthesize. It has tetrahedral molecular geometry.

<span class="mw-page-title-main">Sodium bromate</span> Chemical compound

Sodium bromate, the inorganic compound with the chemical formula of NaBrO3, is the sodium salt of bromic acid. It is a strong oxidant.

<span class="mw-page-title-main">Strontium hydroxide</span> Chemical compound

Strontium hydroxide, Sr(OH)2, is a caustic alkali composed of one strontium ion and two hydroxide ions. It is synthesized by combining a strontium salt with a strong base. Sr(OH)2 exists in anhydrous, monohydrate, or octahydrate form.

<span class="mw-page-title-main">Aluminium nitrate</span> Chemical compound

Aluminium nitrate is a white, water-soluble salt of aluminium and nitric acid, most commonly existing as the crystalline hydrate, aluminium nitrate nonahydrate, Al(NO3)3·9H2O.

<span class="mw-page-title-main">Potassium iodate</span> Chemical compound

Potassium iodate (KIO3) is an ionic chemical compound consisting of K+ ions and IO3 ions in a 1:1 ratio.

<span class="mw-page-title-main">Strontium nitrate</span> Chemical compound

Strontium nitrate is an inorganic compound composed of the elements strontium, nitrogen and oxygen with the formula Sr(NO3)2. This colorless solid is used as a red colorant and oxidizer in pyrotechnics.

<span class="mw-page-title-main">Strontium carbonate</span> Chemical compound

Strontium carbonate (SrCO3) is the carbonate salt of strontium that has the appearance of a white or grey powder. It occurs in nature as the mineral strontianite.

<span class="mw-page-title-main">Strontium sulfate</span> Chemical compound

Strontium sulfate (SrSO4) is the sulfate salt of strontium. It is a white crystalline powder and occurs in nature as the mineral celestine. It is poorly soluble in water to the extent of 1 part in 8,800. It is more soluble in dilute HCl and nitric acid and appreciably soluble in alkali chloride solutions (e.g. sodium chloride).

<span class="mw-page-title-main">Strontium iodide</span> Chemical compound

Strontium iodide (SrI2) is a salt of strontium and iodine. It is an ionic, water-soluble, and deliquescent compound that can be used in medicine as a substitute for potassium iodide . It is also used as a scintillation gamma radiation detector, typically doped with europium, due to its optical clarity, relatively high density, high effective atomic number (Z=48), and high scintillation light yield. In recent years, europium-doped strontium iodide (SrI2:Eu2+) has emerged as a promising scintillation material for gamma-ray spectroscopy with extremely high light yield and proportional response, exceeding that of the widely used high performance commercial scintillator LaBr3:Ce3+. Large diameter SrI2 crystals can be grown reliably using vertical Bridgman technique and are being commercialized by several companies.

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<span class="mw-page-title-main">Strontium oxalate</span> Chemical compound

Strontium oxalate is a compound with the chemical formula SrC2O4. Strontium oxalate can exist either in a hydrated form (SrC2O4nH2O) or as the acidic salt of strontium oxalate (SrC2O4mH2C2O4nH2O).

<span class="mw-page-title-main">Strontium barium niobate</span> Chemical compound

Strontium barium niobate is the chemical compound SrxBa1−xNb2O6 for 0.32≤x≤0.82.

<span class="mw-page-title-main">Manganokhomyakovite</span>

Manganokhomyakovite is a very rare mineral of the eudialyte group, with the chemical formula Na12Sr3Ca6Mn3Zr3WSi(Si9O27)2(Si3O9)2O(O,OH,H2O)3(OH,Cl)2. This formula is in extended form, to show the presence of cyclic silicate groups and domination of silicon at the M4 site, basing on the nomenclature of the eudialyte group. Some niobium substitutes for tungsten in khomyakovite. As suggested by its name, manganokhomyakovite is a manganese-analogue of khomyakovite, the latter being more rare. The two minerals are the only group representatives, beside taseqite, with species-defining strontium, although many other members display strontium diadochy. Manganokhomyakovite is the third eudialyte-group mineral with essential tungsten.

The per­iodato­nickelates are a series of anions and salts of nickel complexed to the periodate anion. The most important of these salts are the di­periodato­nickelates, in which nickel exhibits the +4 oxidation state: these are powerful oxidising agents, capable of oxidising bromate to perbromate.

References

  1. Oliver Sacks (2002). Uncle Tungsten: Memories of a Chemical Boyhood (First Vintage Books ed.). p. 230.
  2. "Strontium Bromate". American Elements. Retrieved 25 July 2013.