The unit cell of the layered perovskite structure of strontium ruthenate. Ruthenium ions are red, strontium ions are blue, and oxygen ions are green. | |
Identifiers | |
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3D model (JSmol) | |
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Properties | |
Sr2RuO4 | |
Structure [1] | |
K2NiF4 structure (body-centered tetragonal) | |
a = 387 pm, c = 1274 pm | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Distrontium ruthenate, also known as strontium ruthenate, is an oxide of strontium and ruthenium with the chemical formula Sr2RuO4. It was the first reported perovskite superconductor that did not contain copper. Strontium ruthenate is structurally very similar to the high-temperature cuprate superconductors, and in particular, is almost identical to the lanthanum doped superconductor (La, Sr)2CuO4. However, the transition temperature for the superconducting phase transition is 0.93 K (about 1.5 K for the best sample), which is much lower than the corresponding value for cuprates. [2]
Superconductivity in SRO was first observed by Yoshiteru Maeno et al. Unlike the cuprate superconductors, SRO displays superconductivity in the absence of doping. [2] The superconducting order parameter in SRO exhibits signatures of time-reversal symmetry breaking, [3] and hence, it can be classified as an unconventional superconductor.
Sr2RuO4 is believed to be a fairly two-dimensional system, with superconductivity occurring primarily on the Ru-O plane. The electronic structure of Sr2RuO4 is characterized by three bands derived from the Ru t2g 4d orbitals, namely, α, β and γ bands, of which the first is hole-like while the other two are electron-like. Among them, the γ band arises mainly from the dxy orbital, while the α and β bands emerge from the hybridization of dxz and dyz orbitals. Due to the two-dimensionality of Sr2RuO4, its Fermi surface consists of three nearly two-dimensional sheets with little dispersion along the crystalline c-axis and that the compound is nearly magnetic. [4]
Early proposals suggested that superconductivity is dominant in the γ band. In particular, the candidate chiral p-wave order parameter in the momentum space exhibits k-dependence phase winding which is characteristic of time-reversal symmetry breaking. This peculiar single-band superconducting order is expected to give rise to appreciable spontaneous supercurrent at the edge of the sample. Such an effect is closely associated with the topology of the Hamiltonian describing Sr2RuO4 in the superconducting state, which is characterized by a nonzero Chern number. However, scanning probes have so far failed to detect expected time-reversal symmetry breaking fields generated by the supercurrent, off by orders of magnitude. [5] This has led some to speculate that superconductivity arises dominantly from the α and β bands instead. [6] Such a two-band superconductor, although having k-dependence phase winding in its order parameters on the two relevant bands, is topologically trivial with the two bands featuring opposite Chern numbers. Therefore, it could possibly give a much reduced if not completely cancelled supercurrent at the edge. However, this naive reasoning was later found not to be entirely correct: the magnitude of edge current is not directly related to the topological property of the chiral state. [7] In particular, although the non-trivial topology is expected to give rise to protected chiral edge states, due to U(1) symmetry-breaking the edge current is not a protected quantity. In fact, it has been shown that the edge current vanishes identically for any higher angular momentum chiral pairing states which feature even larger Chern numbers, such as chiral d-, f-wave etc. [8] [9]
Tc seems to increase under uniaxial compression [10] that pushes the van Hove singularity of the dxy orbital across the Fermi level. [11]
Evidence was reported for p-wave singlet state as in cuprates and conventional superconductors, instead of the conjectured more unconventional p-wave triplet state. [12] [13] It has also been suggested that Strontium ruthenate superconductivity could be due to a Fulde–Ferrell–Larkin–Ovchinnikov phase. [14] [15]
Strontium ruthenate behaves as a conventional Fermi liquid at temperatures below 25 K. [16]
In 2023, a team of researchers from the University of Illinois Urbana-Champaign confirmed the 67-year-old prediction of Pines' demon excitation in Sr2RuO4. [17]
Superconductivity is a set of physical properties observed in superconductors: materials where electrical resistance vanishes and magnetic fields are expelled from the material. Unlike an ordinary metallic conductor, whose resistance decreases gradually as its temperature is lowered, even down to near absolute zero, a superconductor has a characteristic critical temperature below which the resistance drops abruptly to zero. An electric current through a loop of superconducting wire can persist indefinitely with no power source.
Unconventional superconductors are materials that display superconductivity which is not explained by the usual BCS theory or its extension, the Eliashberg theory. The pairing in unconventional superconductors may originate from some other mechanism than the electron–phonon interaction. Alternatively, a superconductor is unconventional if the superconducting order parameter transforms according to a non-trivial irreducible representation of the point group or space group of the system. Per definition, superconductors that break additional symmetries to U (1) symmetry are known as unconventional superconductors.
High-temperature superconductivity is superconductivity in materials with a critical temperature above 77 K, the boiling point of liquid nitrogen. They are only "high-temperature" relative to previously known superconductors, which function at colder temperatures, close to absolute zero. The "high temperatures" are still far below ambient, and therefore require cooling. The first breakthrough of high-temperature superconductor was discovered in 1986 by IBM researchers Georg Bednorz and K. Alex Müller. Although the critical temperature is around 35.1 K, this new type of superconductor was readily modified by Ching-Wu Chu to make the first high-temperature superconductor with critical temperature 93 K. Bednorz and Müller were awarded the Nobel Prize in Physics in 1987 "for their important break-through in the discovery of superconductivity in ceramic materials". Most high-Tc materials are type-II superconductors.
In physics, topological order is a kind of order in the zero-temperature phase of matter. Macroscopically, topological order is defined and described by robust ground state degeneracy and quantized non-abelian geometric phases of degenerate ground states. Microscopically, topological orders correspond to patterns of long-range quantum entanglement. States with different topological orders cannot change into each other without a phase transition.
In condensed matter physics, a pseudogap describes a state where the Fermi surface of a material possesses a partial energy gap, for example, a band structure state where the Fermi surface is gapped only at certain points.
In superconductivity, a semifluxon is a half integer vortex of supercurrent carrying the magnetic flux equal to the half of the magnetic flux quantum Φ0. Semifluxons exist in the 0-π long Josephson junctions at the boundary between 0 and π regions. This 0-π boundary creates a π discontinuity of the Josephson phase. The junction reacts to this discontinuity by creating a semifluxon. Vortex's supercurrent circulates around 0-π boundary. In addition to semifluxon, there exist also an antisemifluxon. It carries the flux −Φ0/2 and its supercurrent circulates in the opposite direction.
A Majorana fermion, also referred to as a Majorana particle, is a fermion that is its own antiparticle. They were hypothesised by Ettore Majorana in 1937. The term is sometimes used in opposition to a Dirac fermion, which describes fermions that are not their own antiparticles.
A Josephson junction (JJ) is a quantum mechanical device which is made of two superconducting electrodes separated by a barrier. A π Josephson junction is a Josephson junction in which the Josephson phase φ equals π in the ground state, i.e. when no external current or magnetic field is applied.
Patrick A. Lee is a professor of physics at the Massachusetts Institute of Technology (MIT).
Iron-based superconductors (FeSC) are iron-containing chemical compounds whose superconducting properties were discovered in 2006. In 2008, led by recently discovered iron pnictide compounds, they were in the first stages of experimentation and implementation..
Xiao-Gang Wen is a Chinese-American physicist. He is a Cecil and Ida Green Professor of Physics at the Massachusetts Institute of Technology and Distinguished Visiting Research Chair at the Perimeter Institute for Theoretical Physics. His expertise is in condensed matter theory in strongly correlated electronic systems. In Oct. 2016, he was awarded the Oliver E. Buckley Condensed Matter Prize.
Type-1.5 superconductors are multicomponent superconductors characterized by two or more coherence lengths, at least one of which is shorter than the magnetic field penetration length , and at least one of which is longer. This is in contrast to single-component superconductors, where there is only one coherence length and the superconductor is necessarily either type 1 or type 2. When placed in magnetic field, type-1.5 superconductors should form quantum vortices: magnetic-flux-carrying excitations. They allow magnetic field to pass through superconductors due to a vortex-like circulation of superconducting particles. In type-1.5 superconductors these vortices have long-range attractive, short-range repulsive interaction. As a consequence a type-1.5 superconductor in a magnetic field can form a phase separation into domains with expelled magnetic field and clusters of quantum vortices which are bound together by attractive intervortex forces. The domains of the Meissner state retain the two-component superconductivity, while in the vortex clusters one of the superconducting components is suppressed. Thus such materials should allow coexistence of various properties of type-I and type-II superconductors.
The 122 iron arsenide unconventional superconductors are part of a new class of iron-based superconductors. They form in the tetragonal I4/mmm, ThCr2Si2 type, crystal structure. The shorthand name "122" comes from their stoichiometry; the 122s have the chemical formula AEFe2Pn2, where AE stands for alkaline earth metal (Ca, Ba Sr or Eu) and Pn is pnictide (As, P, etc.). These materials become superconducting under pressure and also upon doping. The maximum superconducting transition temperature found to date is 38 K in the Ba0.6K0.4Fe2As2. The microscopic description of superconductivity in the 122s is yet unclear.
Superstripes is a generic name for a phase with spatial broken symmetry that favors the onset of superconducting or superfluid quantum order. This scenario emerged in the 1990s when non-homogeneous metallic heterostructures at the atomic limit with a broken spatial symmetry have been found to favor superconductivity. Before a broken spatial symmetry was expected to compete and suppress the superconducting order. The driving mechanism for the amplification of the superconductivity critical temperature in superstripes matter has been proposed to be the shape resonance in the energy gap parameters ∆n that is a type of Fano resonance for coexisting condensates.
Alexander V. Balatsky is a USSR-born American physicist. He is the professor of theoretical physics at NORDITA and University of Connecticut. He served as the founding director of the Institute for Materials Science (IMS) at Los Alamos National Laboratory in 2014–2017.
Thomas Maurice Rice, known professionally as Maurice Rice, was an Irish theoretical physicist specializing in condensed matter physics.
Dale J. Van Harlingen was an American condensed matter physicist.
In condensed matter physics, Pines' demon or, simply demon is a collective excitation of electrons which corresponds to electrons in different energy bands moving out of phase with each other. Equivalently, a demon corresponds to counter-propagating currents of electrons from different bands. Named after David Pines, who coined the term in 1956, demons are quantum mechanical excited states of a material belonging to a broader class of exotic collective excitations, such as the magnon, phason, or exciton. Pines' demon was first experimentally observed in 2023 by A. A. Husain et al. within the transition-metal oxide distrontium ruthenate (Sr2RuO4).
Dicalsium ruthenate, with the chemical formula Ca2RuO4, is a stochiometric oxide compound Ca2RuO4 that hosts a multi-orbital (band) Mott insulating ground state. For this reason, Ca2RuO4 serves as an important "meeting-point" between conceptual developments of strongly correlated multi-band physics and advanced experimental spectroscopies. Electronic structure but also orbital magnetism is therefore the subject experimental and theoretical scrutiny.